Abstract:
:Biochar is a promising catalyst/support for biomass gasification. Hydrogen production from biomass steam gasification with biochar or Ni-based biochar has been investigated using a two stage fixed bed reactor. Commercial activated carbon was also studied as a comparison. Catalyst was prepared with an impregnation method and characterized by X-ray diffraction, specific surface and porosity analysis, X-ray fluorescence and scanning electron micrograph. The effects of gasification temperature, steam to biomass ratio, Ni loading and bio-char properties on catalyst activity in terms of hydrogen production were explored. The Ni/AC catalyst showed the best performance at gasification temperature of 800°C, S/B=4, Ni loading of 15wt.%. Texture and composition characterization of the catalysts suggested the interaction between volatiles and biochar promoted the reforming of pyrolysis volatiles. Cotton-char supported Ni exhibited the highest activity of H2 production (64.02vol.%, 92.08mgg(-1) biomass) from biomass gasification, while rice-char showed the lowest H2 production.
journal_name
Bioresour Technoljournal_title
Bioresource technologyauthors
Yao D,Hu Q,Wang D,Yang H,Wu C,Wang X,Chen Hdoi
10.1016/j.biortech.2016.05.011subject
Has Abstractpub_date
2016-09-01 00:00:00pages
159-64eissn
0960-8524issn
1873-2976pii
S0960-8524(16)30651-4journal_volume
216pub_type
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