当前位置： SCI文献检索 > INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES期刊下所有文献 > Role of Thermal Process on Self-Assembled Structures of 4'-([2,2':6',2''-Terpyridin]-4'-Yl)-[1,1'-Biphenyl]-4-Carboxylic Acid on Au(III).

Role of Thermal Process on Self-Assembled Structures of 4'-([2,2':6',2''-Terpyridin]-4'-Yl)-[1,1'-Biphenyl]-4-Carboxylic Acid on Au(III).

Abstract：

:The role of dynamic processes on self-assembled structures of 4'-([2,2':6', 2''-terpyridin]-4'-yl)-[1,1'-biphenyl]-4-carboxylic acid (l) molecules on Au(III) has been studied by scanning tunneling microscopy. The as-deposited monolayer is closed-packed and periodic in a short-range due to dipole forces. A thermal annealing process at 110 degrees drives such disordered monolayer into ordered chain-like structures, determined by the combination of the dipole forces and hydrogen bonding. Further annealing at 130 degrees turns the whole monolayer into a bowknot-like structure in which hydrogen bonding plays the dominant role in the formation of assembled structures. Such dependence of an assembled structure on the process demonstrates that an assembled structure can be regulated and controlled not only by the molecular structure but also by the thermal process to form the assembled structure.

journal_name

Int J Mol Sci

journal_title

International journal of molecular sciences

authors

Liu X,Wang Y,Song X,Chen F,Ouyang H,Zhang X,Cai Y,Liu X,Wang L

doi

10.3390/ijms14035686

subject

Has Abstract

pub_date

2013-03-11 00:00:00

pages

5686-93

issue

3

issn

1422-0067

pii

ijms14035686

journal_volume

14

pub_type

杂志文章

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