Real-space observation of spin-split molecular orbitals of adsorbed single-molecule magnets.

Abstract:

:A key challenge in the field of molecular spintronics, and for the design of single-molecule magnet-based devices in particular, is the understanding and control of the molecular coupling at the electrode interfaces. It was demonstrated for the field of molecular electronics that the characterization of the molecule-metal-interface requires the precise knowledge of the atomic environment as well as the molecular orbitals being involved in electron transport. To extend the field of molecular electronics towards molecular spintronics, it is of utmost importance to resolve the spin character of molecular orbitals interacting with ferromagnetic leads. Here we present first direct real-space images of spin-split molecular orbitals of a single-molecule magnet adsorbed on a ferromagnetic nanostructure. Moreover, we are able to determine quantitatively the magnitude of the spin-splitting as well as the charge state of the adsorbed molecule.

journal_name

Nat Commun

journal_title

Nature communications

authors

Schwöbel J,Fu Y,Brede J,Dilullo A,Hoffmann G,Klyatskaya S,Ruben M,Wiesendanger R

doi

10.1038/ncomms1953

subject

Has Abstract

pub_date

2012-07-17 00:00:00

pages

953

issn

2041-1723

pii

ncomms1953

journal_volume

3

pub_type

杂志文章
  • Publisher Correction: Hierarchical self-entangled carbon nanotube tube networks.

    abstract::The original version of this Article was missing the ORCID ID of Professor Nicola Pugno.Also in the original version of this Article, the third to last sentence of the fourth paragraph of the Results incorrectly read 'However, the stepwise addition of CNTs increases the self-entanglement and thereby the compressive st...

    journal_title:Nature communications

    pub_type: 杂志文章,已发布勘误

    doi:10.1038/s41467-017-02372-9

    authors: Schütt F,Signetti S,Krüger H,Röder S,Smazna D,Kaps S,Gorb SN,Mishra YK,Pugno NM,Adelung R

    更新日期:2018-01-09 00:00:00

  • Basement membrane damage by ROS- and JNK-mediated Mmp2 activation drives macrophage recruitment to overgrown tissue.

    abstract::Macrophages are a major immune cell type infiltrating tumors and promoting tumor growth and metastasis. To elucidate the mechanism of macrophage recruitment, we utilize an overgrowth tumor model ("undead" model) in larval Drosophila imaginal discs that are attached by numerous macrophages. Here we report that changes ...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-020-17399-8

    authors: Diwanji N,Bergmann A

    更新日期:2020-07-20 00:00:00

  • Configurable topological textures in strain graded ferroelectric nanoplates.

    abstract::Topological defects in matter behave collectively to form highly non-trivial structures called topological textures that are characterised by conserved quantities such as the winding number. Here we show that an epitaxial ferroelectric square nanoplate of bismuth ferrite subjected to a large strain gradient (as much a...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-017-02813-5

    authors: Kim KE,Jeong S,Chu K,Lee JH,Kim GY,Xue F,Koo TY,Chen LQ,Choi SY,Ramesh R,Yang CH

    更新日期:2018-01-26 00:00:00

  • Assessing technical performance in differential gene expression experiments with external spike-in RNA control ratio mixtures.

    abstract::There is a critical need for standard approaches to assess, report and compare the technical performance of genome-scale differential gene expression experiments. Here we assess technical performance with a proposed standard 'dashboard' of metrics derived from analysis of external spike-in RNA control ratio mixtures. ...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms6125

    authors: Munro SA,Lund SP,Pine PS,Binder H,Clevert DA,Conesa A,Dopazo J,Fasold M,Hochreiter S,Hong H,Jafari N,Kreil DP,Łabaj PP,Li S,Liao Y,Lin SM,Meehan J,Mason CE,Santoyo-Lopez J,Setterquist RA,Shi L,Shi W,Smyth GK,

    更新日期:2014-09-25 00:00:00

  • Promoted cobalt metal catalysts suitable for the production of lower olefins from natural gas.

    abstract::Due to the surge of natural gas production, feedstocks for chemicals shift towards lighter hydrocarbons, particularly methane. The success of a Gas-to-Chemicals process via synthesis gas (CO and H2) depends on the ability of catalysts to suppress methane and carbon dioxide formation. We designed a Co/Mn/Na/S catalyst,...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-018-08019-7

    authors: Xie J,Paalanen PP,van Deelen TW,Weckhuysen BM,Louwerse MJ,de Jong KP

    更新日期:2019-01-11 00:00:00

  • Strong confinement-induced engineering of the g factor and lifetime of conduction electron spins in Ge quantum wells.

