Chances and limits of the coordination chemistry with bis(benzene-l,2-dithiolato) ligands.

abstract：:Four pyrazolone derivatives and their corresponding silver complexes were synthesized and characterized. Based on elemental analysis, 1 : 2 (M : L) molar ratio was suggested for all inspected complexes. 1H, 13C NMR, mass, UV-Vis, TGA, and IR were the spectral tools used for describing the formulae. Moreover, XRD patte...

journal_title：Bioinorganic chemistry and applications

authors： Althagafi I,El-Metwaly NM,Elghalban MG,Farghaly TA,Khedr AM

更新日期：2018-05-14 00:00:00

abstract：:In this study, we describe novel gallium(III), germanium(IV), and hafnium(IV) folate complexes, including their synthesis and analyses. The synthesized folate complexes were also subject to thermal analysis (TGA) to better examine their thermal degradation and kinetic properties. The folate complexes had high stabilit...

journal_title：Bioinorganic chemistry and applications

authors： El-Habeeb AA

更新日期：2020-12-18 00:00:00

abstract：:The chemical design of metal complexes of the type [Cu(phen)(antib)](+) (where antib is a quinolone or a fluoroquinolone) has been carried out in an approach to better understand how the coordination of their components affect the activity of quinolones. The ability of [Cu(phen)(nal)](+) to interact with DNA in vivo a...

journal_title：Bioinorganic chemistry and applications

authors： Ramírez-Ramírez N,Mendoza-Díaz G,Pedraza-Reyes M

更新日期：2003-01-01 00:00:00

abstract：:Terpolymer of 2-amino-6-nitro-benzothiazole-ethylenediamine-formaldehyde (BEF) has been synthesized and characterized by elemental analysis and various spectral techniques like FTIR, UV-Visible, and (1)H and (13)C-NMR. The terpolymer metal complexes were prepared with Cu(2+), Ni(2+), and Zn(2+) metal ions using BEF te...

journal_title：Bioinorganic chemistry and applications

authors： Riswan Ahamed MA,Azarudeen RS,Kani NM

更新日期：2014-01-01 00:00:00

abstract：:Rice husk is an abundant agricultural by-product reaching the output of 80 million tons annually in the world. The most common treatment method of rice husk is burning or burying, which caused serious air pollution and resource waste. In order to solve this problem, a new method is proposed to comprehensively utilize ...

journal_title：Bioinorganic chemistry and applications

authors： Zhang H,Ding X,Wang Z,Zhao X

更新日期：2014-01-01 00:00:00

abstract：:Two oxovanadium(IV) complexes of [VO(msatsc)(phen)], (1) (msatsc = methoxylsalicylaldehyde thiosemicarbazone, phen = phenanthroline) and its novel derivative [VO (4-chlorosatsc)(phen)], (2) (4-chlorosatsc = 4-chlorosalicylaldehyde thiosemicarbazone), have been synthesized and characterized by elemental analysis, IR, E...

journal_title：Bioinorganic chemistry and applications

authors： Zhang Y,Wang X,Fang W,Cai X,Chu F,Liao X,Lu J

更新日期：2013-01-01 00:00:00

abstract：:The zinc(II) complex (C2H6NS)2Zn·ZnCl2 was synthesized with 2-aminoethanethiol hydrochloride and zinc sulfate heptahydrate as the raw materials in aqueous solution. The composition and structure of the complex were characterized by elemental analysis, infrared spectra, single crystal X-ray diffraction, and thermogravi...

journal_title：Bioinorganic chemistry and applications

authors： Shu XG,Wu CL,Li CJ,Zhang M,Wan K,Wu X

更新日期：2016-01-01 00:00:00

abstract：:The thermodynamic equilibria of nickel(II) with N,N'-di(aminoethylene)-2,6-pyridinedicarbonylamine (L1), Bis-(N,N-dimethylethyl)-2,6-pyridinedicarboxamide (L2), and N,N'-bis[2(2-pyridyl)-methyl]pyridine-2,6-dicarboxamide (L3) have been studied at 25°C and an ionic strength of 0.15 mol dm(-3) by glass electrode potenti...

