Consecutively preparing d-xylose, organosolv lignin, and amorphous ultrafine silica from rice husk.

Abstract:

:Rice husk is an abundant agricultural by-product reaching the output of 80 million tons annually in the world. The most common treatment method of rice husk is burning or burying, which caused serious air pollution and resource waste. In order to solve this problem, a new method is proposed to comprehensively utilize the rice husk in this paper. Firstly, the D-xylose was prepared from the semicellulose via dilute acid hydrolysis. Secondly, the lignin was separated via organic solvent pulping from the residue. Finally, the amorphous ultrafine silica was prepared via pyrolysis of the residue produced in the second process. In this way, the three main contents of rice husk (semicellulose, lignin, and silica) are consecutively converted to three fine chemicals, without solid waste produced. The yields of D-xylose and organosolv lignin reach 58.2% and 58.5%, respectively. The purity and specific surface of amorphous ultrafine silica reach 99.92% and 225.20 m(2)/g.

journal_name

Bioinorg Chem Appl

authors

Zhang H,Ding X,Wang Z,Zhao X

doi

10.1155/2014/603481

subject

Has Abstract

pub_date

2014-01-01 00:00:00

pages

603481

eissn

1565-3633

issn

1687-479X

journal_volume

2014

pub_type

杂志文章
  • Biosynthesis and Antimicrobial Activity of Semiconductor Nanoparticles against Oral Pathogens.

    abstract::Dental care is an essential phenomenon in human health. Oral pathogens can cause severe break which may show the way to serious issues in human disease like blood circulation and coronary disease. In the current study, we demonstrated the synthesis and antimicrobial activity of cadmium sulphide and zinc sulphide nanop...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2014/347167

    authors: Malarkodi C,Rajeshkumar S,Paulkumar K,Vanaja M,Gnanajobitha G,Annadurai G

    更新日期:2014-01-01 00:00:00

  • Biosorption of Lanthanides from Aqueous Solutions Using Pretreated Buccinum tenuissimum Shell Biomass.

    abstract::Biosorption experiment from aqueous solutions containing known amount of rare earth elements (REEs) using pre-treated Buccinum tenuissimum shell was explored to evaluate the efficiency of shell biomass as sorbent for REEs. In this work, four kinds of sieved shell samples: (a) "Ground original sample", (b) "Heat-treatm...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2010/804854

    authors: Koto Y,Kano N,Wang Y,Sakamoto N,Imaizumi H

    更新日期:2010-01-01 00:00:00

  • Assessment of Toxicity of Some Penta- and Hexacoordinated Organotin(IV) and Tetracoordinated Tin(II) Complexes of Heterocyclic beta-Diketones.

    abstract::A number of penta- and hexacoordinated organotin(IV) complexes and tetracoordinated tin(II) complexes of compositions Me2SnCl[RCOC:CON(C6H5)N:CCH3] (where R = - CH(3), -p-ClC(6)H(4), and -C(6)H(5)), Me2Sn[RCOC:CON(C6H5)N:CCH3]2 (where R = -CH(3), and -C(6)H(5)), and Sn(II) [RCOC:CON(C6H5)N:CCH3]2 (where R = -p-ClC(6)H...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/BCA/2006/60140

    authors: Jain A,Saxena S,Rai AK,Saxena PN

    更新日期:2006-01-01 00:00:00

  • Spectroscopic, Thermal, Electrochemical, and Antimicrobial Studies of Mononuclear Manganese(II) Ditolyldithiophosphates.

    abstract::New complexes of manganese(II) corresponding to [{(ArO)2PS2}2Mn] and [{(ArO)2PS2}2Mn.nL] (Ar = o-, m-, p-CH3C6H4 and p-Cl-m-CH3C6H3; n = 1, L = N2C12H8, N2C10H8; n = 2, L = NC5H5, P(C6H5)3) have been synthesized and characterized by microelemental analyses (C, H, and N), magnetic susceptibility, molar conductance, the...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2013/261731

    authors: Khajuria R,Syed A,Kumar S,Pandey SK

    更新日期:2013-01-01 00:00:00

  • Chances and limits of the coordination chemistry with bis(benzene-l,2-dithiolato) ligands.

