DNA Binding and Antitumor Activity of α-Diimineplatinum(II) and Palladium(II) Dithiocarbamate Complexes.

abstract：:The toxicity mechanisms of mercury and tin organic derivatives are still under debate. Generally the presence of organic moieties in their molecules makes these compounds lipophilic and membrane active species. The recent results suggest that Hg and Sn compounds deplete HS-groups in proteins, glutathione and glutathio...

journal_title：Bioinorganic chemistry and applications

authors： Milaeva E,Petrosyan V,Berberova N,Pimenov Y,Pellerito L

更新日期：2004-01-01 00:00:00

abstract：:The complex [ReOCl(3)pq] (1) (where pq = 2-(2'pyridyl)quinoxaline) has been synthesized and fully characterized by UV-Vis, FTIR, 1 and 2D NMR, and cyclic voltammetry (CV). The DNA-binding properties of the complex 1 as well as of the compounds [ReOCl(3)bpy] (2), [ReOCl(3)phen] (3), and pq (4) were investigated by UV-s...

journal_title：Bioinorganic chemistry and applications

authors： Mitsopoulou CA,Dagas C

更新日期：2010-01-01 00:00:00

abstract：:Rice husk is an abundant agricultural by-product reaching the output of 80 million tons annually in the world. The most common treatment method of rice husk is burning or burying, which caused serious air pollution and resource waste. In order to solve this problem, a new method is proposed to comprehensively utilize ...

journal_title：Bioinorganic chemistry and applications

authors： Zhang H,Ding X,Wang Z,Zhao X

更新日期：2014-01-01 00:00:00

abstract：:The influences of chondroitin sulfate C (C6S) on size, aggregation, sedimentation, and Zeta potential of sub-micron calcium oxalate monohydrate (COM) and calcium oxalate dihydrate (COD) crystallites with mean sizes of about 330 nm were investigated using an X-ray diffractometer, nanoparticle size Zeta potential analyz...

journal_title：Bioinorganic chemistry and applications

authors： Li JJ,Xue JF,Ouyang JM

更新日期：2013-01-01 00:00:00

abstract：:Dry films of platinum chemotherapeutic drugs covalently bound to plasmid DNA (Pt-DNA) represent a useful experimental model to investigate direct effects of radiation on DNA in close proximity to platinum chemotherapeutic agents, a situation of considerable relevance to understand the mechanisms underlying concomitant...

journal_title：Bioinorganic chemistry and applications

authors： Rezaee M,Alizadeh E,Hunting D,Sanche L

更新日期：2012-01-01 00:00:00

abstract：:A series of perimidine derivatives (L1-5) were prepared and characterized by IR, 1H·NMR, mass spectroscopy, UV-Vis, XRD, thermal, and SEM analysis. Five VO(II) complexes were synthesized and investigated by most previous tools besides the theoretical usage. A neutral tetradentate mode of bonding is the general approac...

journal_title：Bioinorganic chemistry and applications

authors： Al-Hazmi GA,Abou-Melha KS,El-Metwaly NM,Saleh KA

更新日期：2018-09-06 00:00:00

abstract：:N-substituted pyridine hydrazide (pyridine-2-carbonyl chloride and 4-chloro-benzoic acid hydrazide) undergoes hydrazide formation of the iminic carbon nitrogen double bond through its reaction with cobalt(II), nickel(II), and copper(II) metal salts in ethanol which are reported and characterized based on elemental ana...

journal_title：Bioinorganic chemistry and applications

authors： Singh J,Singh P

更新日期：2012-01-01 00:00:00

abstract：:Two oxovanadium(IV) complexes of [VO(msatsc)(phen)], (1) (msatsc = methoxylsalicylaldehyde thiosemicarbazone, phen = phenanthroline) and its novel derivative [VO (4-chlorosatsc)(phen)], (2) (4-chlorosatsc = 4-chlorosalicylaldehyde thiosemicarbazone), have been synthesized and characterized by elemental analysis, IR, E...

