Anaerobic co-digestion of glycerol and wastewater derived from biodiesel manufacturing.

Abstract:

:The anaerobic co-digestion of glycerol and wastewater derived from biodiesel manufacturing, in which COD was found to be 1054 and 428 g/L, respectively, was studied in batch laboratory-scale reactors at mesophilic temperature (35 degrees C). Glycerol was acidified with H(3)PO(4) in order to recover the alkaline catalyst employed in the transesterification reaction (KOH) as agricultural fertiliser (potassium phosphates). Wastewater was subjected to an electrocoagulation process in order to reduce its oil content. After mixing, the anaerobic revalorisation of the wastewater was studied employing inoculum-substrate ratios ranging from 5.02 to 1.48 g VSS/g COD and organic loading rates of 0.27-0.36 g COD/g VSS d. Biodegradability was found to be around 100%, while the methane yield coefficient was 310 mL CH(4)/g COD removed (1 atm, 25 degrees C). At the equilibrium time, the proportionality between r' and the load was constant, showing 1.55 mL CH(4)/(g VSS g COD h). The results showed that anaerobic co-digestion reduces the clean water and nutrient requirement, with the consequent economical and environmental benefit.

journal_name

Bioresour Technol

journal_title

Bioresource technology

authors

Siles JA,Martín MA,Chica AF,Martín A

doi

10.1016/j.biortech.2010.03.042

subject

Has Abstract

pub_date

2010-08-01 00:00:00

pages

6315-21

issue

16

eissn

0960-8524

issn

1873-2976

pii

S0960-8524(10)00519-5

journal_volume

101

pub_type

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