Heat and Bleach: A Cost-Efficient Method for Extracting Microplastics from Return Activated Sludge.

Abstract:

:The extraction of plastic microparticles, so-called microplastics, from sludge is a challenging task due to the complex, highly organic material often interspersed with other benign microparticles. The current procedures for microplastic extraction from sludge are time consuming and require expensive reagents for density separation as well as large volumes of oxidizing agents for organic removal, often resulting in tiny sample sizes and thus a disproportional risk of sample bias. In this work, we present an improved extraction method tested on return activated sludge (RAS). The treatment of 100 ml of RAS requires only 6% hydrogen peroxide (H2O2) for bleaching at 70 °C, followed by density separation with sodium nitrate/sodium thiosulfate (SNT) solution, and is completed within 24 h. Extracted particles of all sizes were chemically analyzed with confocal Raman microscopy. An extraction efficiency of 78 ± 8% for plastic particle sizes 20 µm and up was confirmed in a recovery experiment. However, glass shards with a diameter of less than 20 µm remained in the sample despite the density of glass exceeding the density of the separating SNT solution by 1.1 g/cm3. This indicates that density separation may be unreliable for particle sizes in the lower micrometer range.

authors

Sujathan S,Kniggendorf AK,Kumar A,Roth B,Rosenwinkel KH,Nogueira R

doi

10.1007/s00244-017-0415-8

subject

Has Abstract

pub_date

2017-11-01 00:00:00

pages

641-648

issue

4

eissn

0090-4341

issn

1432-0703

pii

10.1007/s00244-017-0415-8

journal_volume

73

pub_type

杂志文章
  • Effects of Seasonal Changes on the Toxic Impacts of Oil Sands Process-Affected Water on Daphnia magna.

    abstract::Oil sands process-affected water (OSPW), which can be potentially toxic to aquatic biota, is a major by-product of bitumen mining in northern Alberta. The effects of environmental factors on the toxicity of OSPW are understudied. In the present study, the impacts of seasonal changes in water quality on the toxic effec...

    journal_title:Archives of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00244-017-0460-3

    authors: Lari E,Steinkey D,Pyle GG

    更新日期:2018-04-01 00:00:00

  • Fate and comparative toxicity of metallothioneins with differing Cd/Zn ratios in rat kidney.

    abstract::Metallothioneins with differing Cd/Zn ratios were prepared in vitro from rat liver zinc-thionein by replacing zinc with cadmium and were injected intraperitoneally to female rats. The distribution of cadmium, zinc, and copper in the kidney supernatant fraction was determined using a Sephadex G-75 column. The distribut...

    journal_title:Archives of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/BF01055143

    authors: Suzuki KT,Takenaka S,Kubota K

    更新日期:1979-01-01 00:00:00

  • Biological effects of gestational and lactational PCB exposure in neonatal and juvenile C57BL/6 mice.

    abstract::The purpose of this study was to obtain a better understanding of polychlorinated biphenyl (PCB) immunotoxicity in the developing mouse. Adult female mice were dosed with three subcutaneous injections per week of 50 mg/kg Aroclor 1242 (A1242), Aroclor 1254 (A1254), or corn oil for 2 weeks and then mated with nondosed ...

    journal_title:Archives of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00244-002-2022-5

    authors: Arena SM,Greeley EH,Halbrook RS,Hansen LG,Segre M

    更新日期:2003-02-01 00:00:00

  • An insect model for assessing mercury toxicity: effect of mercury on antioxidant enzyme activities of the housefly (Musca domestica) and the cabbage looper moth (Trichoplusia ni).

    abstract::The effect of mercury as Hg2Cl2 and HgCl2 on the antioxidant enzyme levels and its toxicity was investigated in an insect model comprised of adult females of the common housefly, Musca domestica, and fourth-instar larvae of the cabbage looper moth, Trichoplusia ni. HgCl2 was found to be more toxic than Hg2Cl2 to both ...

