Co(III) and Ni(II) complexes containing bioactive ligands: synthesis, DNA binding, and photocleavage studies.

abstract：:Fish and marine mammal consumption are an important pathway for human exposure to mercury. The low mercury content in shellfish poses a low mercury health risk to people who consume shellfish. The objectives of this study are to detect mercury concentrations in different species of shellfish and to calculate the mercu...

journal_title：Bioinorganic chemistry and applications

authors： Zhang L,Zhang L

更新日期：2015-01-01 00:00:00

abstract：:Three hexacoordinated octahedral nickel(II) complexes, [Ni(sal-L-phe)(phen)(CH3OH)]·CH3OH (1), [Ni(naph-L-phe)(phen)(CH3OH)] (2), and [Ni(o-van-L-phe)(phen)(CH3OH)]·5CH3OH (3) (sal-L-phe = a Schiff base derived from salicylaldehyde and L-phenylalanine, naph-L-phe = a Schiff base derived from 2-hydroxy-1-naphthaldehyde...

journal_title：Bioinorganic chemistry and applications

authors： Zhao P,Zhai S,Dong J,Gao L,Liu X,Wang L,Kong J,Li L

更新日期：2018-07-05 00:00:00

abstract：:The adsorption of bixin in aprotic solvents onto acid- and alkali-treated kaolinite was investigated. Kaolinite was treated three times, for 6 h each, with 8 M HCl or 5 M KOH. The adsorbents were characterized by XRD, FT-IR, EDS, and BET-N2. The effects of contact time and dye concentration on adsorption capacity and ...

journal_title：Bioinorganic chemistry and applications

authors： Rahmalia W,Fabre JF,Usman T,Mouloungui Z

更新日期：2018-01-18 00:00:00

abstract：:Hemoglobin- (Hb-) based oxygen carriers (HBOC) have for several decades been explored for treatment of hemorrhage. In our previous top-up tests, HBOC with lower in vitro prooxidant reactivity (incorporating a peroxidase or serum albumin to this end) showed a measurable but small improvement of oxidative stress-related...

journal_title：Bioinorganic chemistry and applications

authors： Farcas AD,Toma VA,Roman I,Sevastre B,Scurtu F,Silaghi-Dumitrescu R

更新日期：2020-09-01 00:00:00

abstract：:The N- and C-terminal blocked hexapeptide Ac-Leu-Ala-His-Tyr-Asn-Lys-amide (LAHYNK) representing the 80-85 fragment of histone H2B was synthesized and its interactions with Cu(II) and Ni(II) ions were studied by potentiometric, UV-Vis, CD, EPR, and NMR spectroscopic techniques in solution. Our data reveal that the imi...

journal_title：Bioinorganic chemistry and applications

authors： Panagiotou K,Panagopoulou M,Karavelas T,Dokorou V,Hagarman A,Soffer J,Schweitzer-Stenner R,Malandrinos G,Hadjiliadis N

更新日期：2008-01-01 00:00:00

abstract：:The synthetic, spectroscopic, and biological studies of sixteen ring-substituted 4-phenylthiosemicarbazones and 4-nitrophenyl-thiosemicarbazones of anisaldehyde, 4-chlorobenzaldehyde, 4-fluorobenzaldehyde, and vanillin with ruthenium(III) and rhodium(III) chlorides are reported here. Their structures were determined o...

journal_title：Bioinorganic chemistry and applications

authors： Sharma VK,Srivastava S,Srivastava A

更新日期：2007-01-01 00:00:00

abstract：:Dry films of platinum chemotherapeutic drugs covalently bound to plasmid DNA (Pt-DNA) represent a useful experimental model to investigate direct effects of radiation on DNA in close proximity to platinum chemotherapeutic agents, a situation of considerable relevance to understand the mechanisms underlying concomitant...

