Acrolein synthesis from glycerol in hot-compressed water.

Abstract:

:Glycerol conversion was conducted in hot-compressed water (HCW: 573-673 K, 25-34.5 MPa) using a batch and a flow apparatus and the influences of temperature, H(2)SO(4), glycerol concentration, and pressure, were examined. The yield of acrolein was enhanced by higher glycerol and H(2)SO(4) concentration, and higher pressure. Approximately 80% selectivity of acrolein was obtained at 90% of glycerol conversion with an acid catalyst in supercritical condition (673 K and 34.5 MPa). The rate constant of acrolein decomposition was always higher than that of acrolein formation in the absence of acid catalyst but the rate constant of acrolein formation could be overcome that of acrolein decomposition by addition acid in supercritical condition.

journal_name

Bioresour Technol

journal_title

Bioresource technology

authors

Watanabe M,Iida T,Aizawa Y,Aida TM,Inomata H

doi

10.1016/j.biortech.2006.05.007

subject

Has Abstract

pub_date

2007-04-01 00:00:00

pages

1285-90

issue

6

eissn

0960-8524

issn

1873-2976

pii

S0960-8524(06)00201-X

journal_volume

98

pub_type

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