Competitive migration behaviors of multiple ions and their impacts on ion-exchange resin packed microbial desalination cell.

Abstract:

:Mixed ion-exchange resins packed microbial desalination cell (R-MDC) could stabilize the internal resistance, however, the impacts of multiple ions on R-MDC performance was unclear. This study investigated the desalination performance, multiple ions migration behaviors and their impacts on R-MDCs fed with salt solution containing multiple anions and cations. Results showed that R-MDC removed multiple anions better than multiple cations with desalination efficiency of 99% (effluent conductivity <0.05 ms/cm) at hydraulic retention time of 50 h. Competitive migration order was SO4(2-)>NO3(-)>Cl(-) for anions and Ca(2+)≈Mg(2+)>NH4(+)>Na(+) for cations, jointly affected by both their molar conductivity and exchange selectivity on resins. After long-term operation, the existence of higher concentration Ca(2+) and Mg(2+) caused the electric conductivity of mixed resins decrease and scaling on the surface of cation-exchange membrane adjoined with cathode chamber, suggesting that R-MDC would be more suitable for desalination of water with lower hardness.

journal_name

Bioresour Technol

journal_title

Bioresource technology

authors

Zuo K,Yuan L,Wei J,Liang P,Huang X

doi

10.1016/j.biortech.2013.07.139

subject

Has Abstract

pub_date

2013-10-01 00:00:00

pages

637-642

eissn

0960-8524

issn

1873-2976

pii

S0960-8524(13)01207-8

journal_volume

146

pub_type

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