Synthesis, Spectroscopic Characterization, and In Vitro Antimicrobial Studies of Pyridine-2-Carboxylic Acid N'-(4-Chloro-Benzoyl)-Hydrazide and Its Co(II), Ni(II), and Cu(II) Complexes.

abstract：:In vivo radionuclide generators make complex combinations of physical and chemical properties available for medical diagnostics and therapy. Perhaps the best-known in vivo generator is 212Pb/212Bi, which takes advantage of the extended half-life of 212Pb to execute a targeted delivery of the therapeutic short-lived α-...

journal_title：Bioinorganic chemistry and applications

authors： Edem PE,Fonslet J,Kjær A,Herth M,Severin G

更新日期：2016-01-01 00:00:00

abstract：:Recent developments in the understanding of the molecular control of iron homeostasis provided novel insights into the mechanisms responsible for normal iron balance. However in chronic anemias associated with iron overload, such mechanisms are no longer sufficient to offer protection from iron toxicity, and iron chel...

journal_title：Bioinorganic chemistry and applications

authors： Hershko C,Abrahamov A,Konijn AM,Breuer W,Cabantchik IZ,Pootrakul P,Link G

更新日期：2003-01-01 00:00:00

abstract：:The highly water-soluble ruthenium complex [Ru(H(2)L)Cl(2)](2)H(2)o, in which H(4)L is the sequestering ligand trans-l, 2-cyclohexanediamminetetraacetic acid (cdta) has been synthesized, structurally characterized and its properties studied. The X-ray crystallographic study shows that the chelating coordinated ligand ...

journal_title：Bioinorganic chemistry and applications

authors： Vilaplana RA,Castiñeiras A,González-Vílchez F

更新日期：2004-01-01 00:00:00

abstract：:1,2-Bis(4-pyridyl)ethane (bpa) and 1,2-bis(4-pyridyl)ethene (bpe) were used for the synthesis of polynuclear silver(I) complexes, {[Ag(bpa)]NO3}n (1), {[Ag(bpa)2]CF3SO3.H2O}n (2) and {[Ag(bpe)]CF3SO3}n (3). In complexes 1-3, the corresponding nitrogen-containing heterocycle acts as a bridging ligand between two Ag(I) ...

journal_title：Bioinorganic chemistry and applications

authors： Đurić SŽ,Vojnovic S,Andrejević TP,Stevanović NL,Savić ND,Nikodinovic-Runic J,Glišić BĐ,Djuran MI

更新日期：2020-04-14 00:00:00

abstract：:Three hexacoordinated octahedral nickel(II) complexes, [Ni(sal-L-phe)(phen)(CH3OH)]·CH3OH (1), [Ni(naph-L-phe)(phen)(CH3OH)] (2), and [Ni(o-van-L-phe)(phen)(CH3OH)]·5CH3OH (3) (sal-L-phe = a Schiff base derived from salicylaldehyde and L-phenylalanine, naph-L-phe = a Schiff base derived from 2-hydroxy-1-naphthaldehyde...

journal_title：Bioinorganic chemistry and applications

authors： Zhao P,Zhai S,Dong J,Gao L,Liu X,Wang L,Kong J,Li L

更新日期：2018-07-05 00:00:00

abstract：:A series of antibacterial and antifungal amino acid-derived compounds and their cobalt(II), copper(II), nickel(II), and zinc(II) metal complexes have been synthesized and characterized by their elemental analyses, molar conductances, magnetic moments, and IR, and electronic spectral measurements. Ligands (L(1))-(L(5))...

journal_title：Bioinorganic chemistry and applications

authors： Chohan ZH,Arif M,Akhtar MA,Supuran CT

更新日期：2006-01-01 00:00:00

abstract：:The adsorption of bixin in aprotic solvents onto acid- and alkali-treated kaolinite was investigated. Kaolinite was treated three times, for 6 h each, with 8 M HCl or 5 M KOH. The adsorbents were characterized by XRD, FT-IR, EDS, and BET-N2. The effects of contact time and dye concentration on adsorption capacity and ...