journal_title：Bioinorganic chemistry and applications

authors： Zhang Y,Wang X,Fang W,Cai X,Chu F,Liao X,Lu J

更新日期：2013-01-01 00:00:00

abstract：:In this study, we describe novel gallium(III), germanium(IV), and hafnium(IV) folate complexes, including their synthesis and analyses. The synthesized folate complexes were also subject to thermal analysis (TGA) to better examine their thermal degradation and kinetic properties. The folate complexes had high stabilit...

journal_title：Bioinorganic chemistry and applications

authors： El-Habeeb AA

更新日期：2020-12-18 00:00:00

abstract：:Terminally protected pentapeptides with 2 histidines (Ac-HHVGD-NH(2) and Ac-HVGDH-NH(2)) and the terminally free peptides containing both internal aspartyl and C-terminal histidyl residues (FDAH and VIDAH) have been synthesized, and copper(II) complexes studied by potentiometric, UV-Vis, CD, and EPR spectroscopic tech...

journal_title：Bioinorganic chemistry and applications

authors： Kállay C,Nagy Z,Várnagy K,Malandrinos G,Hadjiliadis N,Sóvágó I

更新日期：2007-01-01 00:00:00

abstract：:It is important to develop functional transmucosal implant surfaces that reduce the number of initially adhering bacteria and they need to be modified to improve the anti-bacterial performance. Commercially pure Ti sheets were anodized in an electrolyte containing ethylene glycol, distilled water and ammonium fluoride...

journal_title：Bioinorganic chemistry and applications

authors： Yeniyol S,He Z,Yüksel B,Boylan RJ,Urgen M,Ozdemir T,Ricci JL

更新日期：2014-01-01 00:00:00

abstract：:The thermodynamic equilibria of nickel(II) with N,N'-di(aminoethylene)-2,6-pyridinedicarbonylamine (L1), Bis-(N,N-dimethylethyl)-2,6-pyridinedicarboxamide (L2), and N,N'-bis[2(2-pyridyl)-methyl]pyridine-2,6-dicarboxamide (L3) have been studied at 25°C and an ionic strength of 0.15 mol dm(-3) by glass electrode potenti...

journal_title：Bioinorganic chemistry and applications

authors： Odisitse S,Jackson GE

更新日期：2014-01-01 00:00:00

abstract：:Terpolymer of 2-amino-6-nitro-benzothiazole-ethylenediamine-formaldehyde (BEF) has been synthesized and characterized by elemental analysis and various spectral techniques like FTIR, UV-Visible, and (1)H and (13)C-NMR. The terpolymer metal complexes were prepared with Cu(2+), Ni(2+), and Zn(2+) metal ions using BEF te...

journal_title：Bioinorganic chemistry and applications

authors： Riswan Ahamed MA,Azarudeen RS,Kani NM

更新日期：2014-01-01 00:00:00

abstract：:Three hexacoordinated octahedral nickel(II) complexes, [Ni(sal-L-phe)(phen)(CH3OH)]·CH3OH (1), [Ni(naph-L-phe)(phen)(CH3OH)] (2), and [Ni(o-van-L-phe)(phen)(CH3OH)]·5CH3OH (3) (sal-L-phe = a Schiff base derived from salicylaldehyde and L-phenylalanine, naph-L-phe = a Schiff base derived from 2-hydroxy-1-naphthaldehyde...

journal_title：Bioinorganic chemistry and applications

authors： Zhao P,Zhai S,Dong J,Gao L,Liu X,Wang L,Kong J,Li L

更新日期：2018-07-05 00:00:00

abstract：:The incorporation of benzene-l,2-dithiolato building blocks into supramolecular coordination assemblies is the main objective of the investigations described here. Special interest is directed towards dinuclear complexes with bis(benzene-l,2-dithiolato) ligands, which might be able to form helical structures. Bis(benz...

