Influence of Nickel molybdate nanocatalyst for enhancing biohydrogen production in microbial electrolysis cell utilizing sugar industrial effluent.

Abstract:

:Biohydrogen production in Microbial Electrolysis Cell (MEC) had inspired the researchers to overcome the challenges associated towards sustainability. Despite microbial community and various substrates, economical cathode catalyst development is most significant factor for enhancing hydrogen production in the MEC. Hence, in this study, the performance of MEC was investigated with a sugar industry effluent (COD 4200 ± 20 mg/L) with graphite anode and modified Nickel foam (NF) cathode. Nickel molybdate (NiMoO4) coated NF achieved a higher hydrogen production rate 0.12 ± 0.01 L.L-1D-1 as compared to control under favorable conditions. Electrochemical characterizations demonstrated that the improved catalytic activity of novel nanocatalyst with lower impedance favoring faster hydrogen evolution kinetics. The MEC with the novel catalyst performed with 58.2% coloumbic efficiency, 20.36% cathodic hydrogen recovery, 11.96% overall hydrogen recovery and 54.38% COD removal efficiency for a 250 mL substrate during 5 days' batch cycle. Hence, the potentiality of modified cathode was established with the real time industrial effluent highlighting the waste to wealth bio-electrochemical technology.

journal_name

Bioresour Technol

journal_title

Bioresource technology

authors

Jayabalan T,Matheswaran M,Radhakrishnan TK,Naina Mohamed S

doi

10.1016/j.biortech.2020.124284

subject

Has Abstract

pub_date

2021-01-01 00:00:00

pages

124284

issue

Pt A

eissn

0960-8524

issn

1873-2976

pii

S0960-8524(20)31558-3

journal_volume

320

pub_type

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