Mechanical milling assisted by electrical discharge.

Abstract:

:Mechanical milling is an effective technique for the preparation of fine metallic and ceramic powders and can also be used to drive a wide range of chemical reactions. Milling devices include planetary machines, attritors and vibrational mills; products include amorphous, nanocrystalline and quasicrystalline materials, supersaturated solid solutions, reduced minerals, high-surface-area catalysts and reactive chemicals. During milling, solid-solid, solid-liquid and solid-gas reactions are initiated through repeated deformation and fracture of powder particles. A separate materials synthesis and processing technique involves reacting a material in a gas atmosphere under an electrical discharge. Here we show that the application of low-current, high-voltage electrical impulses during milling can result in both faster reactions and new synthesis and processing routes. We demonstrate the effects of glow (cold) and spark (hot) discharge milling on particle fracture for brittle, low-conductivity materials and ductile metals. Glow discharge milling was found to promote solid-gas reactions whereas spark discharge milling promotes fast fracturing, recrystallization, mineral reduction and solid-solid reactions.

journal_name

Nature

journal_title

Nature

authors

Calka A,Wexler D

doi

10.1038/nature00985

keywords:

subject

Has Abstract

pub_date

2002-09-12 00:00:00

pages

147-51

issue

6903

eissn

0028-0836

issn

1476-4687

pii

nature00985

journal_volume

419

pub_type

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