当前位置： SCI文献检索 > Nature Communications期刊下所有文献 > A broadly tunable synthesis of linear α-olefins.

A broadly tunable synthesis of linear α-olefins.

Abstract：

:The catalytic synthesis of linear α-olefins from ethylene is a technologically highly important reaction. A synthesis concept allowing the formation of selective products and various linear α-olefin product distributions with one catalyst system is highly desirable. Here, we describe a trimetallic catalyst system (Y-Al-Ni) consisting of a rare earth metal polymerization catalyst which can mediate coordinative chain transfer to triethylaluminum combined with a simultaneously operating nickel β-hydride elimination/transfer catalyst. This nickel catalyst displaces the grown alkyl chains forming linear α-olefins and recycles the aluminum-based chain transfer agent. With one catalyst system, we can synthesize product spectra ranging from selective 1-butene formation to α-olefin distributions centered at 850 gmol-1 with a low polydispersity. The key to this highly flexible linear α-olefin synthesis is the easy tuning of the rates of the Y and Ni catalysis independently of each other. The reaction is substoichiometric or formally catalytic regarding the chain transfer agent.

journal_name

Nat Commun

journal_title

Nature communications

authors

Gollwitzer A,Dietel T,Kretschmer WP,Kempe R

doi

10.1038/s41467-017-01507-2

subject

Has Abstract

pub_date

2017-10-31 00:00:00

pages

1226

issue

1

issn

2041-1723

pii

10.1038/s41467-017-01507-2

journal_volume

8

pub_type

杂志文章

相关文献

Nature Communications文献大全
  • Targeting VEGF-A in myeloid cells enhances natural killer cell responses to chemotherapy and ameliorates cachexia.

    abstract：:Chemotherapy remains a mainstay of cancer treatment but its use is often limited by the development of adverse reactions. Severe loss of body weight (cachexia) is a frequent cause of death in cancer patients and is exacerbated by chemotherapy. We show that genetic inactivation of vascular endothelial growth factor (VE...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms12528

    authors： Klose R,Krzywinska E,Castells M,Gotthardt D,Putz EM,Kantari-Mimoun C,Chikdene N,Meinecke AK,Schrödter K,Helfrich I,Fandrey J,Sexl V,Stockmann C

    更新日期：2016-08-19 00:00:00

  • Protein determinants of dissemination and host specificity of metallo-β-lactamases.

    abstract：:The worldwide dissemination of metallo-β-lactamases (MBLs), mediating resistance to carbapenem antibiotics, is a major public health problem. The extent of dissemination of MBLs such as VIM-2, SPM-1 and NDM among Gram-negative pathogens cannot be explained solely based on the associated mobile genetic elements or the ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-11615-w

    authors： López C,Ayala JA,Bonomo RA,González LJ,Vila AJ

    更新日期：2019-08-09 00:00:00

  • Publisher Correction: Stateful characterization of resistive switching TiO2 with electron beam induced currents.

    abstract：:The original version of this Article contained an error in Eq. 1. The arrows between the symbols "T" and "B", and "B" and "T", were written "↔" but should have been "→", and incorrectly read: IEBIC=IEBAC+ISEE+I(e↔h)+IEBICT↔B+IESEEB↔T The correct from of the Eq. 1 is as follows:IEBIC=IEBAC+ISEE+I(e↔h)+IEBICT→B+IESEEB→T...

    journal_title：Nature communications

    pub_type： 杂志文章,已发布勘误

    doi：10.1038/s41467-018-02844-6

    authors： Hoskins BD,Adam GC,Strelcov E,Zhitenev N,Kolmakov A,Strukov DB,McClelland JJ

    更新日期：2018-01-24 00:00:00

  • Solid-phase hetero epitaxial growth of α-phase formamidinium perovskite.

