Immobilisation of high-arsenic-containing tailings by using metallurgical slag-cementing materials.

Abstract:

:The mixture of finely ground blast furnace slag (BFS), basic oxygen furnace (BOF) steel slag (SS), and flue gas desulfurisation (FGD) gypsum could be used as cement to solidify heavy metals. In this study, these cementitious materials were combined with high-arsenic-containing tailings to form cemented backfill material (CBM). The results indicated that the optimal design of CBM was that of specimen CBM2 which showed good early strength (10.09 MPa) at a curing age of 3 days containing 60% BF slag, 30% SS, and 10% gypsum. And the arsenic leaching concentration of CBM2 at a curing age of 7 days and 28 days were both less than the limits specified in standards for drinking water quality (Chinese Standard GB 5749-2006). The predominant hydration products of CBM2 contained rod-like ettringite and amorphous C-S-H gel both of which promote arsenic solidification.

journal_name

Chemosphere

journal_title

Chemosphere

authors

Zhang Y,Zhang S,Ni W,Yan Q,Gao W,Li Y

doi

10.1016/j.chemosphere.2019.02.030

subject

Has Abstract

pub_date

2019-05-01 00:00:00

pages

117-123

eissn

0045-6535

issn

1879-1298

pii

S0045-6535(19)30246-2

journal_volume

223

pub_type

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