journal_title：Bioinorganic chemistry and applications

authors： Rahmalia W,Fabre JF,Usman T,Mouloungui Z

更新日期：2018-01-18 00:00:00

abstract：:The two water-soluble designed platinum(II) complex, [Pt(Oct-dtc)(bpy)]NO(3) (Oct-dtc = Octyldithiocarbamate and bpy = 2,2' -bipyridine) and palladium(II) complex, [Pd(Oct-dtc)(bpy)]NO(3), have been synthesized and characterized by elemental analyses, molar conductivity measurements, IR, (1)H NMR, and electronic spect...

journal_title：Bioinorganic chemistry and applications

authors： Mansouri-Torshizi H,Saeidifar M,Khosravi F,Divsalar A,Saboury AA,Hassani F

更新日期：2011-01-01 00:00:00

abstract：:Dry films of platinum chemotherapeutic drugs covalently bound to plasmid DNA (Pt-DNA) represent a useful experimental model to investigate direct effects of radiation on DNA in close proximity to platinum chemotherapeutic agents, a situation of considerable relevance to understand the mechanisms underlying concomitant...

journal_title：Bioinorganic chemistry and applications

authors： Rezaee M,Alizadeh E,Hunting D,Sanche L

更新日期：2012-01-01 00:00:00

abstract：:Two oxovanadium(IV) complexes of [VO(msatsc)(phen)], (1) (msatsc = methoxylsalicylaldehyde thiosemicarbazone, phen = phenanthroline) and its novel derivative [VO (4-chlorosatsc)(phen)], (2) (4-chlorosatsc = 4-chlorosalicylaldehyde thiosemicarbazone), have been synthesized and characterized by elemental analysis, IR, E...

journal_title：Bioinorganic chemistry and applications

authors： Zhang Y,Wang X,Fang W,Cai X,Chu F,Liao X,Lu J

更新日期：2013-01-01 00:00:00

abstract：:In this study, we describe novel gallium(III), germanium(IV), and hafnium(IV) folate complexes, including their synthesis and analyses. The synthesized folate complexes were also subject to thermal analysis (TGA) to better examine their thermal degradation and kinetic properties. The folate complexes had high stabilit...

journal_title：Bioinorganic chemistry and applications

authors： El-Habeeb AA

更新日期：2020-12-18 00:00:00

abstract：:The N- and C-terminal blocked hexapeptide Ac-Leu-Ala-His-Tyr-Asn-Lys-amide (LAHYNK) representing the 80-85 fragment of histone H2B was synthesized and its interactions with Cu(II) and Ni(II) ions were studied by potentiometric, UV-Vis, CD, EPR, and NMR spectroscopic techniques in solution. Our data reveal that the imi...

journal_title：Bioinorganic chemistry and applications

authors： Panagiotou K,Panagopoulou M,Karavelas T,Dokorou V,Hagarman A,Soffer J,Schweitzer-Stenner R,Malandrinos G,Hadjiliadis N

更新日期：2008-01-01 00:00:00

abstract：:Dental care is an essential phenomenon in human health. Oral pathogens can cause severe break which may show the way to serious issues in human disease like blood circulation and coronary disease. In the current study, we demonstrated the synthesis and antimicrobial activity of cadmium sulphide and zinc sulphide nanop...

journal_title：Bioinorganic chemistry and applications

authors： Malarkodi C,Rajeshkumar S,Paulkumar K,Vanaja M,Gnanajobitha G,Annadurai G

更新日期：2014-01-01 00:00:00

abstract：:The antineoplastic potential of a stable monomeric Au(II) complex with hematoporphyrin IX (Hp), namely [Au(II)Hp(-2H).(H(2)O)(2)], was investigated in a panel of tumor cell lines. The complex exhibits strong cytotoxicity, whereby the leukaemia- and lymphoma-derived cell lines are more sensitive, with IC(50) values com...

journal_title：Bioinorganic chemistry and applications

authors： Momekov G,Ferdinandov D,Konstantinov S,Arpadjan S,Tsekova D,Gencheva G,Bontchev PR,Karaivanova M

更新日期：2008-01-01 00:00:00

abstract：:In this work we present a structural and spectroscopic analysis of a copper(II) N-acetyl-5-arylidene tetramic acid by using both experimental and computational techniques. The crystal structure of the Cu(II) complex was determined by single crystal X-ray diffraction and shows that the copper ion lies on a centre of sy...