    abstract::The incorporation of benzene-l,2-dithiolato building blocks into supramolecular coordination assemblies is the main objective of the investigations described here. Special interest is directed towards dinuclear complexes with bis(benzene-l,2-dithiolato) ligands, which might be able to form helical structures. Bis(benz...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/BCA.2005.69

    authors: Seidel WW,Hahn FE

    更新日期:2005-01-01 00:00:00

  • Degradation of single stranded nucleic acids by the chemical nuclease activity of the metal complex [Cu(phen)(nal)]+.

    abstract::The chemical design of metal complexes of the type [Cu(phen)(antib)](+) (where antib is a quinolone or a fluoroquinolone) has been carried out in an approach to better understand how the coordination of their components affect the activity of quinolones. The ability of [Cu(phen)(nal)](+) to interact with DNA in vivo a...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/S1565363303000025

    authors: Ramírez-Ramírez N,Mendoza-Díaz G,Pedraza-Reyes M

    更新日期:2003-01-01 00:00:00

  • Preparation, Characterization, and Antimicrobial Activities of Bimetallic Complexes of Sarcosine with Zn(II) and Sn(IV).

    abstract::Heterobimetallic complexes of Zn(II) and Sn(IV) with sarcosine have been synthesized at room temperature under stirring conditions by the reaction of sarcosine and zinc acetate in 2 : 1 molar ratio followed by the stepwise addition of CS2 and organotin(IV) halides, where R = Me, n-Bu, and Ph. The complexes were charac...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2013/351262

    authors: Arafat Y,Ali S,Shahzadi S,Shahid M

    更新日期:2013-01-01 00:00:00

  • Fertility regulation in male rats by implemented tetraazamacrocyclic compounds of iron(II): synthetic, spectroscopic, and applied aspects with toxicological screening.

    abstract::Antifertility and histopathological investigations were carried out on reproductive organs of male albino rats induced by tetraazamacrocyclic complexes of iron(II). The complexes were synthesized by the template condensation of 1,2-diaminoethane, 1,3-diaminopropane with succinic acid and phthalic acid in 2 : 2 molar r...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/BCA/2006/17316

    authors: Chaudhary A,Singh RV

    更新日期:2006-01-01 00:00:00

  • Physicochemical properties and cellular responses of strontium-doped gypsum biomaterials.

    abstract::This paper describes some physical, structural, and biological properties of gypsum bioceramics doped with various amounts of strontium ions (0.19-2.23 wt%) and compares these properties with those of a pure gypsum as control. Strontium-doped gypsum (gypsum:Sr) was obtained by mixing calcium sulfate hemihydrate powder...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2012/976495

    authors: Pouria A,Bandegani H,Pourbaghi-Masouleh M,Hesaraki S,Alizadeh M

    更新日期:2012-01-01 00:00:00

  • Spectroscopic, thermal and biological studies on some trivalent ruthenium and rhodium NS chelating thiosemicarbazone complexes.

    abstract::The synthetic, spectroscopic, and biological studies of sixteen ring-substituted 4-phenylthiosemicarbazones and 4-nitrophenyl-thiosemicarbazones of anisaldehyde, 4-chlorobenzaldehyde, 4-fluorobenzaldehyde, and vanillin with ruthenium(III) and rhodium(III) chlorides are reported here. Their structures were determined o...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2007/68374

    authors: Sharma VK,Srivastava S,Srivastava A

    更新日期:2007-01-01 00:00:00

  • Biosynthesis of Silver Nanoparticles Using Aegle marmelos (Bael) Fruit Extract and Its Application to Prevent Adhesion of Bacteria: A Strategy to Control Microfouling.

    abstract::Marine biofilms formed due to adhesion of bacteria and other microorganisms on submerged surfaces are generally considered to be a major form of microfouling. Subsequent attachment of larvae of higher organisms like barnacles, mussels, and so forth, on marine biofilms, causes macrofouling. Several approaches have been...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2014/949538

    authors: Nithya Deva Krupa A,Raghavan V

    更新日期:2014-01-01 00:00:00

  • In Vivo Radionuclide Generators for Diagnostics and Therapy.

