Abstract:
:The thermodynamic equilibria of nickel(II) with N,N'-di(aminoethylene)-2,6-pyridinedicarbonylamine (L1), Bis-(N,N-dimethylethyl)-2,6-pyridinedicarboxamide (L2), and N,N'-bis[2(2-pyridyl)-methyl]pyridine-2,6-dicarboxamide (L3) have been studied at 25°C and an ionic strength of 0.15 mol dm(-3) by glass electrode potentiometry. The protonation and formation constants added to blood plasma model predict that Cu(II) competes effectively against Ni(II), Zn(II), and Ca(II) for these ligands in vivo.
journal_name
Bioinorg Chem Appljournal_title
Bioinorganic chemistry and applicationsauthors
Odisitse S,Jackson GEdoi
10.1155/2014/863612subject
Has Abstractpub_date
2014-01-01 00:00:00pages
863612eissn
1565-3633issn
1687-479Xjournal_volume
2014pub_type
杂志文章abstract::Terpolymer of 2-amino-6-nitro-benzothiazole-ethylenediamine-formaldehyde (BEF) has been synthesized and characterized by elemental analysis and various spectral techniques like FTIR, UV-Visible, and (1)H and (13)C-NMR. The terpolymer metal complexes were prepared with Cu(2+), Ni(2+), and Zn(2+) metal ions using BEF te...
journal_title:Bioinorganic chemistry and applications
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doi:10.1155/2014/764085
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journal_title:Bioinorganic chemistry and applications
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journal_title:Bioinorganic chemistry and applications
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journal_title:Bioinorganic chemistry and applications
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journal_title:Bioinorganic chemistry and applications
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doi:10.1155/BCA.2005.69
更新日期:2005-01-01 00:00:00
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journal_title:Bioinorganic chemistry and applications
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journal_title:Bioinorganic chemistry and applications
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journal_title:Bioinorganic chemistry and applications
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更新日期:2018-04-05 00:00:00
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更新日期:2018-05-14 00:00:00
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doi:10.1155/S1565363303000128
更新日期:2003-01-01 00:00:00
abstract::Changes in the expression of microRNAs can affect cancer cells' viability and behavior and the impact on cancer treatment. In this study, the expression of miR-155-5p, miR-203a-3p, and miR-223-3p in the MCF7 cancer cell line was studied when exposed to ZnO nanoparticles synthesized through a green route. Mentioned ZnO...
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doi:10.1155/2020/8817110
更新日期:2020-11-20 00:00:00
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journal_title:Bioinorganic chemistry and applications
pub_type: 杂志文章
doi:10.1155/2015/159521
更新日期:2015-01-01 00:00:00
abstract::Hemoglobin- (Hb-) based oxygen carriers (HBOC) have for several decades been explored for treatment of hemorrhage. In our previous top-up tests, HBOC with lower in vitro prooxidant reactivity (incorporating a peroxidase or serum albumin to this end) showed a measurable but small improvement of oxidative stress-related...
journal_title:Bioinorganic chemistry and applications
pub_type: 杂志文章
doi:10.1155/2020/1096573
更新日期:2020-09-01 00:00:00
abstract::In this work we present a structural and spectroscopic analysis of a copper(II) N-acetyl-5-arylidene tetramic acid by using both experimental and computational techniques. The crystal structure of the Cu(II) complex was determined by single crystal X-ray diffraction and shows that the copper ion lies on a centre of sy...
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doi:10.1155/2017/7895023
更新日期:2017-01-01 00:00:00
abstract::The highly water-soluble ruthenium complex [Ru(H(2)L)Cl(2)](2)H(2)o, in which H(4)L is the sequestering ligand trans-l, 2-cyclohexanediamminetetraacetic acid (cdta) has been synthesized, structurally characterized and its properties studied. The X-ray crystallographic study shows that the chelating coordinated ligand ...
journal_title:Bioinorganic chemistry and applications
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doi:10.1155/S1565363304000160
更新日期:2004-01-01 00:00:00
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journal_title:Bioinorganic chemistry and applications
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doi:10.1155/2010/718606
更新日期:2010-01-01 00:00:00
abstract::Marine biofilms formed due to adhesion of bacteria and other microorganisms on submerged surfaces are generally considered to be a major form of microfouling. Subsequent attachment of larvae of higher organisms like barnacles, mussels, and so forth, on marine biofilms, causes macrofouling. Several approaches have been...
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更新日期:2013-01-01 00:00:00
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journal_title:Bioinorganic chemistry and applications
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journal_title:Bioinorganic chemistry and applications
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doi:10.1155/2008/367471
更新日期:2008-01-01 00:00:00
abstract::The chemical design of metal complexes of the type [Cu(phen)(antib)](+) (where antib is a quinolone or a fluoroquinolone) has been carried out in an approach to better understand how the coordination of their components affect the activity of quinolones. The ability of [Cu(phen)(nal)](+) to interact with DNA in vivo a...
journal_title:Bioinorganic chemistry and applications
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journal_title:Bioinorganic chemistry and applications
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更新日期:2010-01-01 00:00:00
abstract::In this study, we describe novel gallium(III), germanium(IV), and hafnium(IV) folate complexes, including their synthesis and analyses. The synthesized folate complexes were also subject to thermal analysis (TGA) to better examine their thermal degradation and kinetic properties. The folate complexes had high stabilit...
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journal_title:Bioinorganic chemistry and applications
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更新日期:2011-01-01 00:00:00
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journal_title:Bioinorganic chemistry and applications
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doi:10.1155/2010/973742
更新日期:2010-01-01 00:00:00
abstract::The catalytic decomposition of hydrogen peroxide by Cu(II) complexes with polymers bearing L-alanine (PAla) and glycylglycine (PGlygly) in their side chain was studied in alkaline aqueous media. The reactions were of pseudo-first order with respect to [H(2)O(2)] and [L-Cu(II)] (L stands for PAla or PGlygly) and the re...
journal_title:Bioinorganic chemistry and applications
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更新日期:2010-01-01 00:00:00
abstract::Antifertility and histopathological investigations were carried out on reproductive organs of male albino rats induced by tetraazamacrocyclic complexes of iron(II). The complexes were synthesized by the template condensation of 1,2-diaminoethane, 1,3-diaminopropane with succinic acid and phthalic acid in 2 : 2 molar r...
journal_title:Bioinorganic chemistry and applications
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更新日期:2006-01-01 00:00:00