Thermodynamic and structural characterization of the copper(II) complexes of peptides containing both histidyl and aspartyl residues.

abstract：:The Rieske iron-sulfur protein, one of the catalytic subunits of the cytochrome bc(1) complex, is involved in electron transfer at the level of the inner membrane of yeast mitochondria. The Rieske iron-sulfur protein is encoded by nuclear DNA and, after being synthesized in the cytosol, is imported into mitochondria w...

journal_title：Bioinorganic chemistry and applications

authors： Conte L,Zara V

更新日期：2011-01-01 00:00:00

abstract：:Rice husk is an abundant agricultural by-product reaching the output of 80 million tons annually in the world. The most common treatment method of rice husk is burning or burying, which caused serious air pollution and resource waste. In order to solve this problem, a new method is proposed to comprehensively utilize ...

journal_title：Bioinorganic chemistry and applications

authors： Zhang H,Ding X,Wang Z,Zhao X

更新日期：2014-01-01 00:00:00

abstract：:Hemoglobin- (Hb-) based oxygen carriers (HBOC) have for several decades been explored for treatment of hemorrhage. In our previous top-up tests, HBOC with lower in vitro prooxidant reactivity (incorporating a peroxidase or serum albumin to this end) showed a measurable but small improvement of oxidative stress-related...

journal_title：Bioinorganic chemistry and applications

authors： Farcas AD,Toma VA,Roman I,Sevastre B,Scurtu F,Silaghi-Dumitrescu R

更新日期：2020-09-01 00:00:00

abstract：:The synthesis and characterization of a novel ligand, bis[(2-ethyl-5-methyl-imidazo-4-yl)methyl]sulfide (bemims), as well as a bemims-containing copper(II) coordination complex are described. In this complex, [Cu(bemims)X(2)] with X = NO(3) (-), bemims acts as a tridentate ligand and two monodentate nitrate ions compl...

journal_title：Bioinorganic chemistry and applications

authors： Barrón-Garcés JD,Mendoza-Díaz G,Vilchez-Aguado F,Bernès S

更新日期：2009-01-01 00:00:00

abstract：:The incorporation of benzene-l,2-dithiolato building blocks into supramolecular coordination assemblies is the main objective of the investigations described here. Special interest is directed towards dinuclear complexes with bis(benzene-l,2-dithiolato) ligands, which might be able to form helical structures. Bis(benz...

journal_title：Bioinorganic chemistry and applications

authors： Seidel WW,Hahn FE

更新日期：2005-01-01 00:00:00

abstract：:Terpolymer of 2-amino-6-nitro-benzothiazole-ethylenediamine-formaldehyde (BEF) has been synthesized and characterized by elemental analysis and various spectral techniques like FTIR, UV-Visible, and (1)H and (13)C-NMR. The terpolymer metal complexes were prepared with Cu(2+), Ni(2+), and Zn(2+) metal ions using BEF te...

journal_title：Bioinorganic chemistry and applications

authors： Riswan Ahamed MA,Azarudeen RS,Kani NM

更新日期：2014-01-01 00:00:00

abstract：:The chemical design of metal complexes of the type [Cu(phen)(antib)](+) (where antib is a quinolone or a fluoroquinolone) has been carried out in an approach to better understand how the coordination of their components affect the activity of quinolones. The ability of [Cu(phen)(nal)](+) to interact with DNA in vivo a...

journal_title：Bioinorganic chemistry and applications

authors： Ramírez-Ramírez N,Mendoza-Díaz G,Pedraza-Reyes M

更新日期：2003-01-01 00:00:00

abstract：:In this work we present a structural and spectroscopic analysis of a copper(II) N-acetyl-5-arylidene tetramic acid by using both experimental and computational techniques. The crystal structure of the Cu(II) complex was determined by single crystal X-ray diffraction and shows that the copper ion lies on a centre of sy...

journal_title：Bioinorganic chemistry and applications

authors： Matiadis D,Tsironis D,Stefanou V,Igglessi-Markopoulou O,McKee V,Sanakis Y,Lazarou KN,Chrissanthopoulos A,Yannopoulos SN,Markopoulos JM