journal_title：Bioinorganic chemistry and applications

authors： Rezaee M,Alizadeh E,Hunting D,Sanche L

更新日期：2012-01-01 00:00:00

abstract：:A number of penta- and hexacoordinated organotin(IV) complexes and tetracoordinated tin(II) complexes of compositions Me2SnCl[RCOC:CON(C6H5)N:CCH3] (where R = - CH(3), -p-ClC(6)H(4), and -C(6)H(5)), Me2Sn[RCOC:CON(C6H5)N:CCH3]2 (where R = -CH(3), and -C(6)H(5)), and Sn(II) [RCOC:CON(C6H5)N:CCH3]2 (where R = -p-ClC(6)H...

journal_title：Bioinorganic chemistry and applications

authors： Jain A,Saxena S,Rai AK,Saxena PN

更新日期：2006-01-01 00:00:00

abstract：:The Rieske iron-sulfur protein, one of the catalytic subunits of the cytochrome bc(1) complex, is involved in electron transfer at the level of the inner membrane of yeast mitochondria. The Rieske iron-sulfur protein is encoded by nuclear DNA and, after being synthesized in the cytosol, is imported into mitochondria w...

journal_title：Bioinorganic chemistry and applications

authors： Conte L,Zara V

更新日期：2011-01-01 00:00:00

abstract：:In this work we present a structural and spectroscopic analysis of a copper(II) N-acetyl-5-arylidene tetramic acid by using both experimental and computational techniques. The crystal structure of the Cu(II) complex was determined by single crystal X-ray diffraction and shows that the copper ion lies on a centre of sy...

journal_title：Bioinorganic chemistry and applications

authors： Matiadis D,Tsironis D,Stefanou V,Igglessi-Markopoulou O,McKee V,Sanakis Y,Lazarou KN,Chrissanthopoulos A,Yannopoulos SN,Markopoulos JM

更新日期：2017-01-01 00:00:00

abstract：:Rice husk is an abundant agricultural by-product reaching the output of 80 million tons annually in the world. The most common treatment method of rice husk is burning or burying, which caused serious air pollution and resource waste. In order to solve this problem, a new method is proposed to comprehensively utilize ...

journal_title：Bioinorganic chemistry and applications

authors： Zhang H,Ding X,Wang Z,Zhao X

更新日期：2014-01-01 00:00:00

abstract：:The two water-soluble designed platinum(II) complex, [Pt(Oct-dtc)(bpy)]NO(3) (Oct-dtc = Octyldithiocarbamate and bpy = 2,2' -bipyridine) and palladium(II) complex, [Pd(Oct-dtc)(bpy)]NO(3), have been synthesized and characterized by elemental analyses, molar conductivity measurements, IR, (1)H NMR, and electronic spect...

journal_title：Bioinorganic chemistry and applications

authors： Mansouri-Torshizi H,Saeidifar M,Khosravi F,Divsalar A,Saboury AA,Hassani F

更新日期：2011-01-01 00:00:00

abstract：:Biosorption experiment from aqueous solutions containing known amount of rare earth elements (REEs) using pre-treated Buccinum tenuissimum shell was explored to evaluate the efficiency of shell biomass as sorbent for REEs. In this work, four kinds of sieved shell samples: (a) "Ground original sample", (b) "Heat-treatm...

journal_title：Bioinorganic chemistry and applications

authors： Koto Y,Kano N,Wang Y,Sakamoto N,Imaizumi H

更新日期：2010-01-01 00:00:00

abstract：:The chemical design of metal complexes of the type [Cu(phen)(antib)](+) (where antib is a quinolone or a fluoroquinolone) has been carried out in an approach to better understand how the coordination of their components affect the activity of quinolones. The ability of [Cu(phen)(nal)](+) to interact with DNA in vivo a...

journal_title：Bioinorganic chemistry and applications

authors： Ramírez-Ramírez N,Mendoza-Díaz G,Pedraza-Reyes M

更新日期：2003-01-01 00:00:00

abstract：:The highly water-soluble ruthenium complex [Ru(H(2)L)Cl(2)](2)H(2)o, in which H(4)L is the sequestering ligand trans-l, 2-cyclohexanediamminetetraacetic acid (cdta) has been synthesized, structurally characterized and its properties studied. The X-ray crystallographic study shows that the chelating coordinated ligand ...

