Enhanced adsorption of phenolic compounds, commonly encountered in olive mill wastewaters, on olive husk derived activated carbons.

Abstract:

:Olive husk was used for the preparation of activated carbon by chemical activation with KOH. The effects of carbonization and activation time on carbon properties were evaluated. The surface area of the produced carbons was measured by means of N(2) adsorption at 77K. The carbons with the highest surface area were further characterized by means of elemental analysis, particle size measurement, Boehm titration, zeta potential measurement, and temperature programmed desorption (TPD). Subsequently they were used for adsorption of a mixture of polyphenols consisting of caffeic acid, vanillin, vanillic acid, pi-hydroxybenzoic acid and gallic acid at two temperatures, and their adsorptive capacity was compared to a commercial carbon Acticarbon CX and found to be higher enough. The role of the porosity and surface groups are discussed in relation to the adsorption forces and the properties of the adsorbed substances. A thermodynamic interpretation of the results is also attempted.

journal_name

Bioresour Technol

journal_title

Bioresource technology

authors

Michailof C,Stavropoulos GG,Panayiotou C

doi

10.1016/j.biortech.2007.11.057

subject

Has Abstract

pub_date

2008-09-01 00:00:00

pages

6400-8

issue

14

eissn

0960-8524

issn

1873-2976

pii

S0960-8524(07)00994-7

journal_volume

99

pub_type

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