    abstract::Control of electron spin coherence via external fields is fundamental in spintronics. Its implementation demands a host material that accommodates the desirable but contrasting requirements of spin robustness against relaxation mechanisms and sizeable coupling between spin and orbital motion of the carriers. Here, we ...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms13886

    authors: Giorgioni A,Paleari S,Cecchi S,Vitiello E,Grilli E,Isella G,Jantsch W,Fanciulli M,Pezzoli F

    更新日期:2016-12-21 00:00:00

  • An autonomous DNA nanomachine maps spatiotemporal pH changes in a multicellular living organism.

    abstract::Structural DNA nanotechnology seeks to build synthetic molecular machinery from DNA. DNA nanomachines are artificially designed assemblies that switch between defined conformations in response to an external cue. Though it has proved possible to create DNA machines and rudimentary walkers, the function of such autonom...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms1340

    authors: Surana S,Bhat JM,Koushika SP,Krishnan Y

    更新日期:2011-06-07 00:00:00

  • Integrating an electrically active colloidal quantum dot photodiode with a graphene phototransistor.

    abstract::The realization of low-cost photodetectors with high sensitivity, high quantum efficiency, high gain and fast photoresponse in the visible and short-wave infrared remains one of the challenges in optoelectronics. Two classes of photodetectors that have been developed are photodiodes and phototransistors, each of them ...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms11954

    authors: Nikitskiy I,Goossens S,Kufer D,Lasanta T,Navickaite G,Koppens FH,Konstantatos G

    更新日期:2016-06-17 00:00:00

  • The AAA + ATPase TorsinA polymerizes into hollow helical tubes with 8.5 subunits per turn.

    abstract::TorsinA is an ER-resident AAA + ATPase, whose deletion of glutamate E303 results in the genetic neuromuscular disease primary dystonia. TorsinA is an unusual AAA + ATPase that needs an external activator. Also, it likely does not thread a peptide substrate through a narrow central channel, in contrast to its closest s...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-11194-w

    authors: Demircioglu FE,Zheng W,McQuown AJ,Maier NK,Watson N,Cheeseman IM,Denic V,Egelman EH,Schwartz TU

    更新日期:2019-07-22 00:00:00

  • FLOWERING LOCUS C in monocots and the tandem origin of angiosperm-specific MADS-box genes.

    abstract::MADS-domain transcription factors have been shown to act as key repressors or activators of the transition to flowering and as master regulators of reproductive organ identities. Despite their important roles in plant development, the origin of several MADS-box subfamilies has remained enigmatic so far. Here we demons...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms3280

    authors: Ruelens P,de Maagd RA,Proost S,Theißen G,Geuten K,Kaufmann K

    更新日期:2013-01-01 00:00:00

  • Bio-inspired self-shaping ceramics.

    abstract::Shaping ceramics into complex and intricate geometries using cost-effective processes is desirable in many applications but still remains an open challenge. Inspired by plant seed dispersal units that self-fold on differential swelling, we demonstrate that self-shaping can be implemented in ceramics by programming the...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms13912

    authors: Bargardi FL,Le Ferrand H,Libanori R,Studart AR

    更新日期:2016-12-23 00:00:00

  • CircAnks1a in the spinal cord regulates hypersensitivity in a rodent model of neuropathic pain.

    abstract::Circular RNAs are non-coding RNAs, and are enriched in the CNS. Dorsal horn neurons of the spinal cord contribute to pain-like hypersensitivity after nerve injury in rodents. Here we show that spinal nerve ligation is associated with an increase in expression of circAnks1a in dorsal horn neurons, in both the cytoplasm...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-12049-0

    authors: Zhang SB,Lin SY,Liu M,Liu CC,Ding HH,Sun Y,Ma C,Guo RX,Lv YY,Wu SL,Xu T,Xin WJ

    更新日期:2019-09-11 00:00:00

  • Arctic-Eurasian climate linkage induced by tropical ocean variability.

    abstract::Eurasian continent has experienced cold winters over the past two decades in contrast with Arctic warming. Previous studies have suggested that the cold Eurasian winters are associated with Arctic sea-ice loss, while others attributed them to atmospheric internal variability. However, here we show that the Arctic and ...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-11359-7

    authors: Matsumura S,Kosaka Y

    更新日期:2019-08-01 00:00:00

  • Genomic analysis on pygmy hog reveals extensive interbreeding during wild boar expansion.

    abstract::Wild boar (Sus scrofa) drastically colonized mainland Eurasia and North Africa, most likely from East Asia during the Plio-Pleistocene (2-1Mya). In recent studies, based on genome-wide information, it was hypothesized that wild boar did not replace the species it encountered, but instead exchanged genetic materials wi...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-10017-2

    authors: Liu L,Bosse M,Megens HJ,Frantz LAF,Lee YL,Irving-Pease EK,Narayan G,Groenen MAM,Madsen O

    更新日期:2019-04-30 00:00:00

  • Stripe-like nanoscale structural phase separation in superconducting BaPb(1-x)Bi(x)O3.

