Kinetics and thermodynamics of the adsorption of some dyestuffs from aqueous solution by poplar sawdust.

Abstract:

:The effect of temperature on the adsorption of metanil yellow (MY) (acidic) and methylene blue (MB) (basic) by poplar sawdust was investigated. In addition, the amounts of NaHCO(3), Na(2)CO(3), NaOH and C(2)H(5)ONa adsorbed by 1g of poplar sawdust to determine its surface acidity were also determined. Kinetical data obtained at different temperatures (293 K, 313 K and 333 K) for the adsorption of each dyestuff by poplar sawdust were applied to the pseudo first-order, the pseudo second-order and the intraparticle diffusion equations, and the rate constants of first-order adsorption (k(1)), the rate constants of second-order adsorption (k(2)) and intraparticle diffusion rate constants (k(p)) at these temperatures were calculated, respectively. In addition, isothermal data obtained at different temperatures (293 K, 313 K and 333 K) for the adsorption of each dyestuff by poplar sawdust were applied to thermodynamical equations, and thermodynamical parameters (DeltaG, DeltaH and DeltaS) were also calculated.

journal_name

Bioresour Technol

journal_title

Bioresource technology

authors

Pekkuz H,Uzun I,Güzel F

doi

10.1016/j.biortech.2007.03.014

subject

Has Abstract

pub_date

2008-04-01 00:00:00

pages

2009-17

issue

6

eissn

0960-8524

issn

1873-2976

pii

S0960-8524(07)00246-5

journal_volume

99

pub_type

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