Some Aspects of the Liquid Water Thermodynamic Behavior: From The Stable to the Deep Supercooled Regime.

Abstract:

:Liquid water is considered to be a peculiar example of glass forming materials because of the possibility of giving rise to amorphous phases with different densities and of the thermodynamic anomalies that characterize its supercooled liquid phase. In the present work, literature data on the density of bulk liquid water are analyzed in a wide temperature-pressure range, also including the glass phases. A careful data analysis, which was performed on different density isobars, made in terms of thermodynamic response functions, like the thermal expansion αP and the specific heat differences CP-CV, proves, exclusively from the experimental data, the thermodynamic consistence of the liquid-liquid transition hypothesis. The study confirms that supercooled bulk water is a mixture of two liquid "phases", namely the high density (HDL) and the low density (LDL) liquids that characterize different regions of the water phase diagram. Furthermore, the CP-CV isobars behaviors clearly support the existence of both a liquid-liquid transition and of a liquid-liquid critical point.

journal_name

Int J Mol Sci

authors

Mallamace F,Mensitieri G,Mallamace D,Salzano de Luna M,Chen SH

doi

10.3390/ijms21197269

subject

Has Abstract

pub_date

2020-10-01 00:00:00

issue

19

issn

1422-0067

pii

ijms21197269

journal_volume

21

pub_type

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