Luminescent pH sensing and DNA binding properties of a novel ruthenium(II) complex.

abstract：:Signal transduction in plants determines their successful adaptation to diverse stress factors. Our group employed suspension cells to study the phosphoinositide pathway, which is triggered by aluminium stress. We investigated about members of the PI-specific phospholipase C (PLC) family and evaluated their transcript...

journal_title：Journal of inorganic biochemistry

authors： González-Mendoza VM,Sánchez-Sandoval ME,Munnik T,Hernández-Sotomayor SMT

更新日期：2020-03-01 00:00:00

abstract：:In the quest for more effective pain palliation radiopharmaceuticals for metastatic bone cancer, this paper relates results obtained with 166Ho complexed to the bone-seeking bisphosphonate, 1-hydroxy-4-aminopropililydenediphosphonate (APD). APD is itself a bone cancer pain palliation agent and this work was therefore ...

journal_title：Journal of inorganic biochemistry

authors： Zeevaart JR,Jarvis NV,Louw WK,Jackson GE,Cukrowski I,Mouton CJ

更新日期：1999-04-01 00:00:00

abstract：:The coordination geometry around copper(II) in [Cu(imda)(phen)(H2O)] (1) (H2imda = iminodiacetic acid, phen = 1,10-phenanthroline) is described as distorted octahedral while those in [Cu(imda)(5,6-dmp)] (2) (5,6-dmp = 5,6-dimethyl-1,10-phenanthroline) and [Cu(imda)(dpq)] (3) (dpq = dipyrido-[3,2-d:2',3'-f]-quinoxaline...

journal_title：Journal of inorganic biochemistry

authors： Selvakumar B,Rajendiran V,Uma Maheswari P,Stoeckli-Evans H,Palaniandavar M

更新日期：2006-03-01 00:00:00

abstract：:An iron porphycene, a structural isomer of iron porphyrin, with trifluoromethyl groups at the peripheral position of the framework was incorporated into sperm whale apomyoglobin. The prepared myoglobin shows the higher O(2) affinity than the native protein. However, the oxygen affinity of the reconstituted myoglobin i...

journal_title：Journal of inorganic biochemistry

authors： Matsuo T,Ito K,Nakashima Y,Hisaeda Y,Hayashi T

更新日期：2008-02-01 00:00:00

abstract：:The inhibitory effect of Cu2+, Mn2+, Co2+, and I- on naproxen-induced photohemolysis was investigated. In order to better understand this effect, these ions were also tested for lipid peroxidation and protein crosslinking, which are among the main processes involved in erythrocyte membrane damage. The overall results ...

journal_title：Journal of inorganic biochemistry

authors： Giuffrida S,De Guidi G,Miano P,Sortino S,Condorelli G,Costanzo LL

更新日期：1996-09-01 00:00:00

abstract：:Bis(picolinato)oxovanadium(IV) [VO(pic)2] is one of the most potent insulin-mimetic vanadium complexes. To probe coordination structural changes of this complex in vivo and provide insights into the origin of its high potency, an electron spin-echo envelope modulation (ESEEM) study was performed on organs (kidney, liv...

journal_title：Journal of inorganic biochemistry

authors： Fukui K,Fujisawa Y,OhyaNishiguchi H,Kamada H,Sakurai H

更新日期：1999-11-01 00:00:00

abstract：:Theoretical and spectroscopic studies of 3,3'-benzylidenedi-4-hydroxycoumarin (bhc) have been performed. B3LYP/6-31G* calculations reproduced the experimental molecular structure of bhc and showed two O-H...O asymmetrical intramolecular hydrogen bonds with O...O distances 2.638 and 2.696 A. The calculated Fukui functi...

journal_title：Journal of inorganic biochemistry

authors： Kostova I,Trendafilova N,Momekov G

更新日期：2005-02-01 00:00:00

abstract：:Cyclic voltammetry performed at rapid scan rates on cytochrome P450 from Pseudomonas putida (P450CAM) in didodecyldimethylammonium bromide (DDAB) films on graphite electrodes revealed a couple (E) at 830mV (vs Ag/AgCl). E was not significantly observed at scan rates less than 30V/s at room temperature, suggesting that...