    abstract::The phase diagram of BaPb(1-x)Bi(x)O3 exhibits a superconducting dome in the proximity of a charge density wave phase. For the superconducting compositions, the material coexists as two structural polymorphs. Here we show, via high-resolution transmission electron microscopy, that the structural dimorphism is accommod...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms9231

    authors: Giraldo-Gallo P,Zhang Y,Parra C,Manoharan HC,Beasley MR,Geballe TH,Kramer MJ,Fisher IR

    更新日期:2015-09-16 00:00:00

  • Emergent electric field control of phase transformation in oxide superlattices.

    abstract::Electric fields can transform materials with respect to their structure and properties, enabling various applications ranging from batteries to spintronics. Recently electrolytic gating, which can generate large electric fields and voltage-driven ion transfer, has been identified as a powerful means to achieve electri...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-020-14631-3

    authors: Yi D,Wang Y,van ʼt Erve OMJ,Xu L,Yuan H,Veit MJ,Balakrishnan PP,Choi Y,N'Diaye AT,Shafer P,Arenholz E,Grutter A,Xu H,Yu P,Jonker BT,Suzuki Y

    更新日期:2020-02-14 00:00:00

  • Simple non-fused electron acceptors for efficient and stable organic solar cells.

    abstract::The flexibility in structural design of organic semiconductors endows organic solar cells (OSCs) not only great function-tunabilities, but also high potential toward practical application. In this work, simple non-fused-ring electron acceptors are developed through two-step synthesis from single aromatic units for con...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-10098-z

    authors: Yu ZP,Liu ZX,Chen FX,Qin R,Lau TK,Yin JL,Kong X,Lu X,Shi M,Li CZ,Chen H

    更新日期:2019-05-14 00:00:00

  • eIF6 coordinates insulin sensitivity and lipid metabolism by coupling translation to transcription.

    abstract::Insulin regulates glycaemia, lipogenesis and increases mRNA translation. Cells with reduced eukaryotic initiation factor 6 (eIF6) do not increase translation in response to insulin. The role of insulin-regulated translation is unknown. Here we show that reduction of insulin-regulated translation in mice heterozygous f...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms9261

    authors: Brina D,Miluzio A,Ricciardi S,Clarke K,Davidsen PK,Viero G,Tebaldi T,Offenhäuser N,Rozman J,Rathkolb B,Neschen S,Klingenspor M,Wolf E,Gailus-Durner V,Fuchs H,Hrabe de Angelis M,Quattrone A,Falciani F,Biffo S

    更新日期:2015-09-18 00:00:00

  • Femtosecond electron imaging of defect-modulated phonon dynamics.

    abstract::Precise manipulation and control of coherent lattice oscillations via nanostructuring and phonon-wave interference has the potential to significantly impact a broad array of technologies and research areas. Resolving the dynamics of individual phonons in defect-laden materials presents an enormous challenge, however, ...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms11230

    authors: Cremons DR,Plemmons DA,Flannigan DJ

    更新日期:2016-04-15 00:00:00

  • Leptin receptor-expressing neuron Sh2b1 supports sympathetic nervous system and protects against obesity and metabolic disease.

    abstract::Leptin stimulates the sympathetic nervous system (SNS), energy expenditure, and weight loss; however, the underlying molecular mechanism remains elusive. Here, we uncover Sh2b1 in leptin receptor (LepR) neurons as a critical component of a SNS/brown adipose tissue (BAT)/thermogenesis axis. LepR neuron-specific deletio...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-020-15328-3

    authors: Jiang L,Su H,Wu X,Shen H,Kim MH,Li Y,Myers MG Jr,Owyang C,Rui L

    更新日期:2020-03-23 00:00:00

  • Host-targeted niclosamide inhibits C. difficile virulence and prevents disease in mice without disrupting the gut microbiota.

    abstract::Clostridium difficile is the leading cause of nosocomial diarrhea and colitis in the industrialized world. Disruption of the protective gut microbiota by antibiotics enables colonization by multidrug-resistant C. difficile, which secrete up to three different protein toxins that are responsible for the gastrointestina...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-018-07705-w

    authors: Tam J,Hamza T,Ma B,Chen K,Beilhartz GL,Ravel J,Feng H,Melnyk RA

    更新日期:2018-12-07 00:00:00

  • CD8+ T cells stimulate Na-Cl co-transporter NCC in distal convoluted tubules leading to salt-sensitive hypertension.

    abstract::Recent studies suggest a role for T lymphocytes in hypertension. However, whether T cells contribute to renal sodium retention and salt-sensitive hypertension is unknown. Here we demonstrate that T cells infiltrate into the kidney of salt-sensitive hypertensive animals. In particular, CD8+ T cells directly contact the...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms14037

    authors: Liu Y,Rafferty TM,Rhee SW,Webber JS,Song L,Ko B,Hoover RS,He B,Mu S

    更新日期:2017-01-09 00:00:00

  • De novo compartment deconvolution and weight estimation of tumor samples using DECODER.