journal_title：Bioinorganic chemistry and applications

authors： Matiadis D,Tsironis D,Stefanou V,Igglessi-Markopoulou O,McKee V,Sanakis Y,Lazarou KN,Chrissanthopoulos A,Yannopoulos SN,Markopoulos JM

更新日期：2017-01-01 00:00:00

abstract：:Fish and marine mammal consumption are an important pathway for human exposure to mercury. The low mercury content in shellfish poses a low mercury health risk to people who consume shellfish. The objectives of this study are to detect mercury concentrations in different species of shellfish and to calculate the mercu...

journal_title：Bioinorganic chemistry and applications

authors： Zhang L,Zhang L

更新日期：2015-01-01 00:00:00

abstract：:Mn peroxidase has been purified to homogeneity from the culture filtrate of a new fungal strain Fomes durissimus MTCC-1173 using concentration by ultrafiltration and anion exchange chromatography on diethylaminoethyl (DEAE) cellulose. The molecular mass of the purified enzyme has been found to be 42.0 kDa using SDS-PA...

journal_title：Bioinorganic chemistry and applications

authors： Singh SK,Yadav M,Yadava S,Yadav KD

更新日期：2011-01-01 00:00:00

abstract：:The chemical design of metal complexes of the type [Cu(phen)(antib)](+) (where antib is a quinolone or a fluoroquinolone) has been carried out in an approach to better understand how the coordination of their components affect the activity of quinolones. The ability of [Cu(phen)(nal)](+) to interact with DNA in vivo a...

journal_title：Bioinorganic chemistry and applications

authors： Ramírez-Ramírez N,Mendoza-Díaz G,Pedraza-Reyes M

更新日期：2003-01-01 00:00:00

abstract：:Four pyrazolone derivatives and their corresponding silver complexes were synthesized and characterized. Based on elemental analysis, 1 : 2 (M : L) molar ratio was suggested for all inspected complexes. 1H, 13C NMR, mass, UV-Vis, TGA, and IR were the spectral tools used for describing the formulae. Moreover, XRD patte...

journal_title：Bioinorganic chemistry and applications

authors： Althagafi I,El-Metwaly NM,Elghalban MG,Farghaly TA,Khedr AM

更新日期：2018-05-14 00:00:00

abstract：:The novel diphenyltin(IV) compound [Ph(2)(HyFoSc)Sn] (2), where H(2)HyFoSc (1) is 3-hydroxy-2-formylpyridine semicarbazone, was prepared and characterized by vibrational and NMR ((1)H, (13)C) spectroscopy. The structure of [Ph(2)(HyFoSc)Sn] was confirmed by single-crystal X-ray crystallography. The doubly deprotonated...

journal_title：Bioinorganic chemistry and applications

authors： Wiecek J,Kovala-Demertzi D,Ciunik Z,Wietrzyk J,Zervou M,Demertzis MA

更新日期：2010-01-01 00:00:00

abstract：:A low-molecular weight chromium-containing fraction of the material resulting from dichromate reduction by bovine liver homogenate was investigated by NMR and ES-MS. The ES-MS spectrum showed a readily detectable peak at m/z = 786.1. The same molecular weight reasonably agreed with the relatively low diffusion coeffic...

journal_title：Bioinorganic chemistry and applications

authors： Gaggelli E,D'Amelio N,Gaggelli N,Valensin G,Bovalini L,Paffetti A,Trabalzini L

更新日期：2003-01-01 00:00:00

abstract：:Biosorption experiment from aqueous solutions containing known amount of rare earth elements (REEs) using pre-treated Buccinum tenuissimum shell was explored to evaluate the efficiency of shell biomass as sorbent for REEs. In this work, four kinds of sieved shell samples: (a) "Ground original sample", (b) "Heat-treatm...

journal_title：Bioinorganic chemistry and applications

authors： Koto Y,Kano N,Wang Y,Sakamoto N,Imaizumi H

更新日期：2010-01-01 00:00:00

abstract：:The thermodynamic equilibria of nickel(II) with N,N'-di(aminoethylene)-2,6-pyridinedicarbonylamine (L1), Bis-(N,N-dimethylethyl)-2,6-pyridinedicarboxamide (L2), and N,N'-bis[2(2-pyridyl)-methyl]pyridine-2,6-dicarboxamide (L3) have been studied at 25°C and an ionic strength of 0.15 mol dm(-3) by glass electrode potenti...

