One-pot furfural production using choline chloride-dicarboxylic acid based deep eutectic solvents under mild conditions.

Abstract:

:The performances of various anhydrous and aqueous choline chloride-dicarboxylic acid based deep eutectic solvents (DESs) were evaluated for furfural production from oil palm fronds without any additional catalyst. The effects of different carbon chain length dicarboxylic acids and water content in each DES on furfural production were investigated. Oil palm fronds, DES and water (0-5 ml) were mixed and reacted in an oil bath (60-300 min). Reacted oil palm fronds had the potential to be reused as cellulose-rich-valuable by-products. At 100 °C, aqueous choline chloride-oxalic acid (16.4 wt% H2O) produced the highest furfural yield of 26.34% and cellulose composition up to 72.79% in the reacted oil palm fronds. Despite operating at suitable reaction duration for dicarboxylic acid with longer carbon chain length, aqueous choline chloride-malonic acid and aqueous choline chloride-succinic acid performed poorly with furfural yield of less than 1%.

journal_name

Bioresour Technol

journal_title

Bioresource technology

authors

Lee CBTL,Wu TY,Ting CH,Tan JK,Siow LF,Cheng CK,Md Jahim J,Mohammad AW

doi

10.1016/j.biortech.2018.12.034

subject

Has Abstract

pub_date

2019-04-01 00:00:00

pages

486-489

eissn

0960-8524

issn

1873-2976

pii

S0960-8524(18)31693-6

journal_volume

278

pub_type

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