    abstract：:Conventional epitaxy of semiconductor films requires a compatible single crystalline substrate and precisely controlled growth conditions, which limit the price competitiveness and versatility of the process. We demonstrate substrate-tolerant nano-heteroepitaxy (NHE) of high-quality formamidinium-lead-tri-iodide (FAPb...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-19237-3

    authors： Lee JW,Tan S,Han TH,Wang R,Zhang L,Park C,Yoon M,Choi C,Xu M,Liao ME,Lee SJ,Nuryyeva S,Zhu C,Huynh K,Goorsky MS,Huang Y,Pan X,Yang Y

    更新日期：2020-11-02 00:00:00

  • Petahertz non-linear current in a centrosymmetric organic superconductor.

    abstract：:Charge acceleration during an intense light field application to solids attracts much attention as elementary processes in high-harmonic generation and photoelectron emission. For manipulating such attosecond dynamics of charge, carrier-envelope-phase (CEP: relative phase between carrier oscillation of light field and...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-17776-3

    authors： Kawakami Y,Amano T,Ohashi H,Itoh H,Nakamura Y,Kishida H,Sasaki T,Kawaguchi G,Yamamoto HM,Yamamoto K,Ishihara S,Yonemitsu K,Iwai S

    更新日期：2020-08-18 00:00:00

  • Quantitative bounds on morphodynamics and implications for reading the sedimentary record.

    abstract：:Sedimentary rocks are the archives of environmental conditions and ancient planetary surface processes that led to their formation. Reconstructions of Earth's past surface behaviour from the physical sedimentary record remain controversial, however, in part because we lack a quantitative framework to deconvolve intern...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms4298

    authors： Ganti V,Lamb MP,McElroy B

    更新日期：2014-02-28 00:00:00

  • Electron aspirator using electron-electron scattering in nanoscale silicon.

    abstract：:Current enhancement without increasing the input power is a critical issue to be pursued for electronic circuits. However, drivability of metal-oxide-semiconductor (MOS) transistors is limited by the source-injection current, and electrons that have passed through the source unavoidably waste their momentum to the pho...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-07278-8

    authors： Firdaus H,Watanabe T,Hori M,Moraru D,Takahashi Y,Fujiwara A,Ono Y

    更新日期：2018-12-17 00:00:00

  • The immunoreceptor NKG2D promotes tumour growth in a model of hepatocellular carcinoma.

    abstract：:Inflammation is recognized as one of the drivers of cancer. Yet, the individual immune components that possess pro- and anti-tumorigenic functions in individual cancers remain largely unknown. NKG2D is a potent activating immunoreceptor that has emerged as an important player in inflammatory disorders besides its well...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms13930

    authors： Sheppard S,Guedes J,Mroz A,Zavitsanou AM,Kudo H,Rothery SM,Angelopoulos P,Goldin R,Guerra N

    更新日期：2017-01-27 00:00:00

  • Author Correction: Resonant out-of-phase fluorescence microscopy and remote imaging overcome spectral limitations.

    abstract：:The Peer Review File associated with this Article was updated shortly after publication to redact from the authors' point-by-point response a description of unpublished work describing how Speed OPIOM may in future be used to facilitate discrimination between FRET and direct excitation. ...

    journal_title：Nature communications

    pub_type： 杂志文章,已发布勘误

    doi：10.1038/s41467-017-02133-8

    authors： Quérard J,Zhang R,Kelemen Z,Plamont MA,Xie X,Chouket R,Roemgens I,Korepina Y,Albright S,Ipendey E,Volovitch M,Sladitschek HL,Neveu P,Gissot L,Gautier A,Faure JD,Croquette V,Le Saux T,Jullien L

    更新日期：2017-12-14 00:00:00

  • A network-centric approach to drugging TNF-induced NF-κB signaling.

