Accumulation of explosives in hair--Part 3: Binding site study.

Abstract:

:This study extends previous work on the sorption of explosives to the hair matrix. Specifically, we have studied the interaction of 2,4,6-trinitrotoluene (TNT) and triacetone triperoxide (TATP) as a function of chemical pretreatment with acetonitrile, neutral and alkaline hydrogen peroxide, methanolic KOH and potassium permanganate, and the morphological changes that accompany these treatments. While differences in vapor pressure can account for quantitative differences between TNT and TATP sorption, both are markedly affected by the chemical rinses. Examination of the hair surface shows different degrees of smoothening following rinsing, suggesting that the attachment to hair is largely a surface phenomenon involving the 18-methyleicosanoic acid lipid layer. Density functional theory calculations were employed to explore possible nucleation sites of TATP microcrystals on the hair. We conclude that some of the sites on melanin granular surfaces may support nucleation of TATP microcrystals. Moreover, the calculations support the experimental finding that dark hair adsorbs explosives better than light hair.

journal_name

J Forensic Sci

authors

Oxley JC,Smith JL,Kirschenbaum LJ,Marimiganti S,Efremenko I,Zach R,Zeiri Y

doi

10.1111/j.1556-4029.2011.02020.x

subject

Has Abstract

pub_date

2012-05-01 00:00:00

pages

623-35

issue

3

eissn

0022-1198

issn

1556-4029

journal_volume

57

pub_type

杂志文章
  • Sexual dimorphism in America: geometric morphometric analysis of the craniofacial region.

    abstract::One of the four pillars of the anthropological protocol is the estimation of sex. The protocol generally consists of linear metric analysis or visually assessing individual skeletal traits on the skull and pelvis based on an ordinal scale of 1-5, ranging from very masculine to very feminine. The morphologic traits are...

    journal_title:Journal of forensic sciences

    pub_type: 杂志文章

    doi:10.1111/j.1556-4029.2007.00627.x

    authors: Kimmerle EH,Ross A,Slice D

    更新日期:2008-01-01 00:00:00

  • A simple computer-assisted quantification of contrast in a fingerprint.

    abstract::A simple method for quantification of contrast in a fingerprint is proposed. Contrast is defined as the average difference in intensity of pixels between valleys and ridges in a fingerprint. It is quantified from a scanner-acquired image of the fingerprint using a histogram function of Adobe Photoshop. The method was ...

    journal_title:Journal of forensic sciences

    pub_type: 杂志文章

    doi:10.1111/1556-4029.12224

    authors: Matuszewski S,Szafałowicz M

    更新日期:2013-09-01 00:00:00

  • Systematic differences in electropherogram peak heights reported by different versions of the GeneScan software.

    abstract::DNA profiling using STRs on the 310 and 3100 Genetic Analyzers routinely generates electropherograms that are analyzed with the GeneScan software available from the instrument's manufacturer, Applied Biosystems. Users have been able to choose from three different smoothing options that have been known to result in sig...

    journal_title:Journal of forensic sciences

    pub_type: 杂志文章

    doi:

    authors: Gilder JR,Ford S,Doom TE,Raymer ML,Krane DE

    更新日期:2004-01-01 00:00:00

  • Comparison of two methods for isolating DNA from human skeletal remains for STR analysis.

    abstract::The quality and efficiency of a standard organic DNA isolation method and a silica-based method using the QIAGEN Blood Maxi Kit were compared to obtain human DNA and short tandem repeats (STRs) profiles from 39 exhumed bone samples for paternity testing. DNA samples were quantified by real-time PCR, and STR profiles w...

    journal_title:Journal of forensic sciences

    pub_type: 杂志文章

    doi:10.1111/j.1556-4029.2011.02012.x

    authors: Rucinski C,Malaver AL,Yunis EJ,Yunis JJ

    更新日期:2012-05-01 00:00:00

  • Genotypic polymorphisms at seventeen autosomal short tandem repeat loci in four tribal populations of Andhra Pradesh, India.

    abstract::Four tribal populations of Andhra Pradesh, South India (1), Chenchu (n=100), Lambadi (n=107), Naikpod Gond (n=104) and Yerukula (n=101) were analyzed for DNA polymorphisms at 15 tetranucleotide and 2 pentanucleotide short tandem repeat (STR) loci in the present study. ...

    journal_title:Journal of forensic sciences

    pub_type: 杂志文章

    doi:

    authors: Bindu GH,Trivedi R,Kashyap VK

    更新日期:2005-07-01 00:00:00

  • Severe Retinal Hemorrhages with Retinoschisis in Infants are Not Pathognomonic for Abusive Head Trauma.

