Di-n-butyltin(IV) complexes derived from heterocyclic beta-diketones and N-phthaloyl amino acids: preparation, biological evaluation, structural elucidation based upon spectral [IR, NMR (1H, 13C, 19F and 119Sn)] studies.

Abstract:

:Stable, six coordinated Bu(2)SnLA type complexes have been prepared [where LH = RCOC:C(OH)N(C(6) H(5))N:CCH(3); R = -4-F-C(6)H(4)-(L(1)H), R = -4-Cl-C(6)H(4)-(L(2)H), R= -4-Br-C(6)H(4)-(L(3)H), R=-CF(3)(L(4)H) and AH = C(O)C(6) H(4) C(O)NCHR'COOH; R'= -H(A(1)H), -CH(3)(A(2)H), -CH(CH(3))(2)(A(3)H)] by the interaction of 1:1:1 molar ratios of di-n-butyltin(IV) dichloride with corresponding organic moieties in refluxing benzene using two moles of Et(3)N as a base. In these complexes LH and AH behave as bidentate and coordination is taking place through oxygen, this is inferred from IR and (13)C NMR studies. These complexes possess tin atoms in skew trapezoidal bipyramidal geometry with the C-Sn-C angles ranging from 149.88( degrees ) to 156.84( degrees ). Some of these complexes with their corresponding organic moieties (LH, AH) were tested for their antimicrobial activities.

journal_name

Bioinorg Chem Appl

authors

Joshi A,Verma S,Gaurb RB,Sharma RR

doi

10.1155/BCA.2005.201

subject

Has Abstract

pub_date

2005-01-01 00:00:00

pages

201-15

eissn

1565-3633

issn

1687-479X

pub_type

杂志文章
  • Impact of Different Serum Potassium Levels on Postresuscitation Heart Function and Hemodynamics in Patients with Nontraumatic Out-of-Hospital Cardiac Arrest.

    abstract:Background:Sustained return of spontaneous circulation (ROSC) can be initially established in patients with out-of-hospital cardiac arrest (OHCA); however, the early postresuscitation hemodynamics can still be impaired by high levels of serum potassium (hyperkalemia). The impact of different potassium levels on early p...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2018/5825929

    authors: Lin YR,Syue YJ,Lee TH,Chou CC,Chang CF,Li CJ

    更新日期:2018-04-05 00:00:00

  • Synthesis of Novel VO(II)-Perimidine Complexes: Spectral, Computational, and Antitumor Studies.

    abstract::A series of perimidine derivatives (L1-5) were prepared and characterized by IR, 1H·NMR, mass spectroscopy, UV-Vis, XRD, thermal, and SEM analysis. Five VO(II) complexes were synthesized and investigated by most previous tools besides the theoretical usage. A neutral tetradentate mode of bonding is the general approac...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2018/7176040

    authors: Al-Hazmi GA,Abou-Melha KS,El-Metwaly NM,Saleh KA

    更新日期:2018-09-06 00:00:00

  • Synthesis, Crystal Structure, Spectroscopic Properties, and Interaction with Ct-DNA of Zn(II) with 2-Aminoethanethiol Hydrochloride Ligand.

    abstract::The zinc(II) complex (C2H6NS)2Zn·ZnCl2 was synthesized with 2-aminoethanethiol hydrochloride and zinc sulfate heptahydrate as the raw materials in aqueous solution. The composition and structure of the complex were characterized by elemental analysis, infrared spectra, single crystal X-ray diffraction, and thermogravi...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2016/2691253

    authors: Shu XG,Wu CL,Li CJ,Zhang M,Wan K,Wu X

    更新日期:2016-01-01 00:00:00

  • DNA-Platinum Thin Films for Use in Chemoradiation Therapy Studies.

    abstract::Dry films of platinum chemotherapeutic drugs covalently bound to plasmid DNA (Pt-DNA) represent a useful experimental model to investigate direct effects of radiation on DNA in close proximity to platinum chemotherapeutic agents, a situation of considerable relevance to understand the mechanisms underlying concomitant...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2012/923914

    authors: Rezaee M,Alizadeh E,Hunting D,Sanche L

    更新日期:2012-01-01 00:00:00

  • Biosynthesis of Silver Nanoparticles Using Aegle marmelos (Bael) Fruit Extract and Its Application to Prevent Adhesion of Bacteria: A Strategy to Control Microfouling.

