Some aspects of the persistence and fate of acrolein herbicide in water.

Abstract:

:Experimental data for the decay of acrolein approximated first order kinetics. The reaction continued to completion in local waters but in buffered solution (pH 5.1-8.6) an equilibrium was reached after reaction of about 92% of the acrolein. It is proposed that data presented on the effects of pH on decay of acrolein may be used as a conservative estimate of dissipation rates in water where non-target organisms are at risk. In flowing water in two channels the 8 to 10 fold discrepancy between observed and predicted rates of dissipation was attributed to major losses in volatilization and adsorption. A relatively non-volatile reaction product (which gave a positive reaction with dinitrophenylhydrazine) accumulated initially but dissipated rapidly, probably by microbiological processes, when acrolein concentrations fell below about 2 to 3 ppm.

authors

Bowmer KH,Higgins ML

doi

10.1007/BF02220892

subject

Has Abstract

pub_date

1976-01-01 00:00:00

pages

87-96

issue

1

eissn

0090-4341

issn

1432-0703

journal_volume

5

pub_type

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