Abstract:
:The attapulgite supported nanoscale zero-valent iron composite (AT-nZVI) was synthesized and used for Cr(VI) removal. X-ray diffraction (XRD) and transmission electron microscope (TEM) indicated that nZVI particles were well distributed and immobilized on the attapulgite surface. Batch experiments of Cr(VI) removal were conducted at varying mass ratios, initial Cr(VI) concentrations and kinetics. The results indicated that the removal efficiency of Cr(VI) by AT-nZVI approaches 90.6%, being greater than that by non-supported nZVI (62.9%). The removal kinetics could be more accurately explained using pseudo second order kinetics model. The composite exhibited a synergistic interaction instead of simple mixture of AT and nZVI. Reduction was the dominant mechanism at low concentrations as opposed to adsorption at high concentrations. FeCr2O4 was the main reduction product by AT-nZVI, which was attributed to the reduction of Cr(VI) by nZVI and co-precipitation of CrFe oxides on the surface of AT. In the meantime, Fe(II) ion contributed to 64% for the Cr(VI) removal, which resulted from the dissolution of nZVI during the removal process. From the analysis of XRD and XPS results, the crystallization of FeCr2O4 is believed to be formed easily after the reaction of the AT-nZVI composite with Cr(VI) which is more stable and greatly reduce the risk of secondary pollution compared with nZVI. The introduction of AT enhanced adsorption of Cr(VI) and crystallization of the products. The above results suggested that AT-nZVI could be a promising remediation material for Cr(VI)-contaminated groundwater.
journal_name
Chemospherejournal_title
Chemosphereauthors
Zhang W,Qian L,Ouyang D,Chen Y,Han L,Chen Mdoi
10.1016/j.chemosphere.2019.01.070subject
Has Abstractpub_date
2019-04-01 00:00:00pages
683-692eissn
0045-6535issn
1879-1298pii
S0045-6535(19)30070-0journal_volume
221pub_type
杂志文章相关文献
CHEMOSPHERE文献大全abstract::Liver samples of Eurasian otters from various parts of Hungary were analysed for mercury, copper, zinc, lead and cadmium. Only zinc concentration was significantly higher in females. Higher mercury and cadmium concentrations in adults and higher zinc values in immature otters were measured. Accumulation of mercury, co...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2008.10.022
更新日期:2009-02-01 00:00:00
abstract::We investigated whether polychlorinated biphenyls (PCBs) and water could be simultaneously removed from river sediment by solvent extraction using liquefied dimethyl ether (DME) as the extractant. DME exists in a gaseous state at normal temperature and pressure and can dissolve organic substances and some amount of wa...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2009.12.017
更新日期:2010-02-01 00:00:00
abstract::Removal of the refractory organic matters in leachate brines generated from nanofiltration unit in two full-scale municipal solid waste landfill leachate treatment plants was investigated by Fenton oxidative-coagulation and ultraviolet photo - Fenton processes in this study. Fenton oxidative-coagulation was performed ...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2015.12.069
更新日期:2016-03-01 00:00:00
abstract::This work describes the application electrokinetic fence technology to a soil polluted with herbicides in a large prototype containing 32 m3 of soil. It compares performance in this large facility with results previously obtained in a pilot-scale mockup (175 L) and with results obtained in a lab-scale soil column (1 L...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2016.09.113
更新日期:2017-01-01 00:00:00
abstract::The environmental impact of toxic metal contamination from legacy mining activities, many of which had operated and were closed prior to the enforcement of robust environmental legislation, is of growing concern to modern society. We have carried out analysis of As and potentially toxic metals (Cd, Co, Cr, Cu, Hg, Mn,...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2017.10.150
更新日期:2018-02-01 00:00:00
abstract::A long-term randomised block field experiment was established in 1997 to study the dynamics of total P and dissolved P in the surface waters of rice fields receiving two application rates of fertiliser P and one rate of combined fertiliser and manure P. Preliminary results from the first two crops show that concentrat...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/s0045-6535(00)00127-2
更新日期:2001-01-01 00:00:00
abstract::The mixture of finely ground blast furnace slag (BFS), basic oxygen furnace (BOF) steel slag (SS), and flue gas desulfurisation (FGD) gypsum could be used as cement to solidify heavy metals. In this study, these cementitious materials were combined with high-arsenic-containing tailings to form cemented backfill materi...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2019.02.030