journal_title：Bioinorganic chemistry and applications

authors： Odisitse S,Jackson GE

更新日期：2014-01-01 00:00:00

abstract：:Heterobimetallic complexes of Zn(II) and Sn(IV) with sarcosine have been synthesized at room temperature under stirring conditions by the reaction of sarcosine and zinc acetate in 2 : 1 molar ratio followed by the stepwise addition of CS2 and organotin(IV) halides, where R = Me, n-Bu, and Ph. The complexes were charac...

journal_title：Bioinorganic chemistry and applications

authors： Arafat Y,Ali S,Shahzadi S,Shahid M

更新日期：2013-01-01 00:00:00

abstract：:In vivo radionuclide generators make complex combinations of physical and chemical properties available for medical diagnostics and therapy. Perhaps the best-known in vivo generator is 212Pb/212Bi, which takes advantage of the extended half-life of 212Pb to execute a targeted delivery of the therapeutic short-lived α-...

journal_title：Bioinorganic chemistry and applications

authors： Edem PE,Fonslet J,Kjær A,Herth M,Severin G

更新日期：2016-01-01 00:00:00

abstract：:The complex [ReOCl(3)pq] (1) (where pq = 2-(2'pyridyl)quinoxaline) has been synthesized and fully characterized by UV-Vis, FTIR, 1 and 2D NMR, and cyclic voltammetry (CV). The DNA-binding properties of the complex 1 as well as of the compounds [ReOCl(3)bpy] (2), [ReOCl(3)phen] (3), and pq (4) were investigated by UV-s...

journal_title：Bioinorganic chemistry and applications

authors： Mitsopoulou CA,Dagas C

更新日期：2010-01-01 00:00:00

abstract：:The highly water-soluble ruthenium complex [Ru(H(2)L)Cl(2)](2)H(2)o, in which H(4)L is the sequestering ligand trans-l, 2-cyclohexanediamminetetraacetic acid (cdta) has been synthesized, structurally characterized and its properties studied. The X-ray crystallographic study shows that the chelating coordinated ligand ...

journal_title：Bioinorganic chemistry and applications

authors： Vilaplana RA,Castiñeiras A,González-Vílchez F

更新日期：2004-01-01 00:00:00

abstract：:Biosorption experiment from aqueous solutions containing known amount of rare earth elements (REEs) using pre-treated Buccinum tenuissimum shell was explored to evaluate the efficiency of shell biomass as sorbent for REEs. In this work, four kinds of sieved shell samples: (a) "Ground original sample", (b) "Heat-treatm...

journal_title：Bioinorganic chemistry and applications

authors： Koto Y,Kano N,Wang Y,Sakamoto N,Imaizumi H

更新日期：2010-01-01 00:00:00

abstract：:Dental care is an essential phenomenon in human health. Oral pathogens can cause severe break which may show the way to serious issues in human disease like blood circulation and coronary disease. In the current study, we demonstrated the synthesis and antimicrobial activity of cadmium sulphide and zinc sulphide nanop...

journal_title：Bioinorganic chemistry and applications

authors： Malarkodi C,Rajeshkumar S,Paulkumar K,Vanaja M,Gnanajobitha G,Annadurai G

更新日期：2014-01-01 00:00:00

abstract：:A number of penta- and hexacoordinated organotin(IV) complexes and tetracoordinated tin(II) complexes of compositions Me2SnCl[RCOC:CON(C6H5)N:CCH3] (where R = - CH(3), -p-ClC(6)H(4), and -C(6)H(5)), Me2Sn[RCOC:CON(C6H5)N:CCH3]2 (where R = -CH(3), and -C(6)H(5)), and Sn(II) [RCOC:CON(C6H5)N:CCH3]2 (where R = -p-ClC(6)H...