journal_title：Bioinorganic chemistry and applications

authors： Vilaplana RA,Castiñeiras A,González-Vílchez F

更新日期：2004-01-01 00:00:00

abstract：:It is important to develop functional transmucosal implant surfaces that reduce the number of initially adhering bacteria and they need to be modified to improve the anti-bacterial performance. Commercially pure Ti sheets were anodized in an electrolyte containing ethylene glycol, distilled water and ammonium fluoride...

journal_title：Bioinorganic chemistry and applications

authors： Yeniyol S,He Z,Yüksel B,Boylan RJ,Urgen M,Ozdemir T,Ricci JL

更新日期：2014-01-01 00:00:00

abstract：:This paper describes some physical, structural, and biological properties of gypsum bioceramics doped with various amounts of strontium ions (0.19-2.23 wt%) and compares these properties with those of a pure gypsum as control. Strontium-doped gypsum (gypsum:Sr) was obtained by mixing calcium sulfate hemihydrate powder...

journal_title：Bioinorganic chemistry and applications

authors： Pouria A,Bandegani H,Pourbaghi-Masouleh M,Hesaraki S,Alizadeh M

更新日期：2012-01-01 00:00:00

abstract：:A series of perimidine derivatives (L1-5) were prepared and characterized by IR, 1H·NMR, mass spectroscopy, UV-Vis, XRD, thermal, and SEM analysis. Five VO(II) complexes were synthesized and investigated by most previous tools besides the theoretical usage. A neutral tetradentate mode of bonding is the general approac...

journal_title：Bioinorganic chemistry and applications

authors： Al-Hazmi GA,Abou-Melha KS,El-Metwaly NM,Saleh KA

更新日期：2018-09-06 00:00:00

abstract：:The novel diphenyltin(IV) compound [Ph(2)(HyFoSc)Sn] (2), where H(2)HyFoSc (1) is 3-hydroxy-2-formylpyridine semicarbazone, was prepared and characterized by vibrational and NMR ((1)H, (13)C) spectroscopy. The structure of [Ph(2)(HyFoSc)Sn] was confirmed by single-crystal X-ray crystallography. The doubly deprotonated...

journal_title：Bioinorganic chemistry and applications

authors： Wiecek J,Kovala-Demertzi D,Ciunik Z,Wietrzyk J,Zervou M,Demertzis MA

更新日期：2010-01-01 00:00:00

abstract：:Antifertility and histopathological investigations were carried out on reproductive organs of male albino rats induced by tetraazamacrocyclic complexes of iron(II). The complexes were synthesized by the template condensation of 1,2-diaminoethane, 1,3-diaminopropane with succinic acid and phthalic acid in 2 : 2 molar r...

journal_title：Bioinorganic chemistry and applications

authors： Chaudhary A,Singh RV

更新日期：2006-01-01 00:00:00

abstract：:The catalytic decomposition of hydrogen peroxide by Cu(II) complexes with polymers bearing L-alanine (PAla) and glycylglycine (PGlygly) in their side chain was studied in alkaline aqueous media. The reactions were of pseudo-first order with respect to [H(2)O(2)] and [L-Cu(II)] (L stands for PAla or PGlygly) and the re...

journal_title：Bioinorganic chemistry and applications

authors： Skounas S,Methenitis C,Pneumatikakis G,Morcellet M

更新日期：2010-01-01 00:00:00

abstract：:In this study, we describe novel gallium(III), germanium(IV), and hafnium(IV) folate complexes, including their synthesis and analyses. The synthesized folate complexes were also subject to thermal analysis (TGA) to better examine their thermal degradation and kinetic properties. The folate complexes had high stabilit...

journal_title：Bioinorganic chemistry and applications

authors： El-Habeeb AA

更新日期：2020-12-18 00:00:00

abstract：:Water disinfection has attracted the attention of scientists worldwide due to water scarcity. The most significant challenges are determining how to achieve proper disinfection without producing harmful byproducts obtained usually using conventional chemical disinfectants and developing new point-of-use methods for th...