    abstract::The combination of subdural hemorrhage (SDH), retinal hemorrhage (RH), and encephalopathy, or the presence of severe retinal hemorrhages alone in infants, is often attributed to and has been stated to be pathognomonic for abusive head trauma (AHT) or shaken baby syndrome. These beliefs have been challenged, because th...

    journal_title:Journal of forensic sciences

    pub_type:

    doi:10.1111/1556-4029.13336

    authors: Shuman MJ,Hutchins KD

    更新日期:2017-05-01 00:00:00

  • Quantitative analysis of the morphological changes of the pubic symphyseal face and the auricular surface and implications for age at death estimation.

    abstract::Age estimation methods are often based on the age-related morphological changes of the auricular surface and the pubic bone. In this study, a mathematical approach to quantify these changes has been tested analyzing the curvature variation on 3D models from CT and laser scans. The sample consisted of the 24 Suchey-Bro...

    journal_title:Journal of forensic sciences

    pub_type: 杂志文章

    doi:10.1111/1556-4029.12689

    authors: Villa C,Buckberry J,Cattaneo C,Frohlich B,Lynnerup N

    更新日期:2015-05-01 00:00:00

  • Collection of Wet-Origin Footwear Impressions on Various Surfaces Using an Electrostatic Dust Print Lifter.

    abstract::Electrostatic dust print lift method is known to be able to recover only dry-origin footwear impression. However, the wet-origin footwear impression could also be recovered using this method. As the amount of dust accumulated before deposition of the wet-origin footwear impression increased, the intensity of the footw...

    journal_title:Journal of forensic sciences

    pub_type: 杂志文章

    doi:10.1111/1556-4029.13743

    authors: Hong S,Park M

    更新日期:2018-09-01 00:00:00

  • A Test of the DSP Sexing Method on CT Images from a Modern French Sample.

    abstract::The hip bone is considered to be one of the most reliable indicators in sex determination. The aim of this study was to test the reliability of the DSP method for the hip bone proposed by Murail et al. (Bull Mem Soc Anthropol Paris, 17, 2005, 167) on a sample from a present-day population in France (52 males and 54 fe...

    journal_title:Journal of forensic sciences

    pub_type: 杂志文章

    doi:10.1111/1556-4029.12817

    authors: Mestekova S,Bruzek J,Veleminska J,Chaumoitre K

    更新日期:2015-09-01 00:00:00

  • Digital dental radiographic identification in the pediatric, mixed and permanent dentitions.

    abstract::The purpose of this paper is to investigate the utility of digital dental radiographic superimposition in the various stages of development of the human dentition. Digital, computer assisted dental identification is a means of identification which allows the spatial relationships of the root and support structures of ...

    journal_title:Journal of forensic sciences

    pub_type: 杂志文章

    doi:

    authors: Wood RE,Kirk NJ,Sweet DJ

    更新日期:1999-09-01 00:00:00

  • Post-mortem Iris Decomposition and its Dynamics in Morgue Conditions.

    abstract::With increasing interest in employing iris biometrics as a forensic tool for identification by investigation authorities, there is a need for a thorough examination and understanding of postmortem decomposition processes that take place within the human eyeball, especially the iris. This can prove useful for fast and ...

    journal_title:Journal of forensic sciences

    pub_type: 杂志文章

    doi:10.1111/1556-4029.14488

    authors: Trokielewicz M,Czajka A,Maciejewicz P

    更新日期:2020-09-01 00:00:00

  • The role of mobile computed tomography in mass fatality incidents.

    abstract::Mobile multi-detector computed tomography (MDCT) scanners are potentially available to temporary mortuaries and can be operational within 20 min of arrival. We describe, to our knowledge, the first use of mobile MDCT for a mass fatality incident. A mobile MDCT scanner attended the disaster mortuary after a five vehicl...

    journal_title:Journal of forensic sciences

    pub_type: 杂志文章

    doi:10.1111/j.1556-4029.2007.00548.x

    authors: Rutty GN,Robinson CE,BouHaidar R,Jeffery AJ,Morgan B

    更新日期:2007-11-01 00:00:00

  • Some difficulties in the Gustafson dental age estimations.

    abstract::The Gustafson technique was a significant contribution to forensic identification. Unfortunately, many statistical errors were present in the published articles. It now seems clear that greater precision can be achieved through modification of the original technique. One of the authors (W. R. M.) will report soon on m...

    journal_title:Journal of forensic sciences

    pub_type: 杂志文章

    doi:

    authors: Maples WR,Rice PM

    更新日期:1979-01-01 00:00:00

  • Identification of the heme compound copurified with deoxyribonucleic acid (DNA) from bloodstains, a major inhibitor of polymerase chain reaction (PCR) amplification.

