Abstract:
:Palm kernel shells were pyrolyzed in a pyrolysis plant equipped with a fluidized-bed reactor and a char-separation system. The influence of reaction temperature, feed size and feed rate on the product spectrum was also investigated. In addition, the effect of reaction temperature on the yields of phenol and phenolic compounds in the bio-oil was examined. The maximum bio-oil yield was 48.7 wt.% of the product at 490 degrees C. The maximum yield of phenol plus phenolic compounds amounted to about 70 area percentage at 475 degrees C. The yield of pyrolytic lignin after its isolation from the bio-oil was approximately 46 wt.% based on the water and ash free oil. The pyrolytic lignin was mainly composed of phenol, phenolic compounds and oligomers of coniferyl, sinapyl and p-coumaryl alcohols. From the result of a GPC analysis, the number average molecular weight and the weight average molecular weight were 325 and 463 g/mol, respectively.
journal_name
Bioresour Technoljournal_title
Bioresource technologyauthors
Kim SJ,Jung SH,Kim JSdoi
10.1016/j.biortech.2010.06.110subject
Has Abstractpub_date
2010-12-01 00:00:00pages
9294-300issue
23eissn
0960-8524issn
1873-2976pii
S0960-8524(10)01111-9journal_volume
101pub_type
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