    abstract：:Target-centric drug development strategies prioritize single-target potency in vitro and do not account for connectivity and multi-target effects within a signal transduction network. Here, we present a systems biology approach that combines transcriptomic and structural analyses with live-cell imaging to predict smal...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-08802-0

    authors： Pabon NA,Zhang Q,Cruz JA,Schipper DL,Camacho CJ,Lee REC

    更新日期：2019-02-26 00:00:00

  • Evidence of depolarization and ellipticity of high harmonics driven by ultrashort bichromatic circularly polarized fields.

    abstract：:High harmonics generated by counter-rotating laser fields at the fundamental and second harmonic frequencies have raised important interest as a table-top source of circularly polarized ultrashort extreme-ultraviolet light. However, this emission has not yet been fully characterized: in particular it was assumed to be...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-07151-8

    authors： Barreau L,Veyrinas K,Gruson V,Weber SJ,Auguste T,Hergott JF,Lepetit F,Carré B,Houver JC,Dowek D,Salières P

    更新日期：2018-11-09 00:00:00

  • Confinement-deconfinement transition due to spontaneous symmetry breaking in quantum Hall bilayers.

    abstract：:Band-inverted electron-hole bilayers support quantum spin Hall insulator and exciton condensate phases. Interest in quantum spin Hall effect in these systems has recently put them in the spotlight. We investigate such a bilayer in an external magnetic field. We show that the interlayer correlations lead to formation o...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms10462

    authors： Pikulin DI,Silvestrov PG,Hyart T

    更新日期：2016-01-25 00:00:00

  • A bioinspired hydrogen bond-triggered ultrasensitive ionic mechanoreceptor skin.

    abstract：:Biological cellular structures have inspired many scientific disciplines to design synthetic structures that can mimic their functions. Here, we closely emulate biological cellular structures in a rationally designed synthetic multicellular hybrid ion pump, composed of hydrogen-bonded [EMIM+][TFSI-] ion pairs on the s...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-11973-5

    authors： Amoli V,Kim JS,Jee E,Chung YS,Kim SY,Koo J,Choi H,Kim Y,Kim DH

    更新日期：2019-09-05 00:00:00

  • Sequential growth of long DNA strands with user-defined patterns for nanostructures and scaffolds.

    abstract：:DNA strands of well-defined sequence are valuable in synthetic biology and nanostructure assembly. Drawing inspiration from solid-phase synthesis, here we describe a DNA assembly method that uses time, or order of addition, as a parameter to define structural complexity. DNA building blocks are sequentially added with...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms8065

    authors： Hamblin GD,Rahbani JF,Sleiman HF

    更新日期：2015-05-05 00:00:00

  • Copy-choice recombination during mitochondrial L-strand synthesis causes DNA deletions.

    abstract：:Mitochondrial DNA (mtDNA) deletions are associated with mitochondrial disease, and also accumulate during normal human ageing. The mechanisms underlying mtDNA deletions remain unknown although several models have been proposed. Here we use deep sequencing to characterize abundant mtDNA deletions in patients with mutat...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-08673-5

    authors： Persson Ö,Muthukumar Y,Basu S,Jenninger L,Uhler JP,Berglund AK,McFarland R,Taylor RW,Gustafsson CM,Larsson E,Falkenberg M

    更新日期：2019-02-15 00:00:00

  • Tunable multiphase dynamics of arginine and lysine liquid condensates.

    abstract：:Liquid phase separation into two or more coexisting phases has emerged as a new paradigm for understanding subcellular organization, prebiotic life, and the origins of disease. The design principles underlying biomolecular phase separation have the potential to drive the development of novel liquid-based organelles an...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-18224-y

    authors： Fisher RS,Elbaum-Garfinkle S

    更新日期：2020-09-15 00:00:00

  • Lateral orbitofrontal cortex anticipates choices and integrates prior with current information.

    abstract：:Adaptive behavior requires integrating prior with current information to anticipate upcoming events. Brain structures related to this computation should bring relevant signals from the recent past into the present. Here we report that rats can integrate the most recent prior information with sensory information, there...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms14823

    authors： Nogueira R,Abolafia JM,Drugowitsch J,Balaguer-Ballester E,Sanchez-Vives MV,Moreno-Bote R

