Abstract:
:Graft Copolymer resulting from polymerization of acrylic acid from chitosan is non-coherent, brittle and exhibit modest swelling in water, which limits its application. Chitosan-cellulose hybrid was initially prepared and novel polymeric ligand ((CTS/Cell)-g-PAA) derived from grafting polymerization of acrylic acid from this hybrid was fabricated and investigated using fourier transform infrared (FTIR) and Scanning electron microscopy (SEM). Also, the graft copolymer exhibited high mass transfer under a wide range of pH values due to its elevated hydrophilicity in addition to a good mechanical strength with respect to the comparable graft derived from chitosan as sole backbone for the grafting. The high content of different oxygen and nitrogen-containing groups in a crowded chemical atmosphere along with the high swelling qualified the graft to act as very efficient polymeric ligand with high capacity of removal of metal ions from water under broad conditions. The polymeric ligand performed outstandingly and competitively in the removal of water hardness even in presence of other interfering ions.
journal_name
Int J Biol Macromoljournal_title
International journal of biological macromoleculesauthors
Mohamed MF,Zhou X,Ibrahim HS,Ammar NS,Essawy HAdoi
10.1016/j.ijbiomac.2018.05.062subject
Has Abstractpub_date
2018-09-01 00:00:00pages
530-536eissn
0141-8130issn
1879-0003pii
S0141-8130(17)34617-2journal_volume
116pub_type
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