更新日期:2019-05-01 00:00:00
abstract::Sulfide inhibition to nitrifying bacteria has prevented the integration of digestate nitrification and biogas desulfurization to simplify anaerobic digestion systems. In this study, liquid digestate with NaHS solution was treated using nitrifying sludge in a sequential-batch reactor with a long fill period, with an am...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2019.125381
更新日期:2020-04-01 00:00:00
abstract::Singlet oxygen (1O2) is well known to be formed through energy transfer from excited state organic matters to O2, playing an important role in the transformations of contaminants. However, the contribution of small oxidated aromatic compounds (OACs) to the production of 1O2 in surface water is unclear. In this study, ...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2020.127308
更新日期:2020-11-01 00:00:00
abstract::The start up and performance of the Anammox process were tested in sequencing batch reactors with two different configurations: a bubble column (SBR-B) and a gas-lift reactor (SBR-G). Different off-gas upflow velocities were tested (3.53-12.3 cm min(-1)) in order to expose the biomass to different shear conditions and...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2008.05.017
更新日期:2008-08-01 00:00:00
abstract::The threat that exposure to organohalogen (OH) contaminants poses to endangered populations of Kemp's ridley (Lepidochelys kempii) and green sea turtles (Chelonia mydas) is not well understood, partly because few OH data are available. Blood samples from live juvenile and sub-adult L. kempii (n = 46) and C. mydas (n =...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2009.10.059
更新日期:2010-02-01 00:00:00
abstract::Peroxidases from root exudates of sorghum (Sorghum bicolor L. Moench) and alfalfa (Medicago sativa L.) were purified and characterized, and their ability to oxidize native PAHs and PAH-derivatives was evaluated. The obtained data confirm that peroxidases are involved in the rhizosphere degradation of PAHs. Nondenaturi...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2016.11.027
更新日期:2017-02-01 00:00:00
abstract::Pirimiphos-methyl (PMM) is a widely used organophosphorus pesticide that can be released into the atmosphere in gas and condensed phases. It possesses a PS bond and an N,N-dialkyl group adjacent to pyrimidine, which are common functional groups for pesticides. Currently, the reaction mechanisms of O3 with these functi...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2014.12.039
更新日期:2015-11-01 00:00:00
abstract::People have been suffering from air pollution for a decade in China, especially from PM2.5 (particulate matter with a diameter of less than 2.5 μm). Accurate prediction of air quality has great practical significance. In this paper, we propose a data-driven model, called as long short-term memory - fully connected (LS...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2018.12.128
更新日期:2019-04-01 00:00:00
abstract::Increasing studies have established the toxic effects of BPA on development and reproduction in animals. In present study, we investigated epigenetic effects on the transcription of several ovarian steroidogenic genes in rare minnows Gobiocypris rarus after BPA exposure at 15 μgL-1 for 21, 42 and 63 d. Results showed ...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2019.124935
更新日期:2020-02-01 00:00:00
abstract::The effects of surface physicochemical properties of functionalized polystyrene latex (PSL) nanoparticles (NPs) and model filamentous fungi Aspergillus oryzae and Aspergillus nidulans cultivated in different environment (aqueous and atmospheric environment) on the colloidal behavior and cytotoxicity were investigated ...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2016.01.091
更新日期:2016-04-01 00:00:00
abstract::Norfloxacin is a synthetic antibiotics drug which is widely used in the treatment of infectious diseases and also often carelessly released into natural environment resulting in antibiotics-contaminated wastewater. In this work, we employed atmospheric-pressure non-thermal dielectric barrier discharge (DBD) to treat n...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2018.07.035
更新日期:2018-11-01 00:00:00
abstract::In many countries, rice grains and complementary medicines are important sources of arsenic (As) consumption. The objective of this study was to compare the speciation and bioaccessibility of As in selected rice grains and complementary medicines. A number of rice grain samples, and a range of herbal and ayurvedic med...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2017.04.126
更新日期:2017-09-01 00:00:00
abstract::Developing resistance management strategies for eco-friendly insecticides is essential for the management of insect pests without harming the environment. Cyromazine is a biorational insecticide with very low mammalian toxicity. Resistance to cyromazine has recently been reported in house flies from Punjab, Pakistan. ...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2016.10.018
