Abstract:
:A methyl group at the 2-position of methyl mesopyropheophorbide-a was transformed to the 2-formyl group to give methyl mesopyropheophorbide-f, one of the chlorophyll-f analogs. The 2-formylation moved the redmost electronic absorption band in a solution to a longer wavelength and the bathochromic shift was comparable to that by the 3-formylation. Zinc complex of the synthetic compound in solutions showed similar visible absorption spectra as those of naturally occurring chlorophyll-f.
journal_name
Bioorg Med Chem Lettjournal_title
Bioorganic & medicinal chemistry lettersauthors
Xu M,Kinoshita Y,Tamiaki Hdoi
10.1016/j.bmcl.2014.06.022subject
Has Abstractpub_date
2014-08-15 00:00:00pages
3997-4000issue
16eissn
0960-894Xissn
1464-3405pii
S0960-894X(14)00650-7journal_volume
24pub_type
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