Abstract:
:Crystalline phase transitions caused by external stimuli have been used to detect physical changes in the solid-state properties. This study presents the mechanical switching of crystals of ferrocene-containing rotaxane controlled by focused laser light. The expansion and contraction of the crystals can be driven by turning on and off laser light at 445 nm. The irradiation-induced expansion of the crystal involves elongation along the a, b and c axes at 30 °C, whereas heating of the crystal at 105 °C causes the shortening of c axis. The expansions reversibly occur and have the advantage of a rapid relaxation (reverse) process. Single-crystal X-ray crystallography reveals the detailed structural changes of the molecules, corresponding to a change in the size of the crystals on laser irradiation. This molecular crystal behaviour induced by laser irradiation, is demonstrated for the remote control of objects, namely, microparticle transport and microswitching in an electric circuit.
journal_name
Nat Communjournal_title
Nature communicationsauthors
Chen KJ,Tsai YC,Suzaki Y,Osakada K,Miura A,Horie Mdoi
10.1038/ncomms13321subject
Has Abstractpub_date
2016-11-03 00:00:00pages
13321issn
2041-1723pii
ncomms13321journal_volume
7pub_type
杂志文章abstract::The original version of this Article contained errors in Fig. 3. In panel a, bars from a chart depicting the percentage of antibody-positive individuals in non-infectious and infectious groups were inadvertently included in place of bars depicting the percentage of infectious individuals, as described in the Article a...
journal_title:Nature communications
pub_type: 杂志文章,已发布勘误
doi:10.1038/s41467-018-03769-w
更新日期:2018-04-11 00:00:00
abstract::Around 40% of preterm births are attributed to ascending intrauterine infection, and Ureaplasma parvum (UP) is commonly isolated in these cases. Here we present a mouse model of ascending UP infection that resembles human disease, using vaginal inoculation combined with mild cervical injury induced by a common spermic...
journal_title:Nature communications
pub_type: 杂志文章
doi:10.1038/s41467-019-14089-y
更新日期:2020-01-10 00:00:00
abstract::Nascent polypeptides can induce ribosome stalling, regulating downstream genes. Stalling of ErmBL peptide translation in the presence of the macrolide antibiotic erythromycin leads to resistance in Streptococcus sanguis. To reveal this stalling mechanism we obtained 3.6-Å-resolution cryo-EM structures of ErmBL-stalled...
journal_title:Nature communications
pub_type: 杂志文章
doi:10.1038/ncomms12026
更新日期:2016-07-06 00:00:00
abstract::We currently have limited knowledge of the involvement of long non-coding RNAs (lncRNAs) in normal cellular processes and pathologies. Here, we identify and characterize SNHG5 as a stable cytoplasmic lncRNA with up-regulated expression in colorectal cancer. Depletion of SNHG5 induces cell cycle arrest and apoptosis in...
journal_title:Nature communications
pub_type: 杂志文章
doi:10.1038/ncomms13875
更新日期:2016-12-22 00:00:00
abstract::Experimental and modeling work of neural activity has described recurrent and attractor dynamic patterns in cerebral microcircuits. However, it is still poorly understood whether similar dynamic principles exist or can be generalizable to the large-scale level. Here, we applied dynamic graph theory-based analyses to e...
journal_title:Nature communications
pub_type: 杂志文章
doi:10.1038/s41467-018-06346-3
更新日期:2018-09-24 00:00:00
abstract::Following uncontrolled proliferation, a subset of primary tumour cells acquires additional traits/mutations to trigger phenotypic changes that enhance migration and are hypothesized to be the initiators of metastasis. This study reveals an adaptive mechanism that harnesses synergistic paracrine signalling via IL-6/8, ...
journal_title:Nature communications
pub_type: 杂志文章
doi:10.1038/ncomms15584
更新日期:2017-05-26 00:00:00
abstract::In carrier multiplication, the absorption of a single photon results in two or more electron-hole pairs. Quantum dots are promising materials for implementing carrier multiplication principles in real-life technologies. So far, however, most of research in this area has focused on optical studies of solution samples w...
journal_title:Nature communications
pub_type: 杂志文章
doi:10.1038/ncomms9185
更新日期:2015-09-08 00:00:00
abstract::Quintulene, a non-graphitic cycloarene with fivefold symmetry, has remained synthetically elusive due to its high molecular strain originating from its curved structure. Here we report the construction of extended quintulene, which was unambiguously characterized by mass and NMR spectroscopy. The extended quintulene r...