    abstract::The heme compound found in deoxyribonucleic acid (DNA) extracted from bloodstains, which is regarded as a major inhibitor of polymerase chain reaction (PCR), was characterized in comparison with alkaline and acid hematin, histidine and ammonia hemochromogens, and globin and serum albumin hemochromogens digested by pro...

    journal_title:Journal of forensic sciences

    pub_type: 杂志文章

    doi:

    authors: Akane A,Matsubara K,Nakamura H,Takahashi S,Kimura K

    更新日期:1994-03-01 00:00:00

  • Preparing samples for the recording of infrared spectra from synthetic fibers.

    abstract::An improved technique for recording infrared spectra from minute amounts of synthetic fibers by using KBr micropellets is described. The procedure is the same for all commonly encountered synthetic fiber varieties; hence, no preliminary identification is required. ...

    journal_title:Journal of forensic sciences

    pub_type: 杂志文章

    doi:

    authors: Grieve MC,Kearns JA

    更新日期:1976-04-01 00:00:00

  • A semiautomated radioimmunoassay for mass screening of drugs of abuse.

    abstract::A rapid, semiautomated radioimmunoassay system for detection of morphine, barbiturates, and amphetamines is described. The assays are applicable to large drug abuse screening programs. The heart of the system is the automatic pipetting station which can accomplish 600 pipetting operations per hour. The method uses 15 ...

    journal_title:Journal of forensic sciences

    pub_type: 杂志文章

    doi:

    authors: Sulkowski TS,Lathrop GD,Merritt JH,Landez JH,Noe ER

    更新日期:1975-07-01 00:00:00

  • Dangerous information: product tampering and poisoning advice in revenge and murder manuals.

    abstract::This paper reviews 18 publications that advocate the use of product tampering and other poisoning methods as techniques for exacting revenge against individuals and corporations, as methods of committing murder, and for other criminal purposes. Several of the particular techniques recommended in these publications sub...

    journal_title:Journal of forensic sciences

    pub_type: 杂志文章,评审

    doi:

    authors: Dietz PE

    更新日期:1988-09-01 00:00:00

  • Mastoid triangle for sex determination in adult Nigerian population: a validation study.

    abstract::In the quest for a simple, reliable technique to estimate the sex of human remains several novel metric skeletal indices have been reported. Only a few have been examined for utility in populations different from those in which they were developed. In this study, the mastoid process was evaluated for sex determination...

    journal_title:Journal of forensic sciences

    pub_type: 杂志文章

    doi:10.1111/1556-4029.12299

    authors: Jaja BN,Ajua CO,Didia BC

    更新日期:2013-11-01 00:00:00

  • An unusual case of multiple-gunshot suicide of an alcohol-intoxicated cancer sufferer with prolonged physical activity.

    abstract::Multishot firearm suicides are relatively rare and suggest the possibility of homicide. Physical activity following gunshots to the head, the neck, and the thorax does occur, and immediate incapacitation does not occur in every fatal gunshot wound that penetrates the head or perforates the heart. Cancer patients appea...

    journal_title:Journal of forensic sciences

    pub_type: 杂志文章

    doi:10.1111/1556-4029.12073

    authors: Marnerides A,Zagelidou E,Leontari R

    更新日期:2013-03-01 00:00:00

  • Development of latent fingermarks from rocks and stones.

    abstract::Since the beginning of recorded history, stones have been used in the commission of crimes due to their widespread availability. Stones can be used as a lethal weapon that sometimes might be the only evidence in a serious case. The common perception, even in professional fingermark circles, is that stones do not yield...

    journal_title:Journal of forensic sciences

    pub_type: 杂志文章

    doi:10.1111/1556-4029.12438

    authors: Hefetz I,Cohen A,Cohen Y,Chaikovsky A

    更新日期:2014-09-01 00:00:00

  • The determination of cocaine and its major metabolite, benzoylecgonine, in postmortem fluids and tissues by computerized gas chromatography/mass spectrometry.

    abstract::An analytical procedure for the simultaneous determination of both cocaine and benzoylecgonine in postmortem fluid and tissue samples has been developed by using computerized gas chromatography/mass spectrometry and gas chromatography using a nitrogen/phosphorus (N/P) detector. Both methods are accurate and sensitive ...

    journal_title:Journal of forensic sciences

    pub_type: 杂志文章

    doi:

    authors: Griesemer EC,Liu Y,Budd RD,Raftogianis L,Noguchi TT

    更新日期:1983-10-01 00:00:00

  • Fatal blunt trauma of the larynx in a child.

    abstract::We report an autopsy case of an 11-year-old girl who suffered mechanical asphyxia from falling off the metal bars in the playground. This autopsy case is interesting because of the atypical trauma and lesions. To our knowledge there has been no similiar published case reports in the forensic literature. The young age ...