    abstract::Marine biofilms formed due to adhesion of bacteria and other microorganisms on submerged surfaces are generally considered to be a major form of microfouling. Subsequent attachment of larvae of higher organisms like barnacles, mussels, and so forth, on marine biofilms, causes macrofouling. Several approaches have been...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2014/949538

    authors: Nithya Deva Krupa A,Raghavan V

    更新日期:2014-01-01 00:00:00

  • Biosynthesis and Antimicrobial Activity of Semiconductor Nanoparticles against Oral Pathogens.

    abstract::Dental care is an essential phenomenon in human health. Oral pathogens can cause severe break which may show the way to serious issues in human disease like blood circulation and coronary disease. In the current study, we demonstrated the synthesis and antimicrobial activity of cadmium sulphide and zinc sulphide nanop...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2014/347167

    authors: Malarkodi C,Rajeshkumar S,Paulkumar K,Vanaja M,Gnanajobitha G,Annadurai G

    更新日期:2014-01-01 00:00:00

  • Coal Depolymerising Activity and Haloperoxidase Activity of Mn Peroxidase from Fomes durissimus MTCC-1173.

    abstract::Mn peroxidase has been purified to homogeneity from the culture filtrate of a new fungal strain Fomes durissimus MTCC-1173 using concentration by ultrafiltration and anion exchange chromatography on diethylaminoethyl (DEAE) cellulose. The molecular mass of the purified enzyme has been found to be 42.0 kDa using SDS-PA...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2011/260802

    authors: Singh SK,Yadav M,Yadava S,Yadav KD

    更新日期:2011-01-01 00:00:00

  • Assessment of Toxicity of Some Penta- and Hexacoordinated Organotin(IV) and Tetracoordinated Tin(II) Complexes of Heterocyclic beta-Diketones.

    abstract::A number of penta- and hexacoordinated organotin(IV) complexes and tetracoordinated tin(II) complexes of compositions Me2SnCl[RCOC:CON(C6H5)N:CCH3] (where R = - CH(3), -p-ClC(6)H(4), and -C(6)H(5)), Me2Sn[RCOC:CON(C6H5)N:CCH3]2 (where R = -CH(3), and -C(6)H(5)), and Sn(II) [RCOC:CON(C6H5)N:CCH3]2 (where R = -p-ClC(6)H...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/BCA/2006/60140

    authors: Jain A,Saxena S,Rai AK,Saxena PN

    更新日期:2006-01-01 00:00:00

  • The bioactivated interfacial behavior of the fluoridated hydroxyapatite-coated mg-zn alloy in cell culture environments.

    abstract::A partially fluorine substituted hydroxyapatite- (FHA-) coated Mg-Zn alloy was prepared to investigate the interfacial behavior of degradable Mg-based biomaterials with degradable bioactive coatings in a cell culture environment. Peaks from the results of X-ray diffraction (XRD) were characterized and compared before ...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2011/192671

    authors: Li J,Cao L,Song Y,Zhang S,Zhao C,Zhang F,Zhang X

    更新日期:2011-01-01 00:00:00

  • Kinetic Studies and Mechanism of Hydrogen Peroxide Catalytic Decomposition by Cu(II) Complexes with Polyelectrolytes Derived from L-Alanine and Glycylglycine.

    abstract::The catalytic decomposition of hydrogen peroxide by Cu(II) complexes with polymers bearing L-alanine (PAla) and glycylglycine (PGlygly) in their side chain was studied in alkaline aqueous media. The reactions were of pseudo-first order with respect to [H(2)O(2)] and [L-Cu(II)] (L stands for PAla or PGlygly) and the re...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2010/643120

    authors: Skounas S,Methenitis C,Pneumatikakis G,Morcellet M

    更新日期:2010-01-01 00:00:00

  • Preparation, Characterization, and Antimicrobial Activities of Bimetallic Complexes of Sarcosine with Zn(II) and Sn(IV).