journal_title:Nature communications
pub_type: 杂志文章
doi:10.1038/s41467-020-17691-7
更新日期:2020-08-07 00:00:00
abstract::A Correction to this paper has been published: https://doi.org/10.1038/s41467-020-20006-5. ...
journal_title:Nature communications
pub_type: 已发布勘误
doi:10.1038/s41467-020-20006-5
更新日期:2020-11-23 00:00:00
abstract::We study spin transport in a fully hBN encapsulated monolayer-graphene van der Waals heterostructure at room temperature. A top-layer of bilayer-hBN is used as a tunnel barrier for spin-injection and detection in graphene with ferromagnetic cobalt electrodes. We report surprisingly large and bias-induced (differential...
journal_title:Nature communications
pub_type: 杂志文章
doi:10.1038/s41467-017-00317-w
更新日期:2017-08-15 00:00:00
abstract::Chaperone-mediated autophagy (CMA) is a selective mechanism for the degradation of soluble proteins in lysosomes. CMA contributes to cellular quality control and is activated as part of the cellular response to different stressors. Defective CMA has been identified in ageing and different age-related diseases. Until n...
journal_title:Nature communications
pub_type: 杂志文章
doi:10.1038/ncomms1393
更新日期:2011-07-12 00:00:00
abstract::A key challenge in the field of molecular spintronics, and for the design of single-molecule magnet-based devices in particular, is the understanding and control of the molecular coupling at the electrode interfaces. It was demonstrated for the field of molecular electronics that the characterization of the molecule-m...
journal_title:Nature communications
pub_type: 杂志文章
doi:10.1038/ncomms1953
更新日期:2012-07-17 00:00:00
abstract::Liquid crystalline phases of matter permeate nature and technology, with examples ranging from cell membranes to liquid-crystal displays. Remarkably, electronic liquid-crystal phases can exist in two-dimensional electron systems (2DES) at half Landau-level filling in the quantum Hall regime. Theory has predicted the e...
journal_title:Nature communications
pub_type: 杂志文章
doi:10.1038/s41467-017-01810-y
更新日期:2017-11-16 00:00:00
abstract::Stress granules (SG) are translationally silent sites of RNA triage induced by environmental stresses including viral infection. Here we show that HIV-1 Gag blocks SG assembly irrespective of eIF2α phosphorylation and even when SG assembly is forced by overexpression of Ras-GAP SH3 domain-binding protein (G3BP1) or TI...
journal_title:Nature communications
pub_type: 杂志文章
doi:10.1038/ncomms5819
更新日期:2014-09-17 00:00:00
abstract::Analysis of potentially interconnected residential water and energy demand is sparse. In a 1-in-10 random sample of Singapore households living in apartments, water use per capita declines over the socioeconomic distribution, whereas electricity use rises. Here I show that in this leading Asian city and tropical clima...
journal_title:Nature communications
pub_type: 杂志文章
doi:10.1038/s41467-018-07833-3
更新日期:2018-12-20 00:00:00
abstract::Irreversible phase transformation of layered structure into spinel structure is considered detrimental for most of the layered structure cathode materials. Here we report that this presumably irreversible phase transformation can be rendered to be reversible in sodium birnessite (NaxMnO2·yH2O) as a basic structural un...
journal_title:Nature communications
pub_type: 杂志文章
doi:10.1038/s41467-019-11195-9
更新日期:2019-09-02 00:00:00
abstract::In 1816, the coldest summer of the past two centuries was observed over northeastern North America and western Europe. This so-called Year Without a Summer (YWAS) has been widely attributed to the 1815 eruption of Indonesia's Mt. Tambora and was concurrent with agricultural failures and famines worldwide. To understan...
journal_title:Nature communications
pub_type: 杂志文章
doi:10.1038/s41467-017-01302-z
更新日期:2017-10-31 00:00:00
abstract::Organic-inorganic hybrid perovskites are promising candidates for the next-generation solar cells. Many efforts have been made to study their structures in the search for a better mechanistic understanding to guide the materials optimization. Here, we investigate the structure instability of the single-crystalline CH3...
journal_title:Nature communications
pub_type: 杂志文章
doi:10.1038/s41467-018-07177-y
更新日期:2018-11-15 00:00:00
abstract::Primary effusion lymphoma (PEL) is caused by Kaposi's sarcoma-associated herpesvirus. Our understanding of PEL is poor and therefore treatment strategies are lacking. To address this need, we conducted genome-wide CRISPR/Cas9 knockout screens in eight PEL cell lines. Integration with data from unrelated cancers identi...