    journal_title:Archives of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/BF00212802

    authors: Zaman K,MacGill RS,Johnson JE,Ahmad S,Pardini RS

    更新日期:1994-01-01 00:00:00

  • Human exposure to PBDEs via house dust ingestion in Guangzhou, South China.

    abstract::Numerous studies have demonstrated the important role played by indoor dust in human exposure to polybrominated diphenyl ethers (PBDEs), particularly in children, who spend most of their time indoors. Few data have been available for PBDEs in house dust in China. In this study, dust samples were collected randomly fro...

    journal_title:Archives of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00244-010-9564-8

    authors: Chen L,Huang Y,Xu Z,Wen L,Peng X,Ye Z,Zhang S,Meng XZ

    更新日期:2011-04-01 00:00:00

  • Correlation between lead exposure indicators and sister chromatid exchange (SCE) frequencies in lymphocytes from inorganic lead exposed workers.

    abstract::Inorganic lead exposure was studied in 31 volunteers employed in storage battery plant. The genotoxicity of lead was measured in terms of sister chromatid exchange (SCE). Erythrocyte delta-aminolevulinic acid dehydrogenase (ALAD) activity, urinary delta-aminolevulinic acid (U-ALA), and blood lead levels (PbBs) were al...

    journal_title:Archives of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s002440010244

    authors: Duydu Y,Süzen HS,Aydin A,Cander O,Uysal H,Işimer A,Vural N

    更新日期:2001-08-01 00:00:00

  • Legacy and Emerging Brominated Flame Retardants in Bizerte Lagoon Murex (Hexaplex Trunculus): Levels and Human Health Risk Assessment.

    abstract::Occurrence of traditional (PBDEs) and novel (HBB, PBEB, DBDPE) brominated flame retardants, as well as the natural compounds of MeO-PBDEs, were studied in a shellfish species (Hexaplex trunculus) sampled from Bizerte Lagoon. PBDE and MeO-PBDE mean concentrations in murex soft tissues were 187 and 264 ng g-1 lw respect...

    journal_title:Archives of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00244-019-00694-x

    authors: Ameur WB,Annabi A,El Megdiche Y,Mhadhbi T,Hassine SB,Barhoumi B,Touil S,Driss MR,Barceló D,Eljarrat E

    更新日期:2020-04-01 00:00:00

  • Biotoxicity assessment of pyrene in soil using a battery of biological assays.

    abstract::A test battery, composed of a range of biological assays, was applied to evaluate the ecological health of soil aged for 69 days and spiked with a range of pyrene levels (1.04, 8.99, 41.5, 72.6, 136, and 399 μg g(-1) dry soil; Soxhlet-extracted concentrations after 69 days of aging). Chinese cabbage (Brassica rapa), e...

    journal_title:Archives of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00244-012-9793-0

    authors: Khan MI,Cheema SA,Tang X,Shen C,Sahi ST,Jabbar A,Park J,Chen Y

    更新日期:2012-11-01 00:00:00

  • Effects of sustained-release methoprene and a combined formulation of liquid methoprene and Bacillus thuringiensis israelensis on insects in salt marshes.

    abstract::Aquatic insects are an important component of the food web in salt marshes, therefore it is necessary to test whether pesticides used to control mosquitoes in salt marshes are safe for nontarget insects. We tested the nontarget effects of a combined formulation (duplex) of Bacillus thuringiensis israelensis (B.t.i.) a...

    journal_title:Archives of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s002440010094

    authors: Lawler SP,Dritz DA,Jensen T

    更新日期:2000-08-01 00:00:00

  • Exposure of urban applicators to carbaryl.

    abstract::Thirty-eight urban volunteers from the Lincoln and Omaha, Nebraska areas were monitored for carbaryl exposure during the summer of 1979. All volunteers were involved in the application of carbaryl incidental to their employment or leisure activities. The investigators made no attempt to affect the method of carbaryl a...

    journal_title:Archives of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/BF01055187

    authors: Gold RE,Leavitt JR,Holcslaw T,Tupy D

    更新日期:1982-01-01 00:00:00

  • Metal pollution and its impact on algae in flowing waters in India.