更新日期:2017-01-01 00:00:00
abstract::The deterioration of water quality, especially organic pollution in Tai Lake and the Qiantang River, have recently received attention in China. The objectives of this study were to evaluate the formation of halonitromethanes (HNMs) using multiple regression models for chlorination and chloramination and to identify th...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2014.06.084
更新日期:2015-01-01 00:00:00
abstract::This study was designed to investigate the transportation, distribution, and bioaccumulation of PCBs in various environmental media and compartments using an ecologically simulated growth chamber. Spatial and temporal trends of PCBs in the growth chamber were discussed. The release of PCB congeners in soil was affecte...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2005.11.065
更新日期:2006-07-01 00:00:00
abstract::Platinum group elements (PGEs), platinum, palladium and rhodium are widely used in automobile catalytic converters. PGEs are emitted into the environment and enter the aquatic ecosystem via runoff rainwater. The present study investigated the bioavailability of platinum chloride for the zebrafish (Danio rerio) and the...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2009.08.033
更新日期:2009-11-01 00:00:00
abstract::The availability of metal in contaminated soil can be reduced by the addition of soil amendments. The objectives of this study are to study the effects of applying different soil amendments on the concentration of Cd and Pb in soil solution, DTPA or EDTA extractable Cd and Pb, and the uptake of Cd and Pb by wheat (Tri...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2004.08.094
更新日期:2004-12-01 00:00:00
abstract::A mixture of four tetracyclines; oxytetracycline (OTC), chlortetracycline (CTC), tetracycline (TC), and doxycycline (DC) was applied in fifteen 12000l outdoor microcosms at four treatment levels plus controls each with three replicates (n = 3). The dissipation times of parent compounds were monitored and half-lives (D...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2005.01.035
更新日期:2005-07-01 00:00:00
abstract::In recent years, many studies have been devoted to investigate the application of biochar for pollutants removal from aqueous solutions. Biochar exhibits a great potential to efficiently tackle water contaminants considering the wide availability of feedstock, low-cost and favorable physical/chemical surface character...
journal_title:Chemosphere
pub_type: 杂志文章,评审
doi:10.1016/j.chemosphere.2014.12.058
更新日期:2015-04-01 00:00:00
abstract::Direct exposure to cadmium (Cd) may induce persistent impairment in learning and memory. However, the outcomes of maternal exposure on the neurological development of offspring are much less clear, and the underlying mechanism leading to toxicity remains undisclosed. Following chronic exposure of female rats during ge...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2019.03.094
更新日期:2019-06-01 00:00:00
abstract::Paddy fields are characterized by frequent organic input (e.g., fertilization and rice residue amendment), which may affect mercury biogeochemistry and bioaccumulation. To explore potential effects of rice residue amendment on methylmercury (MMHg) accumulation in rice, a mercury-contaminated paddy soil was amended wit...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2016.02.095
更新日期:2016-06-01 00:00:00
abstract::A sequential fractionation method proposed by Jiang and Gu (1989) distinguished three types of calcium phosphates (Ca-P) according to their different plant availabilities. Three extractants, NaHCO3, NH4Ac, and H2SO4 were used to extract Ca2-P, Ca8-P, and Ca10-P types, respectively, from soil. This sequential fractiona...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2016.03.014
更新日期:2016-06-01 00:00:00
abstract::In this study, a facile four-step hydrothermal method was utilized to deposit a core-shell structure on UiO-66(Zr/Ti) nanoflake (NFs) as a visible-light-driven photocatalyst. The core was magnetic Fe3O4 which served as a charge carrier coated with WO3 shell. The as-prepared photocatalyst was characterized by XRD, VSM,...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2020.129206
更新日期:2021-03-01 00:00:00
abstract::Electron donor limitations likely reduce microbial enhanced trichloroethene (TCE) dense non-aqueous phase liquid (DNAPL) dissolution. This study quantitatively examined the relation between the DNAPL dissolution enhancement and the electron donor supply rate. An experiment used diffusion-cells with a 5.5 cm central sa...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2012.11.016
更新日期:2013-03-01 00:00:00