    abstract::In vivo radionuclide generators make complex combinations of physical and chemical properties available for medical diagnostics and therapy. Perhaps the best-known in vivo generator is 212Pb/212Bi, which takes advantage of the extended half-life of 212Pb to execute a targeted delivery of the therapeutic short-lived α-...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章,评审

    doi:10.1155/2016/6148357

    authors: Edem PE,Fonslet J,Kjær A,Herth M,Severin G

    更新日期:2016-01-01 00:00:00

  • Potentiometric and Blood Plasma Simulation Studies of Nickel(II) Complexes of Poly(amino)amido Pentadentate Ligands: Computer Aided Metal-Based Drug Design.

    abstract::The thermodynamic equilibria of nickel(II) with N,N'-di(aminoethylene)-2,6-pyridinedicarbonylamine (L1), Bis-(N,N-dimethylethyl)-2,6-pyridinedicarboxamide (L2), and N,N'-bis[2(2-pyridyl)-methyl]pyridine-2,6-dicarboxamide (L3) have been studied at 25°C and an ionic strength of 0.15 mol dm(-3) by glass electrode potenti...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2014/863612

    authors: Odisitse S,Jackson GE

    更新日期:2014-01-01 00:00:00

  • Di-n-butyltin(IV) complexes derived from heterocyclic beta-diketones and N-phthaloyl amino acids: preparation, biological evaluation, structural elucidation based upon spectral [IR, NMR (1H, 13C, 19F and 119Sn)] studies.

    abstract::Stable, six coordinated Bu(2)SnLA type complexes have been prepared [where LH = RCOC:C(OH)N(C(6) H(5))N:CCH(3); R = -4-F-C(6)H(4)-(L(1)H), R = -4-Cl-C(6)H(4)-(L(2)H), R= -4-Br-C(6)H(4)-(L(3)H), R=-CF(3)(L(4)H) and AH = C(O)C(6) H(4) C(O)NCHR'COOH; R'= -H(A(1)H), -CH(3)(A(2)H), -CH(CH(3))(2)(A(3)H)] by the interaction ...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/BCA.2005.201

    authors: Joshi A,Verma S,Gaurb RB,Sharma RR

    更新日期:2005-01-01 00:00:00

  • Contribution of Shellfish Consumption to Lower Mercury Health Risk for Residents in Northern Jiaozhou Bay, China.

    abstract::Fish and marine mammal consumption are an important pathway for human exposure to mercury. The low mercury content in shellfish poses a low mercury health risk to people who consume shellfish. The objectives of this study are to detect mercury concentrations in different species of shellfish and to calculate the mercu...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2015/159521

    authors: Zhang L,Zhang L

    更新日期:2015-01-01 00:00:00

  • X-Ray Crystallographic Analysis, EPR Studies, and Computational Calculations of a Cu(II) Tetramic Acid Complex.

    abstract::In this work we present a structural and spectroscopic analysis of a copper(II) N-acetyl-5-arylidene tetramic acid by using both experimental and computational techniques. The crystal structure of the Cu(II) complex was determined by single crystal X-ray diffraction and shows that the copper ion lies on a centre of sy...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2017/7895023

    authors: Matiadis D,Tsironis D,Stefanou V,Igglessi-Markopoulou O,McKee V,Sanakis Y,Lazarou KN,Chrissanthopoulos A,Yannopoulos SN,Markopoulos JM

    更新日期:2017-01-01 00:00:00

  • In vitro evaluation of a stable monomeric gold(II) complex with hematoporphyrin IX: cytotoxicity against tumor and kidney cells, cellular accumulation, and induction of apoptosis.

    abstract::The antineoplastic potential of a stable monomeric Au(II) complex with hematoporphyrin IX (Hp), namely [Au(II)Hp(-2H).(H(2)O)(2)], was investigated in a panel of tumor cell lines. The complex exhibits strong cytotoxicity, whereby the leukaemia- and lymphoma-derived cell lines are more sensitive, with IC(50) values com...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2008/367471

    authors: Momekov G,Ferdinandov D,Konstantinov S,Arpadjan S,Tsekova D,Gencheva G,Bontchev PR,Karaivanova M

    更新日期:2008-01-01 00:00:00

  • Fast Disinfection of Escherichia coli Bacteria Using Carbon Nanotubes Interaction with Microwave Radiation.