    abstract::Heterobimetallic complexes of Zn(II) and Sn(IV) with sarcosine have been synthesized at room temperature under stirring conditions by the reaction of sarcosine and zinc acetate in 2 : 1 molar ratio followed by the stepwise addition of CS2 and organotin(IV) halides, where R = Me, n-Bu, and Ph. The complexes were charac...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2013/351262

    authors: Arafat Y,Ali S,Shahzadi S,Shahid M

    更新日期:2013-01-01 00:00:00

  • Antimicrobial applications of transition metal complexes of benzothiazole based terpolymer: synthesis, characterization, and effect on bacterial and fungal strains.

    abstract::Terpolymer of 2-amino-6-nitro-benzothiazole-ethylenediamine-formaldehyde (BEF) has been synthesized and characterized by elemental analysis and various spectral techniques like FTIR, UV-Visible, and (1)H and (13)C-NMR. The terpolymer metal complexes were prepared with Cu(2+), Ni(2+), and Zn(2+) metal ions using BEF te...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2014/764085

    authors: Riswan Ahamed MA,Azarudeen RS,Kani NM

    更新日期:2014-01-01 00:00:00

  • Physicochemical properties and cellular responses of strontium-doped gypsum biomaterials.

    abstract::This paper describes some physical, structural, and biological properties of gypsum bioceramics doped with various amounts of strontium ions (0.19-2.23 wt%) and compares these properties with those of a pure gypsum as control. Strontium-doped gypsum (gypsum:Sr) was obtained by mixing calcium sulfate hemihydrate powder...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2012/976495

    authors: Pouria A,Bandegani H,Pourbaghi-Masouleh M,Hesaraki S,Alizadeh M

    更新日期:2012-01-01 00:00:00

  • Contribution of Shellfish Consumption to Lower Mercury Health Risk for Residents in Northern Jiaozhou Bay, China.

    abstract::Fish and marine mammal consumption are an important pathway for human exposure to mercury. The low mercury content in shellfish poses a low mercury health risk to people who consume shellfish. The objectives of this study are to detect mercury concentrations in different species of shellfish and to calculate the mercu...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2015/159521

    authors: Zhang L,Zhang L

    更新日期:2015-01-01 00:00:00

  • Synthesis and characterization of bis[(2-ethyl-5-methyl-imidazo-4-yl)methyl]sulfide and its coordination behavior toward Cu(II) as a possible approach of a copper site type I.

    abstract::The synthesis and characterization of a novel ligand, bis[(2-ethyl-5-methyl-imidazo-4-yl)methyl]sulfide (bemims), as well as a bemims-containing copper(II) coordination complex are described. In this complex, [Cu(bemims)X(2)] with X = NO(3) (-), bemims acts as a tridentate ligand and two monodentate nitrate ions compl...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2009/905320

    authors: Barrón-Garcés JD,Mendoza-Díaz G,Vilchez-Aguado F,Bernès S

    更新日期:2009-01-01 00:00:00

  • Degradation of single stranded nucleic acids by the chemical nuclease activity of the metal complex [Cu(phen)(nal)]+.

    abstract::The chemical design of metal complexes of the type [Cu(phen)(antib)](+) (where antib is a quinolone or a fluoroquinolone) has been carried out in an approach to better understand how the coordination of their components affect the activity of quinolones. The ability of [Cu(phen)(nal)](+) to interact with DNA in vivo a...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/S1565363303000025

    authors: Ramírez-Ramírez N,Mendoza-Díaz G,Pedraza-Reyes M

    更新日期:2003-01-01 00:00:00

  • In Vivo Radionuclide Generators for Diagnostics and Therapy.

    abstract::In vivo radionuclide generators make complex combinations of physical and chemical properties available for medical diagnostics and therapy. Perhaps the best-known in vivo generator is 212Pb/212Bi, which takes advantage of the extended half-life of 212Pb to execute a targeted delivery of the therapeutic short-lived α-...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章,评审

    doi:10.1155/2016/6148357

    authors: Edem PE,Fonslet J,Kjær A,Herth M,Severin G

    更新日期:2016-01-01 00:00:00

  • Antibacterial Activity of As-Annealed TiO2 Nanotubes Doped with Ag Nanoparticles against Periodontal Pathogens.

