Selective conversion of cellulose to levulinic acid via microwave-assisted synthesis in ionic liquids.

Abstract:

:A highly selective approach to produce levulinic acid from cellulose was developed via microwave-assisted synthesis in SO3H-functionalized ionic liquids (SFILs). The effects of reaction conditions and ionic liquid structures on the yield of levulinic acid have been investigated, where the highest yield of 55.0% was obtained. The catalytic activities of SFILs depend on the anions and decrease in the order: HSO4->CH3SO3->H2PO4-, which is in good agreement with their acidity order. The SFILs are efficient catalysts for cellulose conversion into levulinic acid and the subsequent esterification, which facilitates the separation of product and reuse of ionic liquids.

journal_name

Bioresour Technol

journal_title

Bioresource technology

authors

Ren H,Zhou Y,Liu L

doi

10.1016/j.biortech.2012.12.132

subject

Has Abstract

pub_date

2013-02-01 00:00:00

pages

616-9

eissn

0960-8524

issn

1873-2976

pii

S0960-8524(12)01990-6

journal_volume

129

pub_type

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