    更新日期：2017-03-24 00:00:00

  • Hot carriers perspective on the nature of traps in perovskites.

    abstract：:Amongst the many spectacular properties of hybrid lead halide perovskites, their defect tolerance is regarded as the key enabler for a spectrum of high-performance optoelectronic devices that propel perovskites to prominence. However, the plateauing efficiency enhancement of perovskite devices calls into question the ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-16463-7

    authors： Righetto M,Lim SS,Giovanni D,Lim JWM,Zhang Q,Ramesh S,Tay YKE,Sum TC

    更新日期：2020-06-01 00:00:00

  • Author Correction: Insulin-producing organoids engineered from islet and amniotic epithelial cells to treat diabetes.

    abstract：:An amendment to this paper has been published and can be accessed via a link at the top of the paper. ...

    journal_title：Nature communications

    pub_type： 已发布勘误

    doi：10.1038/s41467-020-19127-8

    authors： Lebreton F,Lavallard V,Bellofatto K,Bonnet R,Wassmer CH,Perez L,Kalandadze V,Follenzi A,Boulvain M,Kerr-Conte J,Goodman DJ,Bosco D,Berney T,Berishvili E

    更新日期：2020-10-09 00:00:00

  • Publisher Correction: An engineered human Fc domain that behaves like a pH-toggle switch for ultra-long circulation persistence.

    abstract：:An amendment to this paper has been published and can be accessed via a link at the top of the paper. ...

    journal_title：Nature communications

    pub_type： 已发布勘误

    doi：10.1038/s41467-019-13458-x

    authors： Lee CH,Kang TH,Godon O,Watanabe M,Delidakis G,Gillis CM,Sterlin D,Hardy D,Cogné M,Macdonald LE,Murphy AJ,Tu N,Lee J,McDaniel JR,Makowski E,Tessier PM,Meyer AS,Bruhns P,Georgiou G

    更新日期：2019-11-26 00:00:00

  • Employing antineutrino detectors to safeguard future nuclear reactors from diversions.

    abstract：:The Non-Proliferation Treaty and other non-proliferation agreements are in place worldwide to ensure that nuclear material and facilities are used only for peaceful purposes. Antineutrino detectors, sensitive to reactor power and fuel changes, can complement the tools already at the disposal of international agencies ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-11434-z

    authors： Stewart C,Abou-Jaoude A,Erickson A

    更新日期：2019-08-06 00:00:00

  • High performance platinum single atom electrocatalyst for oxygen reduction reaction.

    abstract：:For the large-scale sustainable implementation of polymer electrolyte membrane fuel cells in vehicles, high-performance electrocatalysts with low platinum consumption are desirable for use as cathode material during the oxygen reduction reaction in fuel cells. Here we report a carbon black-supported cost-effective, ef...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms15938

    authors： Liu J,Jiao M,Lu L,Barkholtz HM,Li Y,Wang Y,Jiang L,Wu Z,Liu DJ,Zhuang L,Ma C,Zeng J,Zhang B,Su D,Song P,Xing W,Xu W,Wang Y,Jiang Z,Sun G

    更新日期：2017-07-24 00:00:00

  • A surface-stabilized ozonide triggers bromide oxidation at the aqueous solution-vapour interface.

    abstract：:Oxidation of bromide in aqueous environments initiates the formation of molecular halogen compounds, which is important for the global tropospheric ozone budget. In the aqueous bulk, oxidation of bromide by ozone involves a [Br•OOO-] complex as intermediate. Here we report liquid jet X-ray photoelectron spectroscopy m...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-017-00823-x

    authors： Artiglia L,Edebeli J,Orlando F,Chen S,Lee MT,Corral Arroyo P,Gilgen A,Bartels-Rausch T,Kleibert A,Vazdar M,Andres Carignano M,Francisco JS,Shepson PB,Gladich I,Ammann M