journal_title：Bioinorganic chemistry and applications

authors： Jain A,Saxena S,Rai AK,Saxena PN

更新日期：2006-01-01 00:00:00

abstract：:New complexes of manganese(II) corresponding to [{(ArO)2PS2}2Mn] and [{(ArO)2PS2}2Mn.nL] (Ar = o-, m-, p-CH3C6H4 and p-Cl-m-CH3C6H3; n = 1, L = N2C12H8, N2C10H8; n = 2, L = NC5H5, P(C6H5)3) have been synthesized and characterized by microelemental analyses (C, H, and N), magnetic susceptibility, molar conductance, the...

journal_title：Bioinorganic chemistry and applications

authors： Khajuria R,Syed A,Kumar S,Pandey SK

更新日期：2013-01-01 00:00:00

abstract：:Dry films of platinum chemotherapeutic drugs covalently bound to plasmid DNA (Pt-DNA) represent a useful experimental model to investigate direct effects of radiation on DNA in close proximity to platinum chemotherapeutic agents, a situation of considerable relevance to understand the mechanisms underlying concomitant...

journal_title：Bioinorganic chemistry and applications

authors： Rezaee M,Alizadeh E,Hunting D,Sanche L

更新日期：2012-01-01 00:00:00

abstract：:The synthetic, spectroscopic, and biological studies of sixteen ring-substituted 4-phenylthiosemicarbazones and 4-nitrophenyl-thiosemicarbazones of anisaldehyde, 4-chlorobenzaldehyde, 4-fluorobenzaldehyde, and vanillin with ruthenium(III) and rhodium(III) chlorides are reported here. Their structures were determined o...

journal_title：Bioinorganic chemistry and applications

authors： Sharma VK,Srivastava S,Srivastava A

更新日期：2007-01-01 00:00:00

abstract：:1,2-Bis(4-pyridyl)ethane (bpa) and 1,2-bis(4-pyridyl)ethene (bpe) were used for the synthesis of polynuclear silver(I) complexes, {[Ag(bpa)]NO3}n (1), {[Ag(bpa)2]CF3SO3.H2O}n (2) and {[Ag(bpe)]CF3SO3}n (3). In complexes 1-3, the corresponding nitrogen-containing heterocycle acts as a bridging ligand between two Ag(I) ...

journal_title：Bioinorganic chemistry and applications

authors： Đurić SŽ,Vojnovic S,Andrejević TP,Stevanović NL,Savić ND,Nikodinovic-Runic J,Glišić BĐ,Djuran MI

更新日期：2020-04-14 00:00:00

abstract：:Marine biofilms formed due to adhesion of bacteria and other microorganisms on submerged surfaces are generally considered to be a major form of microfouling. Subsequent attachment of larvae of higher organisms like barnacles, mussels, and so forth, on marine biofilms, causes macrofouling. Several approaches have been...

journal_title：Bioinorganic chemistry and applications

authors： Nithya Deva Krupa A,Raghavan V

更新日期：2014-01-01 00:00:00

abstract：:Platelet activation has been reported to play a major role in arterial thrombosis, cancer metastasis, and progression. Recently, we developed a novel Ir(III)-based compound, [Ir(Cp∗)1-(2-pyridyl)-3-(4-dimethylaminophenyl)imidazo[1,5-a]pyridine Cl]BF4 or Ir-6 and assessed its effectiveness as an antiplatelet drug. Ir-6...

journal_title：Bioinorganic chemistry and applications

authors： Shyu RS,Khamrang T,Sheu JR,Hsia CW,Velusamy M,Hsia CH,Chou DS,Chang CC

更新日期：2018-05-02 00:00:00

abstract：:Three hexacoordinated octahedral nickel(II) complexes, [Ni(sal-L-phe)(phen)(CH3OH)]·CH3OH (1), [Ni(naph-L-phe)(phen)(CH3OH)] (2), and [Ni(o-van-L-phe)(phen)(CH3OH)]·5CH3OH (3) (sal-L-phe = a Schiff base derived from salicylaldehyde and L-phenylalanine, naph-L-phe = a Schiff base derived from 2-hydroxy-1-naphthaldehyde...

