Abstract:
:Preparative-scale fermentation of papaveraldine (1), the known benzylisoquinoline alkaloid, with Mucor ramannianus 1839 (sih) has resulted in a stereoselective reduction of the ketone group and the isolation of S-papaverinol (2) and S-papaverinol N-oxide (3). The structure elucidation of both metabolites was based primarily on 1D-, 2D-NMR analyses and chemical transformations. The absolute configuration of 2 was determined using Horeau's method of asymmetric esterification. These metabolism results were consistent with the previous plant cell transformation studies on papaverine and isopapaverine.
journal_name
Phytochemistryjournal_title
Phytochemistryauthors
El Sayed KAdoi
10.1016/s0031-9422(99)00616-0subject
Has Abstractpub_date
2000-03-01 00:00:00pages
675-8issue
6eissn
0031-9422issn
1873-3700pii
S0031-9422(99)00616-0journal_volume
53pub_type
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