journal_title：Bioinorganic chemistry and applications

authors： Seidel WW,Hahn FE

更新日期：2005-01-01 00:00:00

abstract：:Antifertility and histopathological investigations were carried out on reproductive organs of male albino rats induced by tetraazamacrocyclic complexes of iron(II). The complexes were synthesized by the template condensation of 1,2-diaminoethane, 1,3-diaminopropane with succinic acid and phthalic acid in 2 : 2 molar r...

journal_title：Bioinorganic chemistry and applications

authors： Chaudhary A,Singh RV

更新日期：2006-01-01 00:00:00

abstract：:The chemical design of metal complexes of the type [Cu(phen)(antib)](+) (where antib is a quinolone or a fluoroquinolone) has been carried out in an approach to better understand how the coordination of their components affect the activity of quinolones. The ability of [Cu(phen)(nal)](+) to interact with DNA in vivo a...

journal_title：Bioinorganic chemistry and applications

authors： Ramírez-Ramírez N,Mendoza-Díaz G,Pedraza-Reyes M

更新日期：2003-01-01 00:00:00

abstract：:In this work we present a structural and spectroscopic analysis of a copper(II) N-acetyl-5-arylidene tetramic acid by using both experimental and computational techniques. The crystal structure of the Cu(II) complex was determined by single crystal X-ray diffraction and shows that the copper ion lies on a centre of sy...

journal_title：Bioinorganic chemistry and applications

authors： Matiadis D,Tsironis D,Stefanou V,Igglessi-Markopoulou O,McKee V,Sanakis Y,Lazarou KN,Chrissanthopoulos A,Yannopoulos SN,Markopoulos JM

更新日期：2017-01-01 00:00:00

abstract：:The synthesis and characterization of a novel ligand, bis[(2-ethyl-5-methyl-imidazo-4-yl)methyl]sulfide (bemims), as well as a bemims-containing copper(II) coordination complex are described. In this complex, [Cu(bemims)X(2)] with X = NO(3) (-), bemims acts as a tridentate ligand and two monodentate nitrate ions compl...

journal_title：Bioinorganic chemistry and applications

authors： Barrón-Garcés JD,Mendoza-Díaz G,Vilchez-Aguado F,Bernès S

更新日期：2009-01-01 00:00:00

abstract：:Hemoglobin- (Hb-) based oxygen carriers (HBOC) have for several decades been explored for treatment of hemorrhage. In our previous top-up tests, HBOC with lower in vitro prooxidant reactivity (incorporating a peroxidase or serum albumin to this end) showed a measurable but small improvement of oxidative stress-related...

journal_title：Bioinorganic chemistry and applications

authors： Farcas AD,Toma VA,Roman I,Sevastre B,Scurtu F,Silaghi-Dumitrescu R

更新日期：2020-09-01 00:00:00

abstract：:New complexes of manganese(II) corresponding to [{(ArO)2PS2}2Mn] and [{(ArO)2PS2}2Mn.nL] (Ar = o-, m-, p-CH3C6H4 and p-Cl-m-CH3C6H3; n = 1, L = N2C12H8, N2C10H8; n = 2, L = NC5H5, P(C6H5)3) have been synthesized and characterized by microelemental analyses (C, H, and N), magnetic susceptibility, molar conductance, the...

journal_title：Bioinorganic chemistry and applications

authors： Khajuria R,Syed A,Kumar S,Pandey SK

更新日期：2013-01-01 00:00:00

abstract：:Mn peroxidase has been purified to homogeneity from the culture filtrate of a new fungal strain Fomes durissimus MTCC-1173 using concentration by ultrafiltration and anion exchange chromatography on diethylaminoethyl (DEAE) cellulose. The molecular mass of the purified enzyme has been found to be 42.0 kDa using SDS-PA...