journal_title：Bioinorganic chemistry and applications

authors： Odisitse S,Jackson GE

更新日期：2014-01-01 00:00:00

abstract：:Hemoglobin- (Hb-) based oxygen carriers (HBOC) have for several decades been explored for treatment of hemorrhage. In our previous top-up tests, HBOC with lower in vitro prooxidant reactivity (incorporating a peroxidase or serum albumin to this end) showed a measurable but small improvement of oxidative stress-related...

journal_title：Bioinorganic chemistry and applications

authors： Farcas AD,Toma VA,Roman I,Sevastre B,Scurtu F,Silaghi-Dumitrescu R

更新日期：2020-09-01 00:00:00

abstract：:Platelet activation has been reported to play a major role in arterial thrombosis, cancer metastasis, and progression. Recently, we developed a novel Ir(III)-based compound, [Ir(Cp∗)1-(2-pyridyl)-3-(4-dimethylaminophenyl)imidazo[1,5-a]pyridine Cl]BF4 or Ir-6 and assessed its effectiveness as an antiplatelet drug. Ir-6...

journal_title：Bioinorganic chemistry and applications

authors： Shyu RS,Khamrang T,Sheu JR,Hsia CW,Velusamy M,Hsia CH,Chou DS,Chang CC

更新日期：2018-05-02 00:00:00

abstract：:Water disinfection has attracted the attention of scientists worldwide due to water scarcity. The most significant challenges are determining how to achieve proper disinfection without producing harmful byproducts obtained usually using conventional chemical disinfectants and developing new point-of-use methods for th...

journal_title：Bioinorganic chemistry and applications

authors： Al-Hakami SM,Khalil AB,Laoui T,Atieh MA

更新日期：2013-01-01 00:00:00

abstract：:It is important to develop functional transmucosal implant surfaces that reduce the number of initially adhering bacteria and they need to be modified to improve the anti-bacterial performance. Commercially pure Ti sheets were anodized in an electrolyte containing ethylene glycol, distilled water and ammonium fluoride...

journal_title：Bioinorganic chemistry and applications

authors： Yeniyol S,He Z,Yüksel B,Boylan RJ,Urgen M,Ozdemir T,Ricci JL

更新日期：2014-01-01 00:00:00

abstract：:Marine biofilms formed due to adhesion of bacteria and other microorganisms on submerged surfaces are generally considered to be a major form of microfouling. Subsequent attachment of larvae of higher organisms like barnacles, mussels, and so forth, on marine biofilms, causes macrofouling. Several approaches have been...

journal_title：Bioinorganic chemistry and applications

authors： Nithya Deva Krupa A,Raghavan V

更新日期：2014-01-01 00:00:00

abstract：:A number of penta- and hexacoordinated organotin(IV) complexes and tetracoordinated tin(II) complexes of compositions Me2SnCl[RCOC:CON(C6H5)N:CCH3] (where R = - CH(3), -p-ClC(6)H(4), and -C(6)H(5)), Me2Sn[RCOC:CON(C6H5)N:CCH3]2 (where R = -CH(3), and -C(6)H(5)), and Sn(II) [RCOC:CON(C6H5)N:CCH3]2 (where R = -p-ClC(6)H...

journal_title：Bioinorganic chemistry and applications

authors： Jain A,Saxena S,Rai AK,Saxena PN

更新日期：2006-01-01 00:00:00

abstract：:DNA binding and photocleavage characteristics of a series of mixed ligand complexes of the type [M(bpy)(2)qbdp](PF(6))(n).xH(2)O (where M = Co(III) or Ni(II), bpy = 2.2'-bipryidine, qbdp = Quinolino[3,2-b]benzodiazepine, n = 3 or 2 and x = 5 or 2) have been investigated. The DNA binding property of the complexes with ...

journal_title：Bioinorganic chemistry and applications

authors： Prabhakara MC,Basavaraju B,Naik HS

更新日期：2007-01-01 00:00:00