Abstract:
:Sodium and potassium cyanide are highly toxic, produced in large amounts by the chemical industry, and linked to numerous high-profile crimes. The U.S. Centers for Disease Control and Prevention has identified cyanide as one of the most probable agents to be used in a chemical terrorism event. We investigated whether stable C and N isotopic content of sodium and potassium cyanide could serve as a forensic signature for sample matching, using a collection of 65 cyanide samples. Upon analysis, a few of the cyanide samples displayed nonhomogeneous isotopic content associated with degradation to a carbonate salt and loss of hydrogen cyanide. Most samples had highly reproducible isotope content. Of the 65 cyanide samples, >95% could be properly matched based on C and N isotope ratios, with a false match rate <3%. These results suggest that stable C and N isotope ratios are a useful forensic signature for matching cyanide samples.
journal_name
J Forensic Scijournal_title
Journal of forensic sciencesauthors
Kreuzer HW,Horita J,Moran JJ,Tomkins BA,Janszen DB,Carman Adoi
10.1111/j.1556-4029.2011.01946.xsubject
Has Abstractpub_date
2012-01-01 00:00:00pages
75-9issue
1eissn
0022-1198issn
1556-4029journal_volume
57pub_type
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