Abstract:
:The use of stereodynamic probes is becoming one of the leading strategies for the fast and effective determination of enantiomeric excess. Recently, we reported a series of novel molecular architectures based on a modified tris(2-pyridylmethyl)amine complex (TPMA), which are able to amplify the electronic CD, in the case of Zn(II) assemblies and vibrational CD, in the case of Co(II) assemblies. Herein, we report a structural modification of the ligand with the purpose to obtain a fluorescent chiral probe. The study deals with the synthesis of the novel ligand, the formation of the self-assembly system with amino acids, and the study of the electronic CD and circularly polarized luminescence.
journal_name
Chiralityjournal_title
Chiralityauthors
Carmo Dos Santos NA,Badetti E,Licini G,Abbate S,Longhi G,Zonta Cdoi
10.1002/chir.22780subject
Has Abstractpub_date
2018-01-01 00:00:00pages
65-73issue
1eissn
0899-0042issn
1520-636Xjournal_volume
30pub_type
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