更新日期：2017-01-01 00:00:00

abstract：:Antifertility and histopathological investigations were carried out on reproductive organs of male albino rats induced by tetraazamacrocyclic complexes of iron(II). The complexes were synthesized by the template condensation of 1,2-diaminoethane, 1,3-diaminopropane with succinic acid and phthalic acid in 2 : 2 molar r...

journal_title：Bioinorganic chemistry and applications

authors： Chaudhary A,Singh RV

更新日期：2006-01-01 00:00:00

abstract：:The N- and C-terminal blocked hexapeptide Ac-Leu-Ala-His-Tyr-Asn-Lys-amide (LAHYNK) representing the 80-85 fragment of histone H2B was synthesized and its interactions with Cu(II) and Ni(II) ions were studied by potentiometric, UV-Vis, CD, EPR, and NMR spectroscopic techniques in solution. Our data reveal that the imi...

journal_title：Bioinorganic chemistry and applications

authors： Panagiotou K,Panagopoulou M,Karavelas T,Dokorou V,Hagarman A,Soffer J,Schweitzer-Stenner R,Malandrinos G,Hadjiliadis N

更新日期：2008-01-01 00:00:00

abstract：:The complex [ReOCl(3)pq] (1) (where pq = 2-(2'pyridyl)quinoxaline) has been synthesized and fully characterized by UV-Vis, FTIR, 1 and 2D NMR, and cyclic voltammetry (CV). The DNA-binding properties of the complex 1 as well as of the compounds [ReOCl(3)bpy] (2), [ReOCl(3)phen] (3), and pq (4) were investigated by UV-s...

journal_title：Bioinorganic chemistry and applications

authors： Mitsopoulou CA,Dagas C

更新日期：2010-01-01 00:00:00

abstract：:Fish and marine mammal consumption are an important pathway for human exposure to mercury. The low mercury content in shellfish poses a low mercury health risk to people who consume shellfish. The objectives of this study are to detect mercury concentrations in different species of shellfish and to calculate the mercu...

journal_title：Bioinorganic chemistry and applications

authors： Zhang L,Zhang L

更新日期：2015-01-01 00:00:00

abstract：:A series of perimidine derivatives (L1-5) were prepared and characterized by IR, 1H·NMR, mass spectroscopy, UV-Vis, XRD, thermal, and SEM analysis. Five VO(II) complexes were synthesized and investigated by most previous tools besides the theoretical usage. A neutral tetradentate mode of bonding is the general approac...

journal_title：Bioinorganic chemistry and applications

authors： Al-Hazmi GA,Abou-Melha KS,El-Metwaly NM,Saleh KA

更新日期：2018-09-06 00:00:00

abstract：:The two water-soluble designed platinum(II) complex, [Pt(Oct-dtc)(bpy)]NO(3) (Oct-dtc = Octyldithiocarbamate and bpy = 2,2' -bipyridine) and palladium(II) complex, [Pd(Oct-dtc)(bpy)]NO(3), have been synthesized and characterized by elemental analyses, molar conductivity measurements, IR, (1)H NMR, and electronic spect...

journal_title：Bioinorganic chemistry and applications

authors： Mansouri-Torshizi H,Saeidifar M,Khosravi F,Divsalar A,Saboury AA,Hassani F

更新日期：2011-01-01 00:00:00

abstract：:The highly water-soluble ruthenium complex [Ru(H(2)L)Cl(2)](2)H(2)o, in which H(4)L is the sequestering ligand trans-l, 2-cyclohexanediamminetetraacetic acid (cdta) has been synthesized, structurally characterized and its properties studied. The X-ray crystallographic study shows that the chelating coordinated ligand ...

