E.p.r. studies of photolysis of nitrosyl haemoglobin at low temperatures.

Abstract:

:Photolysis of HbNO has been studied from 6.2 K to 15.5 K by electron spin resonance during and after continuous illumination. Non-exponential kinetics of both dissociation and reassociation of NO was observed. The prolonged illumination separates the fast and slow ligands. This picture is consistent with NO tunnelling from two sites at different distances from the bound position. This result is obtained using a model of a sum of two exponentials or of conformational substates.

journal_name

Int J Biol Macromol

authors

Linhares MP,el-Jaick LJ,Bemski G,Wajnberg E

doi

10.1016/0141-8130(90)90083-m

subject

Has Abstract

pub_date

1990-02-01 00:00:00

pages

59-63

issue

1

eissn

0141-8130

issn

1879-0003

pii

0141-8130(90)90083-M

journal_volume

12

pub_type

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