journal_title：Bioinorganic chemistry and applications

authors： Singh SK,Yadav M,Yadava S,Yadav KD

更新日期：2011-01-01 00:00:00

abstract：:Water disinfection has attracted the attention of scientists worldwide due to water scarcity. The most significant challenges are determining how to achieve proper disinfection without producing harmful byproducts obtained usually using conventional chemical disinfectants and developing new point-of-use methods for th...

journal_title：Bioinorganic chemistry and applications

authors： Al-Hakami SM,Khalil AB,Laoui T,Atieh MA

更新日期：2013-01-01 00:00:00

abstract：Background:Sustained return of spontaneous circulation (ROSC) can be initially established in patients with out-of-hospital cardiac arrest (OHCA); however, the early postresuscitation hemodynamics can still be impaired by high levels of serum potassium (hyperkalemia). The impact of different potassium levels on early p...

journal_title：Bioinorganic chemistry and applications

authors： Lin YR,Syue YJ,Lee TH,Chou CC,Chang CF,Li CJ

更新日期：2018-04-05 00:00:00

abstract：:A partially fluorine substituted hydroxyapatite- (FHA-) coated Mg-Zn alloy was prepared to investigate the interfacial behavior of degradable Mg-based biomaterials with degradable bioactive coatings in a cell culture environment. Peaks from the results of X-ray diffraction (XRD) were characterized and compared before ...

journal_title：Bioinorganic chemistry and applications

authors： Li J,Cao L,Song Y,Zhang S,Zhao C,Zhang F,Zhang X

更新日期：2011-01-01 00:00:00

abstract：:Four pyrazolone derivatives and their corresponding silver complexes were synthesized and characterized. Based on elemental analysis, 1 : 2 (M : L) molar ratio was suggested for all inspected complexes. 1H, 13C NMR, mass, UV-Vis, TGA, and IR were the spectral tools used for describing the formulae. Moreover, XRD patte...

journal_title：Bioinorganic chemistry and applications

authors： Althagafi I,El-Metwaly NM,Elghalban MG,Farghaly TA,Khedr AM

更新日期：2018-05-14 00:00:00

abstract：:The synthetic, spectroscopic, and biological studies of sixteen ring-substituted 4-phenylthiosemicarbazones and 4-nitrophenyl-thiosemicarbazones of anisaldehyde, 4-chlorobenzaldehyde, 4-fluorobenzaldehyde, and vanillin with ruthenium(III) and rhodium(III) chlorides are reported here. Their structures were determined o...

journal_title：Bioinorganic chemistry and applications

authors： Sharma VK,Srivastava S,Srivastava A

更新日期：2007-01-01 00:00:00

abstract：:Fish and marine mammal consumption are an important pathway for human exposure to mercury. The low mercury content in shellfish poses a low mercury health risk to people who consume shellfish. The objectives of this study are to detect mercury concentrations in different species of shellfish and to calculate the mercu...

journal_title：Bioinorganic chemistry and applications

authors： Zhang L,Zhang L

更新日期：2015-01-01 00:00:00

abstract：:The zinc(II) complex (C2H6NS)2Zn·ZnCl2 was synthesized with 2-aminoethanethiol hydrochloride and zinc sulfate heptahydrate as the raw materials in aqueous solution. The composition and structure of the complex were characterized by elemental analysis, infrared spectra, single crystal X-ray diffraction, and thermogravi...

journal_title：Bioinorganic chemistry and applications

authors： Shu XG,Wu CL,Li CJ,Zhang M,Wan K,Wu X

更新日期：2016-01-01 00:00:00

abstract：:Biosorption experiment from aqueous solutions containing known amount of rare earth elements (REEs) using pre-treated Buccinum tenuissimum shell was explored to evaluate the efficiency of shell biomass as sorbent for REEs. In this work, four kinds of sieved shell samples: (a) "Ground original sample", (b) "Heat-treatm...

journal_title：Bioinorganic chemistry and applications

authors： Koto Y,Kano N,Wang Y,Sakamoto N,Imaizumi H

更新日期：2010-01-01 00:00:00