    abstract::Tumors are mixtures of different compartments. While global gene expression analysis profiles the average expression of all compartments in a sample, identifying the specific contribution of each compartment remains a challenge. With the increasing recognition of the importance of non-neoplastic components, the abilit...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-12517-7

    authors: Peng XL,Moffitt RA,Torphy RJ,Volmar KE,Yeh JJ

    更新日期:2019-10-18 00:00:00

  • The genetic regulatory signature of type 2 diabetes in human skeletal muscle.

    abstract::Type 2 diabetes (T2D) results from the combined effects of genetic and environmental factors on multiple tissues over time. Of the >100 variants associated with T2D and related traits in genome-wide association studies (GWAS), >90% occur in non-coding regions, suggesting a strong regulatory component to T2D risk. Here...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms11764

    authors: Scott LJ,Erdos MR,Huyghe JR,Welch RP,Beck AT,Wolford BN,Chines PS,Didion JP,Narisu N,Stringham HM,Taylor DL,Jackson AU,Vadlamudi S,Bonnycastle LL,Kinnunen L,Saramies J,Sundvall J,Albanus RD,Kiseleva A,Hensley J,Cr

    更新日期:2016-06-29 00:00:00

  • Recent summer warming in northwestern Canada exceeds the Holocene thermal maximum.

    abstract::Eastern Beringia is one of the few Western Arctic regions where full Holocene climate reconstructions are possible. However, most full Holocene reconstructions in Eastern Beringia are based either on pollen or midges, which show conflicting early Holocene summer temperature histories. This discrepancy precludes unders...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-09622-y

    authors: Porter TJ,Schoenemann SW,Davies LJ,Steig EJ,Bandara S,Froese DG

    更新日期:2019-04-09 00:00:00

  • A new interhemispheric teleconnection increases predictability of winter precipitation in southwestern US.

    abstract::Reliable prediction of seasonal precipitation in the southwestern US (SWUS) remains a challenge with significant implications for the economy, water security and ecosystem management of the region. Winter precipitation in the SWUS has been linked to several climate modes, including the El Niño-Southern Oscillation (EN...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-018-04722-7

    authors: Mamalakis A,Yu JY,Randerson JT,AghaKouchak A,Foufoula-Georgiou E

    更新日期:2018-06-13 00:00:00

  • Mechanically interlocked 3D multi-material micromachines.

    abstract::Metals and polymers are dissimilar materials in terms of their physicochemical properties, but complementary in terms of functionality. As a result, metal-organic structures can introduce a wealth of novel applications in small-scale robotics. However, current fabrication techniques are unable to process three-dimensi...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-020-19725-6

    authors: Alcântara CCJ,Landers FC,Kim S,De Marco C,Ahmed D,Nelson BJ,Pané S

    更新日期:2020-11-24 00:00:00

  • Genome-wide association study identifies the SERPINB gene cluster as a susceptibility locus for food allergy.

    abstract::Genetic factors and mechanisms underlying food allergy are largely unknown. Due to heterogeneity of symptoms a reliable diagnosis is often difficult to make. Here, we report a genome-wide association study on food allergy diagnosed by oral food challenge in 497 cases and 2387 controls. We identify five loci at genome-...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-017-01220-0

    authors: Marenholz I,Grosche S,Kalb B,Rüschendorf F,Blümchen K,Schlags R,Harandi N,Price M,Hansen G,Seidenberg J,Röblitz H,Yürek S,Tschirner S,Hong X,Wang X,Homuth G,Schmidt CO,Nöthen MM,Hübner N,Niggemann B,Beyer K,Lee

    更新日期:2017-10-20 00:00:00

  • Long-range exciton transport and slow annihilation in two-dimensional hybrid perovskites.

    abstract::Two-dimensional hybrid organic-inorganic perovskites with strongly bound excitons and tunable structures are desirable for optoelectronic applications. Exciton transport and annihilation are two key processes in determining device efficiencies; however, a thorough understanding of these processes is hindered by that a...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-020-14403-z

    authors: Deng S,Shi E,Yuan L,Jin L,Dou L,Huang L

    更新日期:2020-01-31 00:00:00

  • Backmapping triangulated surfaces to coarse-grained membrane models.

    abstract::Many biological processes involve large-scale changes in membrane shape. Computer simulations of these processes are challenging since they occur across a wide range of spatiotemporal scales that cannot be investigated in full by any single current simulation technique. A potential solution is to combine different lev...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-020-16094-y

    authors: Pezeshkian W,König M,Wassenaar TA,Marrink SJ

    更新日期:2020-05-08 00:00:00