Assessment of Toxicity of Some Penta- and Hexacoordinated Organotin(IV) and Tetracoordinated Tin(II) Complexes of Heterocyclic beta-Diketones.

abstract：:Marine biofilms formed due to adhesion of bacteria and other microorganisms on submerged surfaces are generally considered to be a major form of microfouling. Subsequent attachment of larvae of higher organisms like barnacles, mussels, and so forth, on marine biofilms, causes macrofouling. Several approaches have been...

journal_title：Bioinorganic chemistry and applications

authors： Nithya Deva Krupa A,Raghavan V

更新日期：2014-01-01 00:00:00

abstract：:Three hexacoordinated octahedral nickel(II) complexes, [Ni(sal-L-phe)(phen)(CH3OH)]·CH3OH (1), [Ni(naph-L-phe)(phen)(CH3OH)] (2), and [Ni(o-van-L-phe)(phen)(CH3OH)]·5CH3OH (3) (sal-L-phe = a Schiff base derived from salicylaldehyde and L-phenylalanine, naph-L-phe = a Schiff base derived from 2-hydroxy-1-naphthaldehyde...

journal_title：Bioinorganic chemistry and applications

authors： Zhao P,Zhai S,Dong J,Gao L,Liu X,Wang L,Kong J,Li L

更新日期：2018-07-05 00:00:00

abstract：:The toxicity mechanisms of mercury and tin organic derivatives are still under debate. Generally the presence of organic moieties in their molecules makes these compounds lipophilic and membrane active species. The recent results suggest that Hg and Sn compounds deplete HS-groups in proteins, glutathione and glutathio...

journal_title：Bioinorganic chemistry and applications

authors： Milaeva E,Petrosyan V,Berberova N,Pimenov Y,Pellerito L

更新日期：2004-01-01 00:00:00

abstract：:The synthetic, spectroscopic, and biological studies of sixteen ring-substituted 4-phenylthiosemicarbazones and 4-nitrophenyl-thiosemicarbazones of anisaldehyde, 4-chlorobenzaldehyde, 4-fluorobenzaldehyde, and vanillin with ruthenium(III) and rhodium(III) chlorides are reported here. Their structures were determined o...

journal_title：Bioinorganic chemistry and applications

authors： Sharma VK,Srivastava S,Srivastava A

更新日期：2007-01-01 00:00:00

abstract：:Terpolymer of 2-amino-6-nitro-benzothiazole-ethylenediamine-formaldehyde (BEF) has been synthesized and characterized by elemental analysis and various spectral techniques like FTIR, UV-Visible, and (1)H and (13)C-NMR. The terpolymer metal complexes were prepared with Cu(2+), Ni(2+), and Zn(2+) metal ions using BEF te...

journal_title：Bioinorganic chemistry and applications

authors： Riswan Ahamed MA,Azarudeen RS,Kani NM

更新日期：2014-01-01 00:00:00

abstract：:The N- and C-terminal blocked hexapeptide Ac-Leu-Ala-His-Tyr-Asn-Lys-amide (LAHYNK) representing the 80-85 fragment of histone H2B was synthesized and its interactions with Cu(II) and Ni(II) ions were studied by potentiometric, UV-Vis, CD, EPR, and NMR spectroscopic techniques in solution. Our data reveal that the imi...

journal_title：Bioinorganic chemistry and applications

authors： Panagiotou K,Panagopoulou M,Karavelas T,Dokorou V,Hagarman A,Soffer J,Schweitzer-Stenner R,Malandrinos G,Hadjiliadis N

更新日期：2008-01-01 00:00:00

abstract：:Two oxovanadium(IV) complexes of [VO(msatsc)(phen)], (1) (msatsc = methoxylsalicylaldehyde thiosemicarbazone, phen = phenanthroline) and its novel derivative [VO (4-chlorosatsc)(phen)], (2) (4-chlorosatsc = 4-chlorosalicylaldehyde thiosemicarbazone), have been synthesized and characterized by elemental analysis, IR, E...