journal_title:Nature communications
pub_type: 杂志文章
doi:10.1038/s41467-018-05506-9
更新日期:2018-08-15 00:00:00
abstract::With the rapidly growing global air traffic, the impacts of the black carbon (BC) in the aviation exhaust on climate, environment and public health are likely rising. The particle number and size distribution are crucial metrics for toxicological analysis and aerosol-cloud interactions. Here, a size-resolved BC partic...
journal_title:Nature communications
pub_type: 杂志文章
doi:10.1038/s41467-019-08491-9
更新日期:2019-02-01 00:00:00
abstract::In magnetic materials, the Pauli exclusion principle typically drives anti-alignment between electron spins on neighbouring species resulting in antiferromagnetic behaviour. Ferromagnetism exhibiting spontaneous spin alignment is a fairly rare behaviour, but once materialized is often associated with itinerant electro...
journal_title:Nature communications
pub_type: 杂志文章
doi:10.1038/ncomms7677
更新日期:2015-03-25 00:00:00
abstract::A central paradigm in conservation biology is that population bottlenecks reduce genetic diversity and population viability. In an era of biodiversity loss and climate change, understanding the determinants and consequences of bottlenecks is therefore an important challenge. However, as most studies focus on single sp...
journal_title:Nature communications
pub_type: 历史文章,杂志文章
doi:10.1038/s41467-018-06695-z
更新日期:2018-11-16 00:00:00
abstract::CRISPR-Cas immunity is at the forefront of antivirus defense in bacteria and archaea and specifically targets viruses carrying protospacers matching the spacers catalogued in the CRISPR arrays. Here, we perform deep sequencing of the CRISPRome-all spacers contained in a microbiome-associated with hyperthermophilic arc...
journal_title:Nature communications
pub_type: 杂志文章
doi:10.1038/s41467-019-13205-2
更新日期:2019-11-15 00:00:00
abstract::The rapidly increasing use of sensors throughout different research disciplines and the demand for more efficient devices with less power consumption depends critically on the emergence of new sensor materials and novel sensor concepts. Atomically thin transition metal dichalcogenides have a huge potential for sensor ...
journal_title:Nature communications
pub_type: 杂志文章
doi:10.1038/ncomms14776
更新日期:2017-03-15 00:00:00
abstract::Tradeoffs affect resource allocation during development and result in fitness consequences that drive the evolution of life history strategies. Yet despite their importance, we know little about the mechanisms underlying life history tradeoffs. Many species of Colias butterflies exhibit an alternative life history str...
journal_title:Nature communications
pub_type: 杂志文章
doi:10.1038/s41467-019-13596-2
更新日期:2019-12-17 00:00:00
abstract::Antibiotics that interfere with translation, when combined, interact in diverse and difficult-to-predict ways. Here, we explain these interactions by "translation bottlenecks": points in the translation cycle where antibiotics block ribosomal progression. To elucidate the underlying mechanisms of drug interactions bet...
journal_title:Nature communications
pub_type: 杂志文章
doi:10.1038/s41467-020-17734-z
更新日期:2020-08-11 00:00:00
abstract::Fungal polyketides display remarkable structural diversity and bioactivity, and therefore the biosynthesis and engineering of this large class of molecules is therapeutically significant. Here, we successfully recode, construct and characterize the biosynthetic pathway of bikaverin, a tetracyclic polyketide with antib...
journal_title:Nature communications
pub_type: 杂志文章
doi:10.1038/s41467-020-19984-3
更新日期:2020-12-03 00:00:00
abstract::Strategies involving metastable phases have been the basis of the design of numerous alloys, yet research on metastable high-entropy alloys is still in its infancy. In dual-phase high-entropy alloys, the combination of local chemical environments and loading-induced crystal structure changes suggests a relationship be...
journal_title:Nature communications
pub_type: 杂志文章
doi:10.1038/s41467-020-14641-1
更新日期:2020-02-11 00:00:00
abstract::The evolutionary and environmental factors that shape fungal biogeography are incompletely understood. Here, we assemble a large dataset consisting of previously generated mycobiome data linked to specific geographical locations across the world. We use this dataset to describe the distribution of fungal taxa and to l...
journal_title:Nature communications
pub_type: 杂志文章,meta分析
doi:10.1038/s41467-019-13164-8
更新日期:2019-11-13 00:00:00
abstract::Water resources are being challenged to meet domestic, agricultural, and industrial needs. To complement finite surface water supplies that are being stressed by changes in precipitation and increased demand, groundwater is increasingly being used. Sustaining groundwater use requires considering both water quantity an...
journal_title:Nature communications
pub_type: 杂志文章
doi:10.1038/s41467-018-04475-3
更新日期:2018-06-05 00:00:00