Removal of tetracycline from an aqueous solution using manganese dioxide modified biochar derived from Chinese herbal medicine residues.

Abstract:

:Biochar (BC) derived from Chinese herbal medicine residues has been investigated for its performance as a potential adsorbent in tetracycline (TC) removal. In the present study, a chemical co-precipitation method was carried out to prepare manganese dioxide modified biochar (Mn-BC) to increase its sorption capacity. The properties of the modified biochar were characterized for further enhancing TC removal from an aqueous solution. Mn-BC was successfully synthesized and resulted in a much higher specific surface area, total pore volume and pore diameter. The sorption kinetics of TC on Mn-BC was described by the pseudo-second-order model. The sorption data of Mn-BC were fitted by Langmuir and Freundlich models. The study findings revealed a maximum adsorption capacity of Mn-BC (1:10) to TC was up to 131.49 mg/g. The adsorption process was endothermic and spontaneous. The degradation of TC was further enhanced by MnO2 acting as an oxidizer on Mn-BC. Overall, the modified biochar derived from Chinese herbal medicine residues is a superior alternative for the removal of TC from an aqueous solution.

journal_name

Environ Res

journal_title

Environmental research

authors

Shen Q,Wang Z,Yu Q,Cheng Y,Liu Z,Zhang T,Zhou S

doi

10.1016/j.envres.2020.109195

subject

Has Abstract

pub_date

2020-04-01 00:00:00

pages

109195

eissn

0013-9351

issn

1096-0953

pii

S0013-9351(20)30087-6

journal_volume

183

pub_type

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