Abstract:
:In this study, biochar derived from municipal sludge was activated by zinc chloride, which was first time used as the precursor for hydrothermal synthesis of magnetic sludge biochar (Fe/Zn-SBC) for tetracycline (TC) and ciprofloxacin (CIP) removal. The maximum adsorption capacity of Fe/Zn-SBC for TC and CIP were 145 mg g-1 and 74.2 mg g-1 at 25 °C, respectively. Kinetics, isotherms, thermodynamics and characterization analysis suggested that the adsorption process was dominated by pore filling, oxygen-containing groups complexation, π-π conjugation and hydrogen bonding. Fe/Zn-SBC had the high selective adsorption capacity for TC and CIP in a wide pH range and even at the high ionic strength. The magnetic sensitivity ensured its easy separation performance. The co-processing of ultrasound and ethanol could effectively regenerate the used Fe/Zn-SBC. Also, it exhibited great environmental safety in the pH range of 3 to 12. These superiority suggested that it is a promising adsorbent for antibiotics removal.
journal_name
Bioresour Technoljournal_title
Bioresource technologyauthors
Ma Y,Li M,Li P,Yang L,Wu L,Gao F,Qi X,Zhang Zdoi
10.1016/j.biortech.2020.124199subject
Has Abstractpub_date
2021-01-01 00:00:00pages
124199eissn
0960-8524issn
1873-2976pii
S0960-8524(20)31473-5journal_volume
319pub_type
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