TiO2 Nanoribbons/Carbon Nanotubes Composite with Enhanced Photocatalytic Activity; Fabrication, Characterization, and Application.

Abstract:

:TiO2 nanoribbons (TiO2 NRs) loaded with FeCo-Al2O3 catalyst were synthesized and used as a precursor in the synthesis of TiO2 nanoribbons/carbon nanotubes (TiO2 NRs/CNTs) composite by a chemical vapor deposition (CVD) method. TiO2 NRs and TiO2 NRs/CNTs composite were characterized by XRD, FT-IR, TEM, SEM, EDX and UV-Vis spectrophotometer. The results revealed the formation of TiO2-B and hydrogen titanate nanoribbon like structures by the hydrothermal treatment. After loading TiO2 NRs by FeCo-Al2O3 catalyst and the CVD growth of carbon nanotubes, the synthetic TiO2 nanoribbons converted entirely to TiO2-B nanoribbons with nanopits structure. The composite composed of tube-like nanostructures forming an interlocked network from CNTs and TiO2-B NRs. The composite shows a relatively red-shifted band gap (3.09 eV), broader and stronger UV absorption band relative to TiO2 NRs. The photocatalytic properties of TiO2 NRs and TiO2 NRs/CNTs composite were studied under sunlight irradiation. The photocatalytic degradation of methylene blue (MB) dye was investigated as a function of contact time, dye concentration, and catalyst dose. The kinetics and mechanisms of degradation were discussed. TiO2 NRs/CNTs composite showed higher stability after six runs and 50% shorter irradiation time than TiO2 NRs photocatalyst.

journal_name

Sci Rep

journal_title

Scientific reports

authors

Shaban M,Ashraf AM,Abukhadra MR

doi

10.1038/s41598-018-19172-w

subject

Has Abstract

pub_date

2018-01-15 00:00:00

pages

781

issue

1

issn

2045-2322

pii

10.1038/s41598-018-19172-w

journal_volume

8

pub_type

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