    abstract::Water disinfection has attracted the attention of scientists worldwide due to water scarcity. The most significant challenges are determining how to achieve proper disinfection without producing harmful byproducts obtained usually using conventional chemical disinfectants and developing new point-of-use methods for th...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2013/458943

    authors: Al-Hakami SM,Khalil AB,Laoui T,Atieh MA

    更新日期:2013-01-01 00:00:00

  • Synthesis and characterization of bis[(2-ethyl-5-methyl-imidazo-4-yl)methyl]sulfide and its coordination behavior toward Cu(II) as a possible approach of a copper site type I.

    abstract::The synthesis and characterization of a novel ligand, bis[(2-ethyl-5-methyl-imidazo-4-yl)methyl]sulfide (bemims), as well as a bemims-containing copper(II) coordination complex are described. In this complex, [Cu(bemims)X(2)] with X = NO(3) (-), bemims acts as a tridentate ligand and two monodentate nitrate ions compl...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2009/905320

    authors: Barrón-Garcés JD,Mendoza-Díaz G,Vilchez-Aguado F,Bernès S

    更新日期:2009-01-01 00:00:00

  • Synthesis, structure, properties and biological behaviour of the complex [RuIV (H2L) Cl2].2H2O (H4L= 1,2-cyclohexanediamminetetraacetic acid).

    abstract::The highly water-soluble ruthenium complex [Ru(H(2)L)Cl(2)](2)H(2)o, in which H(4)L is the sequestering ligand trans-l, 2-cyclohexanediamminetetraacetic acid (cdta) has been synthesized, structurally characterized and its properties studied. The X-ray crystallographic study shows that the chelating coordinated ligand ...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/S1565363304000160

    authors: Vilaplana RA,Castiñeiras A,González-Vílchez F

    更新日期:2004-01-01 00:00:00

  • The Rieske Iron-Sulfur Protein: Import and Assembly into the Cytochrome bc(1) Complex of Yeast Mitochondria.

    abstract::The Rieske iron-sulfur protein, one of the catalytic subunits of the cytochrome bc(1) complex, is involved in electron transfer at the level of the inner membrane of yeast mitochondria. The Rieske iron-sulfur protein is encoded by nuclear DNA and, after being synthesized in the cytosol, is imported into mitochondria w...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2011/363941

    authors: Conte L,Zara V

    更新日期:2011-01-01 00:00:00

  • Stabilization of submicron calcium oxalate suspension by chondroitin sulfate C may be an efficient protection from stone formation.

    abstract::The influences of chondroitin sulfate C (C6S) on size, aggregation, sedimentation, and Zeta potential of sub-micron calcium oxalate monohydrate (COM) and calcium oxalate dihydrate (COD) crystallites with mean sizes of about 330 nm were investigated using an X-ray diffractometer, nanoparticle size Zeta potential analyz...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2013/360142

    authors: Li JJ,Xue JF,Ouyang JM

    更新日期:2013-01-01 00:00:00

  • Glutaraldehyde-Polymerized Hemoglobin: In Search of Improved Performance as Oxygen Carrier in Hemorrhage Models.

    abstract::Hemoglobin- (Hb-) based oxygen carriers (HBOC) have for several decades been explored for treatment of hemorrhage. In our previous top-up tests, HBOC with lower in vitro prooxidant reactivity (incorporating a peroxidase or serum albumin to this end) showed a measurable but small improvement of oxidative stress-related...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2020/1096573

    authors: Farcas AD,Toma VA,Roman I,Sevastre B,Scurtu F,Silaghi-Dumitrescu R

    更新日期:2020-09-01 00:00:00

  • Kinetic Studies and Mechanism of Hydrogen Peroxide Catalytic Decomposition by Cu(II) Complexes with Polyelectrolytes Derived from L-Alanine and Glycylglycine.

    abstract::The catalytic decomposition of hydrogen peroxide by Cu(II) complexes with polymers bearing L-alanine (PAla) and glycylglycine (PGlygly) in their side chain was studied in alkaline aqueous media. The reactions were of pseudo-first order with respect to [H(2)O(2)] and [L-Cu(II)] (L stands for PAla or PGlygly) and the re...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2010/643120

    authors: Skounas S,Methenitis C,Pneumatikakis G,Morcellet M

    更新日期:2010-01-01 00:00:00

  • Antimicrobial Activity and DNA/BSA Binding Affinity of Polynuclear Silver(I) Complexes with 1,2-Bis(4-pyridyl)ethane/ethene as Bridging Ligands.