    abstract::It is important to develop functional transmucosal implant surfaces that reduce the number of initially adhering bacteria and they need to be modified to improve the anti-bacterial performance. Commercially pure Ti sheets were anodized in an electrolyte containing ethylene glycol, distilled water and ammonium fluoride...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2014/829496

    authors: Yeniyol S,He Z,Yüksel B,Boylan RJ,Urgen M,Ozdemir T,Ricci JL

    更新日期:2014-01-01 00:00:00

  • Metal-Based Antibacterial and Antifungal Agents: Synthesis, Characterization, and In Vitro Biological Evaluation of Co(II), Cu(II), Ni(II), and Zn(II) Complexes With Amino Acid-Derived Compounds.

    abstract::A series of antibacterial and antifungal amino acid-derived compounds and their cobalt(II), copper(II), nickel(II), and zinc(II) metal complexes have been synthesized and characterized by their elemental analyses, molar conductances, magnetic moments, and IR, and electronic spectral measurements. Ligands (L(1))-(L(5))...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/BCA/2006/83131

    authors: Chohan ZH,Arif M,Akhtar MA,Supuran CT

    更新日期:2006-01-01 00:00:00

  • Spectroscopic, Thermal, Electrochemical, and Antimicrobial Studies of Mononuclear Manganese(II) Ditolyldithiophosphates.

    abstract::New complexes of manganese(II) corresponding to [{(ArO)2PS2}2Mn] and [{(ArO)2PS2}2Mn.nL] (Ar = o-, m-, p-CH3C6H4 and p-Cl-m-CH3C6H3; n = 1, L = N2C12H8, N2C10H8; n = 2, L = NC5H5, P(C6H5)3) have been synthesized and characterized by microelemental analyses (C, H, and N), magnetic susceptibility, molar conductance, the...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2013/261731

    authors: Khajuria R,Syed A,Kumar S,Pandey SK

    更新日期:2013-01-01 00:00:00

  • Adsorption Characteristics of Bixin on Acid- and Alkali-Treated Kaolinite in Aprotic Solvents.

    abstract::The adsorption of bixin in aprotic solvents onto acid- and alkali-treated kaolinite was investigated. Kaolinite was treated three times, for 6 h each, with 8 M HCl or 5 M KOH. The adsorbents were characterized by XRD, FT-IR, EDS, and BET-N2. The effects of contact time and dye concentration on adsorption capacity and ...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2018/3805654

    authors: Rahmalia W,Fabre JF,Usman T,Mouloungui Z

    更新日期:2018-01-18 00:00:00

  • Inferences on the nature of a Cr(V) or Cr(IV) species formed by reduction of dichromate by a bovine liver homogenate: NMR and mass-spectrometric studies.

    abstract::A low-molecular weight chromium-containing fraction of the material resulting from dichromate reduction by bovine liver homogenate was investigated by NMR and ES-MS. The ES-MS spectrum showed a readily detectable peak at m/z = 786.1. The same molecular weight reasonably agreed with the relatively low diffusion coeffic...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/S1565363303000220

    authors: Gaggelli E,D'Amelio N,Gaggelli N,Valensin G,Bovalini L,Paffetti A,Trabalzini L

    更新日期:2003-01-01 00:00:00

  • Synthesis, Structure, DNA Interaction, and SOD Activity of Three Nickel(II) Complexes Containing L-Phenylalanine Schiff Base and 1,10-Phenanthroline.

    abstract::Three hexacoordinated octahedral nickel(II) complexes, [Ni(sal-L-phe)(phen)(CH3OH)]·CH3OH (1), [Ni(naph-L-phe)(phen)(CH3OH)] (2), and [Ni(o-van-L-phe)(phen)(CH3OH)]·5CH3OH (3) (sal-L-phe = a Schiff base derived from salicylaldehyde and L-phenylalanine, naph-L-phe = a Schiff base derived from 2-hydroxy-1-naphthaldehyde...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2018/8478152

    authors: Zhao P,Zhai S,Dong J,Gao L,Liu X,Wang L,Kong J,Li L

    更新日期:2018-07-05 00:00:00

  • DNA Binding and Antitumor Activity of α-Diimineplatinum(II) and Palladium(II) Dithiocarbamate Complexes.