    journal_title:Journal of forensic sciences

    pub_type: 杂志文章

    doi:

    authors: Durak D,Fedakar R,Eren B,Saka E,Durak VA

    更新日期:2005-09-01 00:00:00

  • Reliability of the acid phosphatase test for the identification of seminal fluid.

    abstract::Data from 100 cases of alleged rape victims demonstrate why the author believes the AP test to be a reliable tool, when employed by an expert for the identification of seminal fluid. ...

    journal_title:Journal of forensic sciences

    pub_type: 杂志文章

    doi:

    authors: Schiff AF

    更新日期:1978-10-01 00:00:00

  • The reliability of digitized radiographs for dental identification: a Web-based study.

    abstract::In the era of Daubert and other judicial rulings pertaining to the acceptability of forensic evidence, it is increasingly important that experts are able to testify that their methods have been scientifically tested and that error rates and other factors relating to reliability have been published. The purpose of this...

    journal_title:Journal of forensic sciences

    pub_type: 杂志文章

    doi:

    authors: Pretty IA,Pretty RJ,Rothwell BR,Sweet D

    更新日期:2003-11-01 00:00:00

  • Postmortem concentrations of citalopram.

    abstract::The postmortem concentrations of citalopram in blood, bile, liver, and vitreous humour were investigated in 14 cases using a specially developed high performance liquid chromatography assay. Concentrations from drug and non-drug related deaths were categorized to determine a postmortem therapeutic and toxic range. The...

    journal_title:Journal of forensic sciences

    pub_type: 杂志文章

    doi:

    authors: Anastos N,McIntyre IM,Lynch MJ,Drummer OH

    更新日期:2002-07-01 00:00:00

  • Case of Fatal Starvation: Can Stable Isotope Analysis Serve to Support Morphological Diagnosis and Approximate the Length of Starvation?

    abstract::The diagnosis of death as a result of starvation is established on anthropological measurements, visual appearance of the deceased on external and internal examination, microscopic analysis, laboratory testing, and exclusion of other causes of death. Herein, we present our findings on a case of 95-year-old man who die...

    journal_title:Journal of forensic sciences

    pub_type:

    doi:10.1111/1556-4029.13244

    authors: Baković M,Vreča P,Mayer D

    更新日期:2017-01-01 00:00:00

  • Feigning Hand Preference? A Case Report Preliminary Data.

    abstract::Hand preference may be crucial in the forensic domain, notably in cases where the assailant is known to be left-handed and the defendant claims to be right-handed (or vice versa). In such cases, forensic psychologists or physicians may be asked to test the hand preference of the defendant. However, hand preference may...

    journal_title:Journal of forensic sciences

    pub_type:

    doi:10.1111/1556-4029.13923

    authors: Merckelbach H,Jelicic M

    更新日期:2019-05-01 00:00:00

  • Virtual autopsy and forensic identification-practical application: a report of one case.

    abstract::The body of an unidentified elderly woman was found trapped in a floodgate. Prior to autopsy, full-body multislice computed tomography (MSCT) was performed for study of bone lesions and cause of death. Age was estimated by analysis of the sternal end of the fourth rib and of the pubic symphyseal medial articular surfa...

    journal_title:Journal of forensic sciences

    pub_type: 杂志文章

    doi:10.1111/j.1556-4029.2007.00475.x

    authors: Dedouit F,Telmon N,Guilbeau-Frugier C,Gainza D,Otal P,Joffre F,Rougé D

    更新日期:2007-07-01 00:00:00

  • AMPFlSTR Identifiler STR allele frequencies in Tanzania, Africa.

    abstract:POPULATION:Identifiler-Employees and students of Muhimibili University College of Health Sciences in Dar es Salaam representing 19 widely distributed administrative districts and 42 tribes within the country. ...

    journal_title:Journal of forensic sciences

    pub_type: 杂志文章

    doi:10.1111/j.1556-4029.2007.00640.x

    authors: Forward BW,Eastman MW,Nyambo TB,Ballard RE

    更新日期:2008-01-01 00:00:00

  • Characterization of deoxyribonucleic acid (DNA) obtained from teeth subjected to various environmental conditions.

    abstract::This study was designed to determine the effects of various environmental factors on the deoxyribonucleic acid (DNA) obtained from dental pulp. Extracted teeth were subjected to the following conditions: varying pH (3,7,10); temperature (4 degrees C, 25 degrees C, 37 degrees C, incineration); humidity (20%, 66%, 98%);...

    journal_title:Journal of forensic sciences

    pub_type: 杂志文章

    doi:

    authors: Schwartz TR,Schwartz EA,Mieszerski L,McNally L,Kobilinsky L

    更新日期:1991-07-01 00:00:00