Abstract:
:Two rare cadinane-type sesquiterpenes, lyophyllone A (1) and lyophyllanetriol A (2), were isolated from the mushroom Lyophyllum transforme. The structures were elucidated on the basis of exhaustive NMR techniques, together with MS, UV-Vis and molecular modelling. The absolute configuration of lyophyllone A was determined by ab initio theoretical CD calculation performed by Density Functional Theory (DFT) using the B3PW91/6-31G(d,p) basis set. The experimental CD were found to be in good agreement with the corresponding population-weighted theoretical CD spectra, allowing for the determination of the absolute stereochemistry of the compound.
journal_name
Phytochemistryjournal_title
Phytochemistryauthors
Clericuzio M,Negri R,Cossi M,Gilardoni G,Gozzini D,Vidari Gdoi
10.1016/j.phytochem.2013.03.019subject
Has Abstractpub_date
2013-09-01 00:00:00pages
192-8eissn
0031-9422issn
1873-3700pii
S0031-9422(13)00115-5journal_volume
93pub_type
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