The interaction of the vanadyl (IV) cation with chondroitin sulfate A.

Abstract:

:The interaction of VO2+ with the muchopolysaccharide chondroitin sulfate A (CSA) has been investigated by electron absorption spectroscopy and infrared measurements in aqueous solutions at different pH-values and ligand to metal ratios up to 6:1. The generation of a VO(CSA)2 species could be demonstrated. Coordination of the oxocation through the carboxylate group and the glycosidic oxygen of the D-glucuronate moieties is suggested. Infrared spectra of some poorly characterized solid VO/CSA complexes point to the same bonding characteristics. Preliminary results obtained at higher ligand to metal ratios suggest a different coordination behavior.

journal_name

Biol Trace Elem Res

authors

Etcheverry SB,Williams PA,Baran EJ

doi

10.1007/BF02990487

subject

Has Abstract

pub_date

1994-07-01 00:00:00

pages

43-52

issue

1

eissn

0163-4984

issn

1559-0720

journal_volume

42

pub_type

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