Sampling the volatile-rich transition zone beneath Bermuda.

Abstract:

:Intraplate magmatic provinces found away from plate boundaries provide direct sampling of the composition and heterogeneity of the Earth's mantle. The chemical heterogeneities that have been observed in the mantle are usually attributed to recycling during subduction1-3, which allows for the addition of volatiles and incompatible elements into the mantle. Although many intraplate volcanoes sample deep-mantle reservoirs-possibly at the core-mantle boundary4-not all intraplate volcanoes are deep-rooted5, and reservoirs in other, shallower boundary layers are likely to participate in magma generation. Here we present evidence that suggests Bermuda sampled a previously unknown mantle domain, characterized by silica-undersaturated melts that are substantially enriched in incompatible elements and volatiles, and a unique, extreme isotopic signature. To our knowledge, Bermuda records the most radiogenic 206Pb/204Pb isotopes that have been documented in an ocean basin (with 206Pb/204Pb ratios of 19.9-21.7) using high-precision methods. Together with low 207Pb/204Pb ratios (15.5-15.6) and relatively invariant Sr, Nd, and Hf isotopes, the data suggest that this source must be less than 650 million years old. We therefore interpret the Bermuda source as a previously unknown, transient mantle reservoir that resulted from the recycling and storage of incompatible elements and volatiles6-8 in the transition zone (between the upper and lower mantle), aided by the fractionation of lead in a mineral that is stable only in this boundary layer, such as K-hollandite9,10. We suggest that recent recycling into the transition zone, related to subduction events during the formation of Pangea, is the reason why this reservoir has only been found in the Atlantic Ocean. Our geodynamic models suggest that this boundary layer was sampled by disturbances related to mantle flow. Seismic studies and diamond inclusions6,7 have shown that recycled materials can be stored in the transition zone11. For the first time, to our knowledge, we show geochemical evidence that this storage is key to the generation of extreme isotopic domains that were previously thought to be related only to deep recycling.

journal_name

Nature

journal_title

Nature

authors

Mazza SE,Gazel E,Bizimis M,Moucha R,Béguelin P,Johnson EA,McAleer RJ,Sobolev AV

doi

10.1038/s41586-019-1183-6

subject

Has Abstract

pub_date

2019-05-01 00:00:00

pages

398-403

issue

7756

eissn

0028-0836

issn

1476-4687

pii

10.1038/s41586-019-1183-6

journal_volume

569

pub_type

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