    更新日期：2017-09-26 00:00:00

  • Reduced exposure to extreme precipitation from 0.5 °C less warming in global land monsoon regions.

    abstract：:The Paris Agreement set a goal to keep global warming well below 2 °C and pursue efforts to limit it to 1.5 °C. Understanding how 0.5 °C less warming reduces impacts and risks is key for climate policies. Here, we show that both areal and population exposures to dangerous extreme precipitation events (e.g., once in 10...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-05633-3

    authors： Zhang W,Zhou T,Zou L,Zhang L,Chen X

    更新日期：2018-08-08 00:00:00

  • The structure of Zika virus NS5 reveals a conserved domain conformation.

    abstract：:The recent outbreak of Zika virus (ZIKV) has imposed a serious threat to public health. Here we report the crystal structure of the ZIKV NS5 protein in complex with S-adenosyl-L-homocysteine, in which the tandem methyltransferase (MTase) and RNA-dependent RNA polymerase (RdRp) domains stack into one of the two alterna...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms14763

    authors： Wang B,Tan XF,Thurmond S,Zhang ZM,Lin A,Hai R,Song J

    更新日期：2017-03-27 00:00:00

  • Diffusion-limited reactions in dynamic heterogeneous media.

    abstract：:Most biochemical reactions in living cells rely on diffusive search for target molecules or regions in a heterogeneous overcrowded cytoplasmic medium. Rapid rearrangements of the medium constantly change the effective diffusivity felt locally by a diffusing particle and thus impact the distribution of the first-passag...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-06610-6

    authors： Lanoiselée Y,Moutal N,Grebenkov DS

    更新日期：2018-10-23 00:00:00

  • Long-term isolation of European steppe outposts boosts the biome's conservation value.

    abstract：:The European steppes and their biota have been hypothesized to be either young remnants of the Pleistocene steppe belt or, alternatively, to represent relicts of long-term persisting populations; both scenarios directly bear on nature conservation priorities. Here, we evaluate the conservation value of threatened disj...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-15620-2

    authors： Kirschner P,Záveská E,Gamisch A,Hilpold A,Trucchi E,Paun O,Sanmartín I,Schlick-Steiner BC,Frajman B,Arthofer W,STEPPE Consortium.,Steiner FM,Schönswetter P

    更新日期：2020-04-23 00:00:00

  • Spin-orbit interaction of light induced by transverse spin angular momentum engineering.

    abstract：:The investigations on optical angular momenta and their interactions have broadened our knowledge of light's behavior at sub-wavelength scales. Recent studies further unveil the extraordinary characteristics of transverse spin angular momentum in confined light fields and orbital angular momentum in optical vortices. ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-03237-5

    authors： Shao Z,Zhu J,Chen Y,Zhang Y,Yu S

    更新日期：2018-03-02 00:00:00

  • Imaging Coulomb islands in a quantum Hall interferometer.

    abstract：:In the quantum Hall regime, near integer filling factors, electrons should only be transmitted through spatially separated edge states. However, in mesoscopic systems, electronic transmission turns out to be more complex, giving rise to a large spectrum of magnetoresistance oscillations. To explain these observations,...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms1038

    authors： Hackens B,Martins F,Faniel S,Dutu CA,Sellier H,Huant S,Pala M,Desplanque L,Wallart X,Bayot V

    更新日期：2010-07-27 00:00:00

  • Distinct homeostatic modulations stabilize reduced postsynaptic receptivity in response to presynaptic DLK signaling.

    abstract：:Synapses are constructed with the stability to last a lifetime, yet sufficiently flexible to adapt during injury. Although fundamental pathways that mediate intrinsic responses to neuronal injury have been defined, less is known about how synaptic partners adapt. We have investigated responses in the postsynaptic cell...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-04270-0

    authors： Goel P,Dickman D

    更新日期：2018-05-10 00:00:00