journal_title：Bioinorganic chemistry and applications

authors： Zhang Y,Wang X,Fang W,Cai X,Chu F,Liao X,Lu J

更新日期：2013-01-01 00:00:00

abstract：:A series of antibacterial and antifungal amino acid-derived compounds and their cobalt(II), copper(II), nickel(II), and zinc(II) metal complexes have been synthesized and characterized by their elemental analyses, molar conductances, magnetic moments, and IR, and electronic spectral measurements. Ligands (L(1))-(L(5))...

journal_title：Bioinorganic chemistry and applications

authors： Chohan ZH,Arif M,Akhtar MA,Supuran CT

更新日期：2006-01-01 00:00:00

abstract：:The zinc(II) complex (C2H6NS)2Zn·ZnCl2 was synthesized with 2-aminoethanethiol hydrochloride and zinc sulfate heptahydrate as the raw materials in aqueous solution. The composition and structure of the complex were characterized by elemental analysis, infrared spectra, single crystal X-ray diffraction, and thermogravi...

journal_title：Bioinorganic chemistry and applications

authors： Shu XG,Wu CL,Li CJ,Zhang M,Wan K,Wu X

更新日期：2016-01-01 00:00:00

abstract：:A low-molecular weight chromium-containing fraction of the material resulting from dichromate reduction by bovine liver homogenate was investigated by NMR and ES-MS. The ES-MS spectrum showed a readily detectable peak at m/z = 786.1. The same molecular weight reasonably agreed with the relatively low diffusion coeffic...

journal_title：Bioinorganic chemistry and applications

authors： Gaggelli E,D'Amelio N,Gaggelli N,Valensin G,Bovalini L,Paffetti A,Trabalzini L

更新日期：2003-01-01 00:00:00

abstract：:The two water-soluble designed platinum(II) complex, [Pt(Oct-dtc)(bpy)]NO(3) (Oct-dtc = Octyldithiocarbamate and bpy = 2,2' -bipyridine) and palladium(II) complex, [Pd(Oct-dtc)(bpy)]NO(3), have been synthesized and characterized by elemental analyses, molar conductivity measurements, IR, (1)H NMR, and electronic spect...

journal_title：Bioinorganic chemistry and applications

authors： Mansouri-Torshizi H,Saeidifar M,Khosravi F,Divsalar A,Saboury AA,Hassani F

更新日期：2011-01-01 00:00:00

abstract：:In this study, we describe novel gallium(III), germanium(IV), and hafnium(IV) folate complexes, including their synthesis and analyses. The synthesized folate complexes were also subject to thermal analysis (TGA) to better examine their thermal degradation and kinetic properties. The folate complexes had high stabilit...

journal_title：Bioinorganic chemistry and applications

authors： El-Habeeb AA

更新日期：2020-12-18 00:00:00

abstract：:Antifertility and histopathological investigations were carried out on reproductive organs of male albino rats induced by tetraazamacrocyclic complexes of iron(II). The complexes were synthesized by the template condensation of 1,2-diaminoethane, 1,3-diaminopropane with succinic acid and phthalic acid in 2 : 2 molar r...

journal_title：Bioinorganic chemistry and applications

authors： Chaudhary A,Singh RV

更新日期：2006-01-01 00:00:00

abstract：:Changes in the expression of microRNAs can affect cancer cells' viability and behavior and the impact on cancer treatment. In this study, the expression of miR-155-5p, miR-203a-3p, and miR-223-3p in the MCF7 cancer cell line was studied when exposed to ZnO nanoparticles synthesized through a green route. Mentioned ZnO...

journal_title：Bioinorganic chemistry and applications

authors： Aalami AH,Mesgari M,Sahebkar A

更新日期：2020-11-20 00:00:00

abstract：:Biosorption experiment from aqueous solutions containing known amount of rare earth elements (REEs) using pre-treated Buccinum tenuissimum shell was explored to evaluate the efficiency of shell biomass as sorbent for REEs. In this work, four kinds of sieved shell samples: (a) "Ground original sample", (b) "Heat-treatm...