    abstract::Metal pollution in the river Godavari in India, due to discharges of liquid wastes from a paper mill, has been studied for a period of two years. At the discharge point and 1 km from the point of discharge, iron, manganese, and zinc were recorded in high concentrations, whereas cadmium and chromium were observed in lo...

    journal_title:Archives of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/BF01183878

    authors: Sudhakar G,Jyothi B,Venkateswarlu V

    更新日期:1991-11-01 00:00:00

  • Developmental instability in a riparian population of the Algerian mouse(Mus spretus) associated with a heavy metal-polluted area in central Portugal.

    abstract::The adverse effects of heavy metals (mostly Cr, Mn, Fe, Cu, Zn, and Se) on the environment were appraised by comparing fluctuating asymmetry of dental characters (molars) in Algerian mice (Mus spretus) from polluted (Oeiras) and reference (Xévora) riparian areas, in central Portugal. The size of tooth traits was shown...

    journal_title:Archives of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s002440010279

    authors: Nunes AC,Auffray JC,Mathias ML

    更新日期:2001-11-01 00:00:00

  • The acute and chronic toxicity of hexadecyl and heptadecyl sulfate to aquatic organisms.

    abstract::HSAS (high-solubility alkyl sulfate) is a new anionic surfactant composed predominantly of methyl and ethyl branched hexadecyl and heptadecyl sulfate. Effects of HSAS on a wide range of fish, algae, and invertebrates were investigated in conventional laboratory toxicity tests as well as in exposures conducted as part ...

    journal_title:Archives of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00244-005-1044-1

    authors: Versteeg DJ,Rawlings J,Bozso E,Shi J

    更新日期:2006-07-01 00:00:00

  • Detection and Monitoring of Oil Spills Using Moderate/High-Resolution Remote Sensing Images.

    abstract::Current marine oil spill detection and monitoring methods using high-resolution remote sensing imagery are quite limited. This study presented a new bottom-up and top-down visual saliency model. We used Landsat 8, GF-1, MAMS, HJ-1 oil spill imagery as dataset. A simplified, graph-based visual saliency model was used t...

    journal_title:Archives of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00244-016-0358-5

    authors: Li Y,Cui C,Liu Z,Liu B,Xu J,Zhu X,Hou Y

    更新日期:2017-07-01 00:00:00

  • Effect of atrazine on growth, photosynthesis, and between-strain variability in scenedesmus subspicatus (Chlorophyceae)

    abstract::The magnitude of between-strain differences in the sensitivity of algal species to toxicants is not well known. Yet, informations obtained with a single strain are used for ecotoxicological assessment and for interspecific comparisons. Using 12 strains, we determined whether intraspecific variability occurs in the gre...

    journal_title:Archives of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s002449900487

    authors: Behra R,Genoni GP,Joseph AL

    更新日期:1999-07-01 00:00:00

  • Metabolism of 4-chlorobiphenyl by lichens.

    abstract::Eighteen lichens from a variety of habitats were treated with 4-chlorobiphenyl (4-CB). All, as determined by means of radioactive tracers, were shown to partially convert 4-CB to 4-chloro-4'-hydroxybiphenyl. Only one species (Pseudocyphellaria crocata) produced a further major metabolite not previously reported, namel...

    journal_title:Archives of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/BF02220817

    authors: Maass WS,Hutzinger O

    更新日期:1975-01-01 00:00:00

  • Hepatic activities of xenobiotic metabolizing enzymes and biliary levels of xenobiotics in English sole (Parophrys vetulus) exposed to environmental contaminants.

    abstract::English sole (Parophrys vetulus) are susceptible to the development of hepatic disease, including neoplasia, as a result of environmental exposure to polycyclic aromatic hydrocarbons (PAHs). The metabolism of PAHs, believed to be an essential factor in the development of neoplasia, has received considerable study in E...

    journal_title:Archives of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/BF01065834

    authors: Collier TK,Varanasi U

    更新日期:1991-05-01 00:00:00

  • Bioaccumulation of benzo(a)pyrene from sediment by fathead minnows: effects of organic content, resuspension and metabolism.