journal_title：Bioinorganic chemistry and applications

authors： Vilaplana RA,Castiñeiras A,González-Vílchez F

更新日期：2004-01-01 00:00:00

abstract：:New complexes of manganese(II) corresponding to [{(ArO)2PS2}2Mn] and [{(ArO)2PS2}2Mn.nL] (Ar = o-, m-, p-CH3C6H4 and p-Cl-m-CH3C6H3; n = 1, L = N2C12H8, N2C10H8; n = 2, L = NC5H5, P(C6H5)3) have been synthesized and characterized by microelemental analyses (C, H, and N), magnetic susceptibility, molar conductance, the...

journal_title：Bioinorganic chemistry and applications

authors： Khajuria R,Syed A,Kumar S,Pandey SK

更新日期：2013-01-01 00:00:00

abstract：:The catalytic decomposition of hydrogen peroxide by Cu(II) complexes with polymers bearing L-alanine (PAla) and glycylglycine (PGlygly) in their side chain was studied in alkaline aqueous media. The reactions were of pseudo-first order with respect to [H(2)O(2)] and [L-Cu(II)] (L stands for PAla or PGlygly) and the re...

journal_title：Bioinorganic chemistry and applications

authors： Skounas S,Methenitis C,Pneumatikakis G,Morcellet M

更新日期：2010-01-01 00:00:00

abstract：:Three hexacoordinated octahedral nickel(II) complexes, [Ni(sal-L-phe)(phen)(CH3OH)]·CH3OH (1), [Ni(naph-L-phe)(phen)(CH3OH)] (2), and [Ni(o-van-L-phe)(phen)(CH3OH)]·5CH3OH (3) (sal-L-phe = a Schiff base derived from salicylaldehyde and L-phenylalanine, naph-L-phe = a Schiff base derived from 2-hydroxy-1-naphthaldehyde...

journal_title：Bioinorganic chemistry and applications

authors： Zhao P,Zhai S,Dong J,Gao L,Liu X,Wang L,Kong J,Li L

更新日期：2018-07-05 00:00:00

abstract：:Biosorption experiment from aqueous solutions containing known amount of rare earth elements (REEs) using pre-treated Buccinum tenuissimum shell was explored to evaluate the efficiency of shell biomass as sorbent for REEs. In this work, four kinds of sieved shell samples: (a) "Ground original sample", (b) "Heat-treatm...

journal_title：Bioinorganic chemistry and applications

authors： Koto Y,Kano N,Wang Y,Sakamoto N,Imaizumi H

更新日期：2010-01-01 00:00:00

abstract：Background:Sustained return of spontaneous circulation (ROSC) can be initially established in patients with out-of-hospital cardiac arrest (OHCA); however, the early postresuscitation hemodynamics can still be impaired by high levels of serum potassium (hyperkalemia). The impact of different potassium levels on early p...

journal_title：Bioinorganic chemistry and applications

authors： Lin YR,Syue YJ,Lee TH,Chou CC,Chang CF,Li CJ

更新日期：2018-04-05 00:00:00

abstract：:The zinc(II) complex (C2H6NS)2Zn·ZnCl2 was synthesized with 2-aminoethanethiol hydrochloride and zinc sulfate heptahydrate as the raw materials in aqueous solution. The composition and structure of the complex were characterized by elemental analysis, infrared spectra, single crystal X-ray diffraction, and thermogravi...

journal_title：Bioinorganic chemistry and applications

authors： Shu XG,Wu CL,Li CJ,Zhang M,Wan K,Wu X

更新日期：2016-01-01 00:00:00

abstract：:Stable, six coordinated Bu(2)SnLA type complexes have been prepared [where LH = RCOC:C(OH)N(C(6) H(5))N:CCH(3); R = -4-F-C(6)H(4)-(L(1)H), R = -4-Cl-C(6)H(4)-(L(2)H), R= -4-Br-C(6)H(4)-(L(3)H), R=-CF(3)(L(4)H) and AH = C(O)C(6) H(4) C(O)NCHR'COOH; R'= -H(A(1)H), -CH(3)(A(2)H), -CH(CH(3))(2)(A(3)H)] by the interaction ...