journal_title：Bioinorganic chemistry and applications

authors： Koto Y,Kano N,Wang Y,Sakamoto N,Imaizumi H

更新日期：2010-01-01 00:00:00

abstract：:The thermodynamic equilibria of nickel(II) with N,N'-di(aminoethylene)-2,6-pyridinedicarbonylamine (L1), Bis-(N,N-dimethylethyl)-2,6-pyridinedicarboxamide (L2), and N,N'-bis[2(2-pyridyl)-methyl]pyridine-2,6-dicarboxamide (L3) have been studied at 25°C and an ionic strength of 0.15 mol dm(-3) by glass electrode potenti...

journal_title：Bioinorganic chemistry and applications

authors： Odisitse S,Jackson GE

更新日期：2014-01-01 00:00:00

abstract：:The Rieske iron-sulfur protein, one of the catalytic subunits of the cytochrome bc(1) complex, is involved in electron transfer at the level of the inner membrane of yeast mitochondria. The Rieske iron-sulfur protein is encoded by nuclear DNA and, after being synthesized in the cytosol, is imported into mitochondria w...

journal_title：Bioinorganic chemistry and applications

authors： Conte L,Zara V

更新日期：2011-01-01 00:00:00

abstract：:The synthesis and characterization of a novel ligand, bis[(2-ethyl-5-methyl-imidazo-4-yl)methyl]sulfide (bemims), as well as a bemims-containing copper(II) coordination complex are described. In this complex, [Cu(bemims)X(2)] with X = NO(3) (-), bemims acts as a tridentate ligand and two monodentate nitrate ions compl...

journal_title：Bioinorganic chemistry and applications

authors： Barrón-Garcés JD,Mendoza-Díaz G,Vilchez-Aguado F,Bernès S

更新日期：2009-01-01 00:00:00

abstract：:Recent developments in the understanding of the molecular control of iron homeostasis provided novel insights into the mechanisms responsible for normal iron balance. However in chronic anemias associated with iron overload, such mechanisms are no longer sufficient to offer protection from iron toxicity, and iron chel...

journal_title：Bioinorganic chemistry and applications

authors： Hershko C,Abrahamov A,Konijn AM,Breuer W,Cabantchik IZ,Pootrakul P,Link G

更新日期：2003-01-01 00:00:00

abstract：:Terminally protected pentapeptides with 2 histidines (Ac-HHVGD-NH(2) and Ac-HVGDH-NH(2)) and the terminally free peptides containing both internal aspartyl and C-terminal histidyl residues (FDAH and VIDAH) have been synthesized, and copper(II) complexes studied by potentiometric, UV-Vis, CD, and EPR spectroscopic tech...

journal_title：Bioinorganic chemistry and applications

authors： Kállay C,Nagy Z,Várnagy K,Malandrinos G,Hadjiliadis N,Sóvágó I

更新日期：2007-01-01 00:00:00

abstract：:Fish and marine mammal consumption are an important pathway for human exposure to mercury. The low mercury content in shellfish poses a low mercury health risk to people who consume shellfish. The objectives of this study are to detect mercury concentrations in different species of shellfish and to calculate the mercu...

journal_title：Bioinorganic chemistry and applications

authors： Zhang L,Zhang L

更新日期：2015-01-01 00:00:00

abstract：:Water disinfection has attracted the attention of scientists worldwide due to water scarcity. The most significant challenges are determining how to achieve proper disinfection without producing harmful byproducts obtained usually using conventional chemical disinfectants and developing new point-of-use methods for th...