    abstract::The two water-soluble designed platinum(II) complex, [Pt(Oct-dtc)(bpy)]NO(3) (Oct-dtc = Octyldithiocarbamate and bpy = 2,2' -bipyridine) and palladium(II) complex, [Pd(Oct-dtc)(bpy)]NO(3), have been synthesized and characterized by elemental analyses, molar conductivity measurements, IR, (1)H NMR, and electronic spect...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2011/394506

    authors: Mansouri-Torshizi H,Saeidifar M,Khosravi F,Divsalar A,Saboury AA,Hassani F

    更新日期:2011-01-01 00:00:00

  • Co(III) and Ni(II) complexes containing bioactive ligands: synthesis, DNA binding, and photocleavage studies.

    abstract::DNA binding and photocleavage characteristics of a series of mixed ligand complexes of the type [M(bpy)(2)qbdp](PF(6))(n).xH(2)O (where M = Co(III) or Ni(II), bpy = 2.2'-bipryidine, qbdp = Quinolino[3,2-b]benzodiazepine, n = 3 or 2 and x = 5 or 2) have been investigated. The DNA binding property of the complexes with ...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2007/36497

    authors: Prabhakara MC,Basavaraju B,Naik HS

    更新日期:2007-01-01 00:00:00

  • Objectives and methods of iron chelation therapy.

    abstract::Recent developments in the understanding of the molecular control of iron homeostasis provided novel insights into the mechanisms responsible for normal iron balance. However in chronic anemias associated with iron overload, such mechanisms are no longer sufficient to offer protection from iron toxicity, and iron chel...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/S1565363303000128

    authors: Hershko C,Abrahamov A,Konijn AM,Breuer W,Cabantchik IZ,Pootrakul P,Link G

    更新日期:2003-01-01 00:00:00

  • Stabilization of submicron calcium oxalate suspension by chondroitin sulfate C may be an efficient protection from stone formation.

    abstract::The influences of chondroitin sulfate C (C6S) on size, aggregation, sedimentation, and Zeta potential of sub-micron calcium oxalate monohydrate (COM) and calcium oxalate dihydrate (COD) crystallites with mean sizes of about 330 nm were investigated using an X-ray diffractometer, nanoparticle size Zeta potential analyz...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2013/360142

    authors: Li JJ,Xue JF,Ouyang JM

    更新日期:2013-01-01 00:00:00

  • Spectroscopic, thermal and biological studies on some trivalent ruthenium and rhodium NS chelating thiosemicarbazone complexes.

    abstract::The synthetic, spectroscopic, and biological studies of sixteen ring-substituted 4-phenylthiosemicarbazones and 4-nitrophenyl-thiosemicarbazones of anisaldehyde, 4-chlorobenzaldehyde, 4-fluorobenzaldehyde, and vanillin with ruthenium(III) and rhodium(III) chlorides are reported here. Their structures were determined o...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2007/68374

    authors: Sharma VK,Srivastava S,Srivastava A

    更新日期:2007-01-01 00:00:00

  • Novel Gallium(III), Germanium(IV), and Hafnium(IV) Folate Complexes and Their Spectroscopic, Thermal Decomposition, Morphological, and Biological Characteristics.

    abstract::In this study, we describe novel gallium(III), germanium(IV), and hafnium(IV) folate complexes, including their synthesis and analyses. The synthesized folate complexes were also subject to thermal analysis (TGA) to better examine their thermal degradation and kinetic properties. The folate complexes had high stabilit...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2020/6678688

    authors: El-Habeeb AA

    更新日期:2020-12-18 00:00:00

  • Synthesis and Characterization of Green Zinc Oxide Nanoparticles with Antiproliferative Effects through Apoptosis Induction and MicroRNA Modulation in Breast Cancer Cells.

    abstract::Changes in the expression of microRNAs can affect cancer cells' viability and behavior and the impact on cancer treatment. In this study, the expression of miR-155-5p, miR-203a-3p, and miR-223-3p in the MCF7 cancer cell line was studied when exposed to ZnO nanoparticles synthesized through a green route. Mentioned ZnO...

    journal_title:Bioinorganic chemistry and applications

    pub_type: 杂志文章

    doi:10.1155/2020/8817110

    authors: Aalami AH,Mesgari M,Sahebkar A

    更新日期:2020-11-20 00:00:00