    abstract::1,2-Bis(4-pyridyl)ethane (bpa) and 1,2-bis(4-pyridyl)ethene (bpe) were used for the synthesis of polynuclear silver(I) complexes, {[Ag(bpa)]NO3}n (1), {[Ag(bpa)2]CF3SO3.H2O}n (2) and {[Ag(bpe)]CF3SO3}n (3). In complexes 1-3, the corresponding nitrogen-containing heterocycle acts as a bridging ligand between two Ag(I) ...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2020/3812050

    authors: Đurić SŽ,Vojnovic S,Andrejević TP,Stevanović NL,Savić ND,Nikodinovic-Runic J,Glišić BĐ,Djuran MI

    更新日期:2020-04-14 00:00:00

  • Synthesis, Crystal Structure, Spectroscopic Properties, and Interaction with Ct-DNA of Zn(II) with 2-Aminoethanethiol Hydrochloride Ligand.

    abstract::The zinc(II) complex (C2H6NS)2Zn·ZnCl2 was synthesized with 2-aminoethanethiol hydrochloride and zinc sulfate heptahydrate as the raw materials in aqueous solution. The composition and structure of the complex were characterized by elemental analysis, infrared spectra, single crystal X-ray diffraction, and thermogravi...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2016/2691253

    authors: Shu XG,Wu CL,Li CJ,Zhang M,Wan K,Wu X

    更新日期:2016-01-01 00:00:00

  • Objectives and methods of iron chelation therapy.

    abstract::Recent developments in the understanding of the molecular control of iron homeostasis provided novel insights into the mechanisms responsible for normal iron balance. However in chronic anemias associated with iron overload, such mechanisms are no longer sufficient to offer protection from iron toxicity, and iron chel...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/S1565363303000128

    authors: Hershko C,Abrahamov A,Konijn AM,Breuer W,Cabantchik IZ,Pootrakul P,Link G

    更新日期:2003-01-01 00:00:00

  • Synthesis of Pyrazolone Derivatives and Their Nanometer Ag(I) Complexes and Physicochemical, DNA Binding, Antitumor, and Theoretical Implementations.

    abstract::Four pyrazolone derivatives and their corresponding silver complexes were synthesized and characterized. Based on elemental analysis, 1 : 2 (M : L) molar ratio was suggested for all inspected complexes. 1H, 13C NMR, mass, UV-Vis, TGA, and IR were the spectral tools used for describing the formulae. Moreover, XRD patte...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2018/2727619

    authors: Althagafi I,El-Metwaly NM,Elghalban MG,Farghaly TA,Khedr AM

    更新日期:2018-05-14 00:00:00

  • Antibacterial Activity of As-Annealed TiO2 Nanotubes Doped with Ag Nanoparticles against Periodontal Pathogens.

    abstract::It is important to develop functional transmucosal implant surfaces that reduce the number of initially adhering bacteria and they need to be modified to improve the anti-bacterial performance. Commercially pure Ti sheets were anodized in an electrolyte containing ethylene glycol, distilled water and ammonium fluoride...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2014/829496

    authors: Yeniyol S,He Z,Yüksel B,Boylan RJ,Urgen M,Ozdemir T,Ricci JL

    更新日期:2014-01-01 00:00:00

  • Metal-Based Antibacterial and Antifungal Agents: Synthesis, Characterization, and In Vitro Biological Evaluation of Co(II), Cu(II), Ni(II), and Zn(II) Complexes With Amino Acid-Derived Compounds.

    abstract::A series of antibacterial and antifungal amino acid-derived compounds and their cobalt(II), copper(II), nickel(II), and zinc(II) metal complexes have been synthesized and characterized by their elemental analyses, molar conductances, magnetic moments, and IR, and electronic spectral measurements. Ligands (L(1))-(L(5))...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/BCA/2006/83131

    authors: Chohan ZH,Arif M,Akhtar MA,Supuran CT

    更新日期:2006-01-01 00:00:00