Abstract:
:Biochar (BC) derived from Chinese herbal medicine residues has been investigated for its performance as a potential adsorbent in tetracycline (TC) removal. In the present study, a chemical co-precipitation method was carried out to prepare manganese dioxide modified biochar (Mn-BC) to increase its sorption capacity. The properties of the modified biochar were characterized for further enhancing TC removal from an aqueous solution. Mn-BC was successfully synthesized and resulted in a much higher specific surface area, total pore volume and pore diameter. The sorption kinetics of TC on Mn-BC was described by the pseudo-second-order model. The sorption data of Mn-BC were fitted by Langmuir and Freundlich models. The study findings revealed a maximum adsorption capacity of Mn-BC (1:10) to TC was up to 131.49 mg/g. The adsorption process was endothermic and spontaneous. The degradation of TC was further enhanced by MnO2 acting as an oxidizer on Mn-BC. Overall, the modified biochar derived from Chinese herbal medicine residues is a superior alternative for the removal of TC from an aqueous solution.
journal_name
Environ Resjournal_title
Environmental researchauthors
Shen Q,Wang Z,Yu Q,Cheng Y,Liu Z,Zhang T,Zhou Sdoi
10.1016/j.envres.2020.109195subject
Has Abstractpub_date
2020-04-01 00:00:00pages
109195eissn
0013-9351issn
1096-0953pii
S0013-9351(20)30087-6journal_volume
183pub_type
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