journal_title：Bioinorganic chemistry and applications

authors： Joshi A,Verma S,Gaurb RB,Sharma RR

更新日期：2005-01-01 00:00:00

abstract：:The antineoplastic potential of a stable monomeric Au(II) complex with hematoporphyrin IX (Hp), namely [Au(II)Hp(-2H).(H(2)O)(2)], was investigated in a panel of tumor cell lines. The complex exhibits strong cytotoxicity, whereby the leukaemia- and lymphoma-derived cell lines are more sensitive, with IC(50) values com...

journal_title：Bioinorganic chemistry and applications

authors： Momekov G,Ferdinandov D,Konstantinov S,Arpadjan S,Tsekova D,Gencheva G,Bontchev PR,Karaivanova M

更新日期：2008-01-01 00:00:00

abstract：:Marine biofilms formed due to adhesion of bacteria and other microorganisms on submerged surfaces are generally considered to be a major form of microfouling. Subsequent attachment of larvae of higher organisms like barnacles, mussels, and so forth, on marine biofilms, causes macrofouling. Several approaches have been...

journal_title：Bioinorganic chemistry and applications

authors： Nithya Deva Krupa A,Raghavan V

更新日期：2014-01-01 00:00:00

abstract：:It is important to develop functional transmucosal implant surfaces that reduce the number of initially adhering bacteria and they need to be modified to improve the anti-bacterial performance. Commercially pure Ti sheets were anodized in an electrolyte containing ethylene glycol, distilled water and ammonium fluoride...

journal_title：Bioinorganic chemistry and applications

authors： Yeniyol S,He Z,Yüksel B,Boylan RJ,Urgen M,Ozdemir T,Ricci JL

更新日期：2014-01-01 00:00:00

abstract：:The toxicity mechanisms of mercury and tin organic derivatives are still under debate. Generally the presence of organic moieties in their molecules makes these compounds lipophilic and membrane active species. The recent results suggest that Hg and Sn compounds deplete HS-groups in proteins, glutathione and glutathio...

journal_title：Bioinorganic chemistry and applications

authors： Milaeva E,Petrosyan V,Berberova N,Pimenov Y,Pellerito L

更新日期：2004-01-01 00:00:00

abstract：:The influences of chondroitin sulfate C (C6S) on size, aggregation, sedimentation, and Zeta potential of sub-micron calcium oxalate monohydrate (COM) and calcium oxalate dihydrate (COD) crystallites with mean sizes of about 330 nm were investigated using an X-ray diffractometer, nanoparticle size Zeta potential analyz...

journal_title：Bioinorganic chemistry and applications

authors： Li JJ,Xue JF,Ouyang JM

更新日期：2013-01-01 00:00:00

abstract：:N-substituted pyridine hydrazide (pyridine-2-carbonyl chloride and 4-chloro-benzoic acid hydrazide) undergoes hydrazide formation of the iminic carbon nitrogen double bond through its reaction with cobalt(II), nickel(II), and copper(II) metal salts in ethanol which are reported and characterized based on elemental ana...

journal_title：Bioinorganic chemistry and applications

authors： Singh J,Singh P

更新日期：2012-01-01 00:00:00

abstract：:The adsorption of bixin in aprotic solvents onto acid- and alkali-treated kaolinite was investigated. Kaolinite was treated three times, for 6 h each, with 8 M HCl or 5 M KOH. The adsorbents were characterized by XRD, FT-IR, EDS, and BET-N2. The effects of contact time and dye concentration on adsorption capacity and ...

journal_title：Bioinorganic chemistry and applications

authors： Rahmalia W,Fabre JF,Usman T,Mouloungui Z

更新日期：2018-01-18 00:00:00

abstract：:DNA binding and photocleavage characteristics of a series of mixed ligand complexes of the type [M(bpy)(2)qbdp](PF(6))(n).xH(2)O (where M = Co(III) or Ni(II), bpy = 2.2'-bipryidine, qbdp = Quinolino[3,2-b]benzodiazepine, n = 3 or 2 and x = 5 or 2) have been investigated. The DNA binding property of the complexes with ...

journal_title：Bioinorganic chemistry and applications

authors： Prabhakara MC,Basavaraju B,Naik HS

更新日期：2007-01-01 00:00:00