journal_title：Bioinorganic chemistry and applications

authors： Zhao P,Zhai S,Dong J,Gao L,Liu X,Wang L,Kong J,Li L

更新日期：2018-07-05 00:00:00

abstract：:Fish and marine mammal consumption are an important pathway for human exposure to mercury. The low mercury content in shellfish poses a low mercury health risk to people who consume shellfish. The objectives of this study are to detect mercury concentrations in different species of shellfish and to calculate the mercu...

journal_title：Bioinorganic chemistry and applications

authors： Zhang L,Zhang L

更新日期：2015-01-01 00:00:00

abstract：:The adsorption of bixin in aprotic solvents onto acid- and alkali-treated kaolinite was investigated. Kaolinite was treated three times, for 6 h each, with 8 M HCl or 5 M KOH. The adsorbents were characterized by XRD, FT-IR, EDS, and BET-N2. The effects of contact time and dye concentration on adsorption capacity and ...

journal_title：Bioinorganic chemistry and applications

authors： Rahmalia W,Fabre JF,Usman T,Mouloungui Z

更新日期：2018-01-18 00:00:00

abstract：:Changes in the expression of microRNAs can affect cancer cells' viability and behavior and the impact on cancer treatment. In this study, the expression of miR-155-5p, miR-203a-3p, and miR-223-3p in the MCF7 cancer cell line was studied when exposed to ZnO nanoparticles synthesized through a green route. Mentioned ZnO...

journal_title：Bioinorganic chemistry and applications

authors： Aalami AH,Mesgari M,Sahebkar A

更新日期：2020-11-20 00:00:00

abstract：:Terminally protected pentapeptides with 2 histidines (Ac-HHVGD-NH(2) and Ac-HVGDH-NH(2)) and the terminally free peptides containing both internal aspartyl and C-terminal histidyl residues (FDAH and VIDAH) have been synthesized, and copper(II) complexes studied by potentiometric, UV-Vis, CD, and EPR spectroscopic tech...

journal_title：Bioinorganic chemistry and applications

authors： Kállay C,Nagy Z,Várnagy K,Malandrinos G,Hadjiliadis N,Sóvágó I

更新日期：2007-01-01 00:00:00

abstract：:Hemoglobin- (Hb-) based oxygen carriers (HBOC) have for several decades been explored for treatment of hemorrhage. In our previous top-up tests, HBOC with lower in vitro prooxidant reactivity (incorporating a peroxidase or serum albumin to this end) showed a measurable but small improvement of oxidative stress-related...

journal_title：Bioinorganic chemistry and applications

authors： Farcas AD,Toma VA,Roman I,Sevastre B,Scurtu F,Silaghi-Dumitrescu R

更新日期：2020-09-01 00:00:00

abstract：:DNA binding and photocleavage characteristics of a series of mixed ligand complexes of the type [M(bpy)(2)qbdp](PF(6))(n).xH(2)O (where M = Co(III) or Ni(II), bpy = 2.2'-bipryidine, qbdp = Quinolino[3,2-b]benzodiazepine, n = 3 or 2 and x = 5 or 2) have been investigated. The DNA binding property of the complexes with ...

journal_title：Bioinorganic chemistry and applications

authors： Prabhakara MC,Basavaraju B,Naik HS

更新日期：2007-01-01 00:00:00

abstract：:A series of perimidine derivatives (L1-5) were prepared and characterized by IR, 1H·NMR, mass spectroscopy, UV-Vis, XRD, thermal, and SEM analysis. Five VO(II) complexes were synthesized and investigated by most previous tools besides the theoretical usage. A neutral tetradentate mode of bonding is the general approac...

journal_title：Bioinorganic chemistry and applications

authors： Al-Hazmi GA,Abou-Melha KS,El-Metwaly NM,Saleh KA

更新日期：2018-09-06 00:00:00

abstract：:N-substituted pyridine hydrazide (pyridine-2-carbonyl chloride and 4-chloro-benzoic acid hydrazide) undergoes hydrazide formation of the iminic carbon nitrogen double bond through its reaction with cobalt(II), nickel(II), and copper(II) metal salts in ethanol which are reported and characterized based on elemental ana...

journal_title：Bioinorganic chemistry and applications

authors： Singh J,Singh P

更新日期：2012-01-01 00:00:00