    abstract::The accumulation of 14C-benzo(a)pyrene (BaP) sorbed to sediment was examined in fathead minnows (Pimephales promelas) to compare uptake from sediment with a high organic carbon (OC) content (7.7%), to that with a low OC content (2%). Ingestion of sediments was quantified by co-labeling the sediment with 141Cerium, whi...

    journal_title:Archives of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00244-003-2148-0

    authors: McCarthy JF,Burrus LW,Tolbert VR

    更新日期:2003-10-01 00:00:00

  • Toxicologic and histopathologic response of the terrestrial salamander Plethodon cinereus to soil exposures of 1,3,5-trinitrohexahydro-1,3,5-triazine.

    abstract::Red-backed salamanders (Plethodon cinereus) were exposed to four different concentrations of 1,3,5-trinitrohexahydro-1,3,5-triazine (RDX) in soil under controlled laboratory conditions for 28 days. Wild-caught P. cinereus (N = 20/treatment) were exposed to target concentrations of 5,000, 1000, 100, 10, and 0 mg RDX/kg...

    journal_title:Archives of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00244-004-3242-7

    authors: Johnson MS,Paulus HI,Salice CJ,Checkai RT,Simini M

    更新日期:2004-11-01 00:00:00

  • Comparative developmental toxicity of n-butyl benzyl phthalate and di-n-butyl phthalate in rats.

    abstract::n-Butyl benzyl phthalate (BBP) and di-n-butyl phthalate (DBP) were evaluated and compared for their developmental toxic potential. Pregnant rats were given either BBP or DBP by gastric intubation at a dose of 0.75, 1.0 and 1.25 g/kg on days 7-9, days 10-12 and days 13-15 of pregnancy. Regardless of the days of treatme...

    journal_title:Archives of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/BF00217620

    authors: Ema M,Kurosaka R,Amano H,Ogawa Y

    更新日期:1995-02-01 00:00:00

  • Mercury accumulation in sediment cores from three Washington state lakes: evidence for local deposition from a coal-fired power plant.

    abstract::Mercury accumulation rates measured in age-dated sediment cores were compared at three Washington state lakes. Offutt Lake and Lake St. Clair are located immediately downwind (18 and 28 km, respectively) of a coal-fired power plant and Lake Sammamish is located outside of the immediate area of the plant (110 km). The ...

    journal_title:Archives of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00244-010-9530-5

    authors: Furl CV,Meredith CA

    更新日期:2011-01-01 00:00:00

  • Toxicity of cadmium and copper on larval and juvenile stages of the estuarine crab Chasmagnathus granulata (Brachyura, Grapsidae).

    abstract::The toxicity of cadmium and copper were assayed in the estuarine crab Chasmagnathus granulata. Acute assays were made on the first larvae stage, and both acute and chronic assays were made on juvenile crabs. The acute lethal toxicity of the assayed heavy metals was three orders of magnitude higher in larvae than in ju...

    journal_title:Archives of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s002440010256

    authors: Greco LS,Sánchez MV,Nicoloso GL,Medesani DA,Rodríguez EM

    更新日期:2001-10-01 00:00:00

  • Effects of Dispersant Treatment on the Acute Aquatic Toxicity of Petroleum Hydrocarbons

    abstract::The acute effects of both untreated and dispersant-treated Prudhoe Bay crude oil on the early life-stages of three marine species were investigated. Identification of which water-accommodated fraction (undispersed or chemically dispersed) was considered "more toxic" was dependent on species, time, and endpoint (and by...

    journal_title:Archives of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s002449900302

    authors: Singer MM,George S,Lee I I,Jacobson S,Weetman LL,Blondina G,Tjeerdema RS,Aurand D,Sowby ML

    更新日期:1998-02-01 00:00:00

  • Brain acetylcholinesterase activity in shiner perch (Cymatogaster aggregata) and juvenile chinook salmon (Oncorhynchus tshawytscha) after application of carbaryl to control burrowing shrimp within Willapa Bay, Washington.