journal_title：Journal of inorganic biochemistry

authors： Udit AK,Hill MG,Gray HB

更新日期：2006-04-01 00:00:00

abstract：:The action mechanism of vanadocene dichloride, Cp2VCl2 (Cp=eta5-C5H5), has been investigated by interaction with human serum transferrin for its promising antitumor activities. Our results have shown that Cp2VCl2 binds to transferrin and form a new complex, and the calculated apparent association constant is 1.37 x 10...

journal_title：Journal of inorganic biochemistry

authors： Du H,Xiang J,Zhang Y,Tang Y,Xu G

更新日期：2008-01-01 00:00:00

abstract：:Cross-linked enzyme aggregate (CLEA) methodology has been applied to immobilize cytochrome P450 BM3 variants (F87A and 21B3) with peroxygenase activity. Several Ru(II)-diimine complexes were found to be suitable cross-linking agents, surpassing the traditional glutaraldehyde and dextran aldehyde. They offer modular nu...

journal_title：Journal of inorganic biochemistry

authors： Do MQ,Henry E,Kato M,Cheruzel L

更新日期：2018-09-01 00:00:00

abstract：:A new Schiff base copper(II) complex, Cu(o-VANAHE)(2) (o-VANAHE = 2-(o-vanillinamino)-1-hydroxyethane), has been synthesized and characterized. Single crystal X-ray diffraction results suggest that this complex structure belongs to triclinic crystal system, space group P1 with the following crystallographic parameters...

journal_title：Journal of inorganic biochemistry

authors： Li LZ,Zhao C,Xu T,Ji HW,Yu YH,Guo GQ,Chao H

更新日期：2005-05-01 00:00:00

abstract：:Cystine, selenocytsine, and several analogs were reduced by dithiothreitol (DTT), beta-mercaptoethanol (ME) and sodium borohydride (NaBH4). DTT was the most effective; DTT to cystine ratios from 10 to 80 were equally effective. With selenocysteine, however, absorption was considerably reduced at all ratios. Selenocyst...

journal_title：Journal of inorganic biochemistry

authors： Burnell JN,Karle JA,Shrift A

更新日期：1980-07-01 00:00:00

abstract：:Three vanadium complexes of chlorodipicolinic acid (4-chloro-2,6-dipicolinic acid) in oxidation states III, IV, and V were prepared and their properties characterized across the oxidation states. In addition, the series of hydroxylamido, methylhydroxylamido, dimethylhydroxylamido, and diethylhydroxylamido complexes we...

journal_title：Journal of inorganic biochemistry

authors： Smee JJ,Epps JA,Ooms K,Bolte SE,Polenova T,Baruah B,Yang L,Ding W,Li M,Willsky GR,la Cour A,Anderson OP,Crans DC

更新日期：2009-04-01 00:00:00

abstract：:Two ruthenium(II) complexes (Ru-complexes) were synthesized and characterized in this study. The selectivity and ability of the complexes to interact with bcl-2 DNA were investigated here. It turned out that [Ru(ip)3](ClO4)2·2H2O (complex 1, ip = 1H-iminazole [4,5-f][1,10] phenanthroline) could induce and stabilize th...

journal_title：Journal of inorganic biochemistry

authors： Zhang J,Yu Q,Li Q,Yang L,Chen L,Zhou Y,Liu J

更新日期：2014-05-01 00:00:00

abstract：:Maintenance of cellular iron homeostasis demands the coordination of iron uptake, intracellular storage, and utilization. Recent investigations suggest that a single genetic regulatory system orchestrates the expression of proteins with central importance for all three aspects of cellular iron metabolism at the level ...