journal_title：Bioinorganic chemistry and applications

authors： Al-Hakami SM,Khalil AB,Laoui T,Atieh MA

更新日期：2013-01-01 00:00:00

abstract：:Hemoglobin- (Hb-) based oxygen carriers (HBOC) have for several decades been explored for treatment of hemorrhage. In our previous top-up tests, HBOC with lower in vitro prooxidant reactivity (incorporating a peroxidase or serum albumin to this end) showed a measurable but small improvement of oxidative stress-related...

journal_title：Bioinorganic chemistry and applications

authors： Farcas AD,Toma VA,Roman I,Sevastre B,Scurtu F,Silaghi-Dumitrescu R

更新日期：2020-09-01 00:00:00

abstract：:Rice husk is an abundant agricultural by-product reaching the output of 80 million tons annually in the world. The most common treatment method of rice husk is burning or burying, which caused serious air pollution and resource waste. In order to solve this problem, a new method is proposed to comprehensively utilize ...

journal_title：Bioinorganic chemistry and applications

authors： Zhang H,Ding X,Wang Z,Zhao X

更新日期：2014-01-01 00:00:00

abstract：:Four pyrazolone derivatives and their corresponding silver complexes were synthesized and characterized. Based on elemental analysis, 1 : 2 (M : L) molar ratio was suggested for all inspected complexes. 1H, 13C NMR, mass, UV-Vis, TGA, and IR were the spectral tools used for describing the formulae. Moreover, XRD patte...

journal_title：Bioinorganic chemistry and applications

authors： Althagafi I,El-Metwaly NM,Elghalban MG,Farghaly TA,Khedr AM

更新日期：2018-05-14 00:00:00

abstract：:The incorporation of benzene-l,2-dithiolato building blocks into supramolecular coordination assemblies is the main objective of the investigations described here. Special interest is directed towards dinuclear complexes with bis(benzene-l,2-dithiolato) ligands, which might be able to form helical structures. Bis(benz...

journal_title：Bioinorganic chemistry and applications

authors： Seidel WW,Hahn FE

更新日期：2005-01-01 00:00:00

abstract：:The highly water-soluble ruthenium complex [Ru(H(2)L)Cl(2)](2)H(2)o, in which H(4)L is the sequestering ligand trans-l, 2-cyclohexanediamminetetraacetic acid (cdta) has been synthesized, structurally characterized and its properties studied. The X-ray crystallographic study shows that the chelating coordinated ligand ...

journal_title：Bioinorganic chemistry and applications

authors： Vilaplana RA,Castiñeiras A,González-Vílchez F

更新日期：2004-01-01 00:00:00

abstract：:A partially fluorine substituted hydroxyapatite- (FHA-) coated Mg-Zn alloy was prepared to investigate the interfacial behavior of degradable Mg-based biomaterials with degradable bioactive coatings in a cell culture environment. Peaks from the results of X-ray diffraction (XRD) were characterized and compared before ...

journal_title：Bioinorganic chemistry and applications

authors： Li J,Cao L,Song Y,Zhang S,Zhao C,Zhang F,Zhang X

更新日期：2011-01-01 00:00:00

abstract：:Mn peroxidase has been purified to homogeneity from the culture filtrate of a new fungal strain Fomes durissimus MTCC-1173 using concentration by ultrafiltration and anion exchange chromatography on diethylaminoethyl (DEAE) cellulose. The molecular mass of the purified enzyme has been found to be 42.0 kDa using SDS-PA...

journal_title：Bioinorganic chemistry and applications

authors： Singh SK,Yadav M,Yadava S,Yadav KD

更新日期：2011-01-01 00:00:00

abstract：:Heterobimetallic complexes of Zn(II) and Sn(IV) with sarcosine have been synthesized at room temperature under stirring conditions by the reaction of sarcosine and zinc acetate in 2 : 1 molar ratio followed by the stepwise addition of CS2 and organotin(IV) halides, where R = Me, n-Bu, and Ph. The complexes were charac...

journal_title：Bioinorganic chemistry and applications

authors： Arafat Y,Ali S,Shahzadi S,Shahid M

更新日期：2013-01-01 00:00:00