Sorption of Cr(III) onto chelating b-DAEG-sporopollenin and CEP-sporopollenin resins.

Abstract:

:In the present study, the removal of Cr(III) from aqueous solution was studied using a new chelate-resins (b-DAEG-sporopollenin and CEP-sporopollenin). Mechanisms including ion exchange, complexation and adsorption to the surface are possible in the sorption process. Adsorption analysis results obtained at various concentrations of Cr(III) showed that the adsorption pattern on the resin followed a Langmuir isotherm. Langmuir constant Gamma max and k for Cr(III) were found as 1.23, 84.84 mmol/g for b-DAEG-sporopollenin, 133.33, 10.39 mmol/g for CEP-sporopollenin at 20 +/- 1 degrees C, respectively. In addition, kinetic and thermodynamic parameters such as enthalpy (DeltaH0), free energy (DeltaG0) and entropy (DeltaS0) were calculated and these values show that adsorption of Cr(III) on b-DAEG-sporopollenin and CEP-sporopollenin was an exothermic process and the process of adsorption was favored at high temperatures. Maximum Cr(III) removal was observed near a pH of 6.

journal_name

Bioresour Technol

journal_title

Bioresource technology

authors

Gode F,Pehlivan E

doi

10.1016/j.biortech.2006.02.043

subject

Has Abstract

pub_date

2007-03-01 00:00:00

pages

904-11

issue

4

eissn

0960-8524

issn

1873-2976

pii

S0960-8524(06)00103-9

journal_volume

98

pub_type

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