journal_title：Journal of inorganic biochemistry

authors： Kühn LC,Hentze MW

更新日期：1992-08-15 00:00:00

abstract：:New heteroditopic, bi- and multidentate imino- and aminophosphine ligands were synthesised and complexed to [AuCl(THT)] (THT=tetrahydrothiophene). X-ray crystallography confirmed Schiff base formation in three products, the successful reduction of the imino-group to the sp(3)-hybridised amine in several instances, and...

journal_title：Journal of inorganic biochemistry

authors： Traut-Johnstone T,Kanyanda S,Kriel FH,Viljoen T,Kotze PD,van Zyl WE,Coates J,Rees DJ,Meyer M,Hewer R,Williams DB

更新日期：2015-04-01 00:00:00

abstract：:The reaction of hydrogen peroxide and certain aromatic aldehydes with cytochrome P450BM3-F87G results in the covalent modification of the heme cofactor of this monooxygenase. Analysis of the resulting heme by electronic absorption spectrophotometry indicates that the reaction in the BM3 isoform is analogous to that in...

journal_title：Journal of inorganic biochemistry

authors： Raner GM,Hatchell AJ,Morton PE,Ballou DP,Coon MJ

更新日期：2000-08-31 00:00:00

abstract：:Because metallothionein (MT) may undergo thiol-disulfide or other redox reactions under certain cellular conditions, the partially and completely oxidized products of the reactions of Cd7-MT-II with the electrophile 5,5'-dithiobis(2-nitrobenzoic acid), ESSE, and oxidized glutathione, GSSG, were characterized. Reaction...

journal_title：Journal of inorganic biochemistry

authors： Savas MM,Shaw CF 3rd,Petering DH

更新日期：1993-12-01 00:00:00

abstract：:Citrate occurs at about 0.1 mM in blood plasma and is the most likely small molecule plasma binder of both Al3+ and Fe3+. This paper assesses published stability constants for citrate binding to each metal ion. From pH 2 to 5 Al3+ forms a neutral complex with citrate that may be absorbed into the body in the upper reg...

journal_title：Journal of inorganic biochemistry

authors： Martin RB

更新日期：1986-10-01 00:00:00

abstract：:Bovine calmodulin, spin-labeled at tyrosine-99, has been utilized in electron paramagnetic resonance (EPR) studies to investigate calmodulin interactions with Ca(II), Cd(II), and Mg(II). The addition of either Ca(II) or Cd(II) to apo-calmodulin results in a complex capable of activating target enzymes, such as 3', 5'-...

journal_title：Journal of inorganic biochemistry

authors： You GF,Buccigross JM,Nelson DJ

更新日期：1990-02-01 00:00:00

abstract：:Arginine 56 in the beta subunit (betaArg56) of the iron-containing nitrile hydratase (NHase), one of the strongly conserved residues within the NHase family, is known to form hydrogen bonds to the sulfinyl (-SO2H) and sulfenyl (-SOH) groups of the post-translationally modified cysteine residues in the catalytic center...

journal_title：Journal of inorganic biochemistry

authors： Piersma SR,Nojiri M,Tsujimura M,Noguchi T,Odaka M,Yohda M,Inoue Y,Endo I

更新日期：2000-07-01 00:00:00

abstract：:Vanadium compounds exert various insulin-mimetic and anti-diabetic effects both in vitro and in vivo. Vanadium(III, IV, V)-chlorodipicolinate (Vdipic-Cl) compounds, including H[V(III)(dipic-Cl)2]·5H2O (V3dipic-Cl), V(IV)O(dipic-Cl)(H2O)2 (V4dipic-Cl) and K[V(V)O2(dipic-Cl)] (V5dipic-Cl), were synthesized with the indi...

journal_title：Journal of inorganic biochemistry

authors： Xie M,Chen D,Zhang F,Willsky GR,Crans DC,Ding W

更新日期：2014-07-01 00:00:00

abstract：:Iron is frequently a growth-limiting nutrient due to its propensity to interact with oxygen to form insoluble precipitates and, therefore, biological systems have evolved specialized uptake mechanisms to obtain this essential nutrient. Many pathogenic bacteria are capable of obtaining stringently sequestered iron from...

