Abstract:
:A series of chitosan/chitin samples with DA's varying between 5.2 and 89% was prepared from the reacetylation under soft conditions of a unique chitosan sample allowing the preservation of the chain distribution. The study of the variation of pH for the same concentration of amine groups, at different ionic strengths, on the scale of DA's allows us to extrapolate the variation of pKa at dissociation degrees (alpha) 0 and 1. A modeling of all the curves was obtained by means of only one equation. Then, for given concentration of chitosan and ionic strength, it is possible to predict the pH of the solution whatever the DA and alpha. The role of DA through the participation of hydrophobic interactions and hydrogen bondings on the electrostatic parameters is discussed. The results allow a better understanding of some physicochemical and biological properties of chitosan and chitin.
journal_name
Biomacromoleculesjournal_title
Biomacromoleculesauthors
Sorlier P,Denuzière A,Viton C,Domard Adoi
10.1021/bm015531+keywords:
subject
Has Abstractpub_date
2001-10-01 00:00:00pages
765-72issue
3eissn
1525-7797issn
1526-4602journal_volume
2pub_type
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