Ballpoint pen inks: the quantitative analysis of ink solvents on paper by solid-phase microextraction.

Abstract:

:We wish to describe further developments to a method previously reported on the detection of 2-phenoxyethanol in ink. The solid-phase microextraction (SPME) sampling technique, together with gas chromatography-mass spectrometry (GC-MS), has been used to quantify solvents in writing ink. In conventional approaches, the analysis of ink on documents requires some degree of destructive sampling. The methods commonly used remove ink samples from paper using a scalpel or a paper punch. To avoid document destruction, a sampling cell was constructed that allows solvents to be adsorbed directly onto the SPME fiber from the headspace above the document surface. Analytes (ink volatiles) are then desorbed from the SPME fiber on a gas chromatograph equipped with a mass selective detector (GC-MSD). With this method, it was possible to detect the presence of ink solvents on documents for a period lasting up to c. 2 years.

journal_name

J Forensic Sci

authors

Brazeau L,Gaudreau M

doi

10.1111/j.1556-4029.2006.00299.x

subject

Has Abstract

pub_date

2007-01-01 00:00:00

pages

209-15

issue

1

eissn

0022-1198

issn

1556-4029

pii

JFO299

journal_volume

52

pub_type

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