journal_title：Journal of inorganic biochemistry

authors： Beasley FC,Heinrichs DE

更新日期：2010-03-01 00:00:00

abstract：:Aluminum, the most abundant neurotoxic metal in our biosphere, has been implicated in the etiology of several neurodegenerative disorders including Alzheimer's disease (AD). To further understand aluminum's influence on gene expression, we examined total messenger RNA levels in untransformed human neural cells exposed...

journal_title：Journal of inorganic biochemistry

authors： Lukiw WJ,Percy ME,Kruck TP

更新日期：2005-09-01 00:00:00

abstract：:N-acetylaspartate (NAA) is the one of the most prominent resonances observed in the solvent-suppressed NMR spectrum of the human brain. Although it is present in the brain at about 10 mM, its precise metabolic function is still unclear, We have examined the NAA as a potential chelator for divalent metal ions such as C...

journal_title：Journal of inorganic biochemistry

authors： Rubin Y,Connelly GP,Lenkinski RE

更新日期：1995-10-01 00:00:00

abstract：:Inhibitory effects of gold(III) ions (Au(III)) on ribonuclease A (RNase A) and deoxyribonuclease I (DNase I) were investigated at neutral pH. RNase A was completely inhibited by 3 molar equivalents of Au(III) ions. DNase I was inhibited by 10 molar equivalents of Au(III) ions. Stoichiometric analyses suggest that Au(I...

journal_title：Journal of inorganic biochemistry

authors： Maruyama T,Sonokawa S,Matsushita H,Goto M

更新日期：2007-01-01 00:00:00

abstract：:The binding and reactivity of the hydrosulfide ion (HS-) to iron(II) porphyrinates has been examined for several synthetic meso-tetraphenylporphine (TPP) derivatives. In all cases, HS- coordinates to the iron centers in a 1:1 stoichiometry with formation constants (Kf) that reflect the electronic characteristics of th...

journal_title：Journal of inorganic biochemistry

authors： Meininger DJ,Arman HD,Tonzetich ZJ

更新日期：2017-02-01 00:00:00

abstract：:Three new binuclear copper(II) complexes have been synthesized and structurally characterized by X-ray crystallography, [Cu(2)(1,4-tpbd)(dafo)(2)(MeOH)(2)](ClO(4))(4)·2.5H(2)O (1), [Cu(2)(1,4-tpbd) (DMSO)(2)(ClO(4))(2)](OH)(2)·6H(2)O (2) and [Cu(2)(1,4-tpbd)(OAC)(2)(ClO(4))(2)]·5H(2)O (3) (1,4-tpbd=N,N,N',N'-tetrakis(...

journal_title：Journal of inorganic biochemistry

authors： Li DD,Tian JL,Gu W,Liu X,Zeng HH,Yan SP

更新日期：2011-06-01 00:00:00

abstract：:The magnetic properties of intact and freeze-dried blood cells of the tunicate Ascidia nigra and of model vanadium(III) and (IV) compounds as polycrystalline solids and in aqueous solution have been measured up to 50 kOe with a SQUID susceptometer. Corrections for the samples' diamagnetism were extracted from the temp...

journal_title：Journal of inorganic biochemistry

authors： Lee S,Kustin K,Robinson WE,Frankel RB,Spartalian K

更新日期：1988-07-01 00:00:00

abstract：:Three new copper(II) complexes of stoichiometry [Cu(L-dipeptide)].nH(2)O, containing as ligands the dipeptides L-alanine-L-isoleucine, L-alanine-L-threonine and L-alanine-L-tyrosine were prepared. They were characterized by single crystal X-ray diffractometry, and electronic and infrared spectroscopy. In all cases, th...

journal_title：Journal of inorganic biochemistry

authors： Facchin G,Torre MH,Kremer E,Piro OE,Castellano EE,Baran EJ

更新日期：2002-04-28 00:00:00