Properties of heat-treated calcium phosphate coatings deposited by high-velocity oxy-fuel (HVOF) spray.

Abstract:

:The influence of crystallization, upon heat treatment, on the properties of high-velocity oxy-fuel (HVOF) sprayed hydroxyapatite (HA) coatings was investigated. The characterization of the HA coating was performed by X-ray diffraction (XRD) and Fourier Transform Infrared Spectroscopy (FTIR). Differential Scanning Calorimeter (DSC) was employed to determine the crystallization temperature of the amorphous phase in an as-sprayed HA coating. The study demonstrated the effect of crystallization on the coating properties by considering the changes in materials chemistry, crystallinity level, and mechanical performance. Results showed that complete crystallization of the amorphous phase occurred at approximately 700 degrees C and the crystallization temperature was dependent on sample heating rate in the DSC test. The changes of ion groups were detected by FTIR, before and after the phase transformation. The crystallization of the coating after annealing at 750 degrees C resulted in a significant increase of the coatings' adhesive strength and shear strength, which attained maximum values 34 +/- 3 and 14.1 -/+ 0.8 MPa, respectively. Young's modulus increased from 21 +/- 1 to 25 +/- 2 GPa. Microhardness measurements confirmed the changes in coating properties. It is also found that the transformation from the amorphous phase has crystalline HA as the only resultant phase detected by XRD.

journal_name

Biomaterials

journal_title

Biomaterials

authors

Li H,Khor KA,Cheang P

doi

10.1016/s0142-9612(01)00326-x

keywords:

subject

Has Abstract

pub_date

2002-05-01 00:00:00

pages

2105-12

issue

10

eissn

0142-9612

issn

1878-5905

pii

S0142-9612(01)00326-X

journal_volume

23

pub_type

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