    abstract::Carbaryl has been applied in Willapa Bay, Washington, for five decades to control burrowing shrimp (Neotrypaea californiensis and Upogebia pugettensis) on commercial oyster (Crassostrea gigas) beds. Concerns about effects on nontarget species, including fishes, have led to restrictions in use despite a lack of data on...

    journal_title:Archives of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00244-013-9951-z

    authors: Troiano AT,King KA,Grue CE,Grassley JM,Ekblad CJ

    更新日期:2013-11-01 00:00:00

  • Concentrations, sources, and risk assessment of polychlorinated biphenyls in vegetables near a waste-incinerator site, South China.

    abstract::Numerous studies have reported polychlorinated biphenyl (PCB) concentrations in soil, root, and aerial parts of vegetables. However, few studies have measured the contribution of PCBs bound to particles in air in relation to uptake by vegetables. In the present study, PCB concentrations were measured in five types of ...

    journal_title:Archives of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00244-014-0045-3

    authors: Zeng L,Li N,Shao D,Kang Y,Zhang Q,Lu P,Li L,Luo J,Guo X

    更新日期:2014-07-01 00:00:00

  • Low-level atrazine exposure decreases cell proliferation in human fibroblasts.

    abstract::There is continuing concern that release of certain chemicals into the environment leads to human exposure to toxins, particularly through contaminated ground and surface waters. The triazine herbicide atrazine (2-chloro-4-ethylamine-6-isopropylamino-S-triazine) is routinely found as a contaminant in many surface and ...

    journal_title:Archives of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00244-003-3087-5

    authors: Manske MK,Beltz LA,Dhanwada KR

    更新日期:2004-05-01 00:00:00

  • Climate and Physiography Predict Mercury Concentrations in Game Fish Species in Quebec Lakes Better than Anthropogenic Disturbances.

    abstract::The fluctuations of mercury levels (Hg) in fish consumed by sport fishers in North-Eastern America depend upon a plethora of interrelated biological and abiological factors. To identify the dominant factors ultimately controlling fish Hg concentrations, we compiled mercury levels (Hg) during the 1976-2010 period in 90...

    journal_title:Archives of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s00244-016-0261-0

    authors: Lucotte M,Paquet S,Moingt M

    更新日期:2016-05-01 00:00:00

  • The suitability of oiled guillemots (Uria aalge) as monitoring organisms for geographical comparisons of trace element contaminants.

    abstract::The influence of the nutritional state (condition factor), age, and sex of Common Guillemots (Uria aalge) on trace element levels was examined to investigate the validity of geographical comparisons of metal accumulations in dying and dead oiled seabirds. A quotient of liver mass to kidney mass was calculated as a con...

    journal_title:Archives of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/BF00212675

    authors: Wenzel C,Adelung D

    更新日期:1996-10-01 00:00:00

  • Bioluminescent method in studying the complex effect of sewage components.

    abstract::The inhibition of bacterial luminescence has been used in testing industrial enterprises sewage. The toxicity of the sewage is less than the total toxicity of separate components due to neutralization of quinone products of polyphenol oxidation in the reactions with the other phenol components of sewage. Toxicity incr...

    journal_title:Archives of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/BF00213286

    authors: Stom DI,Geel TA,Balayan AE,Shachova GI,Kuznetsov AM,Medvedeva SE

    更新日期:1992-02-01 00:00:00

  • Reduction in human exposure to pesticide using traditional work clothing fabrics with chemical finishing: carboxymethylation and starch.

    abstract::Franz diffusion experiments with human skin combined with work-clothing fabric have shown that skin exposure to pesticides is reduced by the presence of traditional nonbarrier textiles. This study was undertaken to obtain further information about the reduction in exposure using traditional work-clothing fabrics that ...

    journal_title:Archives of environmental contamination and toxicology

    pub_type: 杂志文章

    doi:10.1007/s002449900359

    authors: Csiszár E,Borsa J,Rácz I,Obendorf SK

    更新日期:1998-07-01 00:00:00