journal_title：Bioinorganic chemistry and applications

authors： Al-Hakami SM,Khalil AB,Laoui T,Atieh MA

更新日期：2013-01-01 00:00:00

abstract：:Changes in the expression of microRNAs can affect cancer cells' viability and behavior and the impact on cancer treatment. In this study, the expression of miR-155-5p, miR-203a-3p, and miR-223-3p in the MCF7 cancer cell line was studied when exposed to ZnO nanoparticles synthesized through a green route. Mentioned ZnO...

journal_title：Bioinorganic chemistry and applications

authors： Aalami AH,Mesgari M,Sahebkar A

更新日期：2020-11-20 00:00:00

abstract：:Terminally protected pentapeptides with 2 histidines (Ac-HHVGD-NH(2) and Ac-HVGDH-NH(2)) and the terminally free peptides containing both internal aspartyl and C-terminal histidyl residues (FDAH and VIDAH) have been synthesized, and copper(II) complexes studied by potentiometric, UV-Vis, CD, and EPR spectroscopic tech...

journal_title：Bioinorganic chemistry and applications

authors： Kállay C,Nagy Z,Várnagy K,Malandrinos G,Hadjiliadis N,Sóvágó I

更新日期：2007-01-01 00:00:00

abstract：Background:Sustained return of spontaneous circulation (ROSC) can be initially established in patients with out-of-hospital cardiac arrest (OHCA); however, the early postresuscitation hemodynamics can still be impaired by high levels of serum potassium (hyperkalemia). The impact of different potassium levels on early p...

journal_title：Bioinorganic chemistry and applications

authors： Lin YR,Syue YJ,Lee TH,Chou CC,Chang CF,Li CJ

更新日期：2018-04-05 00:00:00

abstract：:The incorporation of benzene-l,2-dithiolato building blocks into supramolecular coordination assemblies is the main objective of the investigations described here. Special interest is directed towards dinuclear complexes with bis(benzene-l,2-dithiolato) ligands, which might be able to form helical structures. Bis(benz...

journal_title：Bioinorganic chemistry and applications

authors： Seidel WW,Hahn FE

更新日期：2005-01-01 00:00:00

abstract：:The antineoplastic potential of a stable monomeric Au(II) complex with hematoporphyrin IX (Hp), namely [Au(II)Hp(-2H).(H(2)O)(2)], was investigated in a panel of tumor cell lines. The complex exhibits strong cytotoxicity, whereby the leukaemia- and lymphoma-derived cell lines are more sensitive, with IC(50) values com...

journal_title：Bioinorganic chemistry and applications

authors： Momekov G,Ferdinandov D,Konstantinov S,Arpadjan S,Tsekova D,Gencheva G,Bontchev PR,Karaivanova M

更新日期：2008-01-01 00:00:00

abstract：:Four pyrazolone derivatives and their corresponding silver complexes were synthesized and characterized. Based on elemental analysis, 1 : 2 (M : L) molar ratio was suggested for all inspected complexes. 1H, 13C NMR, mass, UV-Vis, TGA, and IR were the spectral tools used for describing the formulae. Moreover, XRD patte...

journal_title：Bioinorganic chemistry and applications

authors： Althagafi I,El-Metwaly NM,Elghalban MG,Farghaly TA,Khedr AM

更新日期：2018-05-14 00:00:00

abstract：:Dental care is an essential phenomenon in human health. Oral pathogens can cause severe break which may show the way to serious issues in human disease like blood circulation and coronary disease. In the current study, we demonstrated the synthesis and antimicrobial activity of cadmium sulphide and zinc sulphide nanop...

journal_title：Bioinorganic chemistry and applications

authors： Malarkodi C,Rajeshkumar S,Paulkumar K,Vanaja M,Gnanajobitha G,Annadurai G

更新日期：2014-01-01 00:00:00