A Sustainable Nanocomposite Au(Salen)@CC for Catalytic Degradation of Eosin Y and Chromotrope 2R Dyes.

Abstract:

:Up to now, a very few catalysts have been developed approaching the heterogeneous catalytic degradation of Eosin Y and Chromotrope 2R dyes (Acid Red 29). The present study provides a complete perspective of recyclable nanocomposite Au(Salen)@CC for catalytic degradation of hazardous water pollutant dyes viz., Eosin Y & Chromotrope 2R using mild reaction conditions. New gold Salen complex doped carbon nanocomposite Au(Salen)@CC was developed by easy methodology using nano carbon cage (CC) prepared from low-priced Pyrolysis fuel oil (PFO) residue based Pitch. The UV-Vis adsorption spectroscopy results of Eosin Y and Chromotrope 2R dyes indicated complete degradation into acidic compounds which can be further mineralized to CO2 and H2O under mild reaction conditions. The heterogeneous catalyst recycled and reused successfully for four repeated experiments without loss in its adequate performance. This new sustainable and eco-friendly catalyst delivered significant degradation activity compared to existing reports and it can be further utilized for new multifunctional applications such as, radiopharmaceutical activities, heterogeneous catalysis and chiral resolution.

journal_name

Sci Rep

journal_title

Scientific reports

authors

Mayani VJ,Mayani SV,Kim SW

doi

10.1038/s41598-017-07707-6

subject

Has Abstract

pub_date

2017-08-03 00:00:00

pages

7239

issue

1

issn

2045-2322

pii

10.1038/s41598-017-07707-6

journal_volume

7

pub_type

杂志文章
  • Usefulness of continuous probability distributions of rates for modelling radionuclide biokinetics in humans and animals.

    abstract::Modelling the biokinetics of radionuclide excretion or retention is important in nuclear medicine and following accidental/malicious radioactivity releases. Sums of discrete exponential decay rates are often used, but we hypothesized that continuous probability distributions (CPD) of decay rates can describe the data ...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-018-38046-9

    authors: Shuryak I,Dadachova E

    更新日期:2019-02-04 00:00:00

  • The metabolic footprint of compromised insulin sensitivity under fasting and hyperinsulinemic-euglycemic clamp conditions in an Arab population.

    abstract::Metabolic pathways that are corrupted at early stages of insulin resistance (IR) remain elusive. This study investigates changes in body metabolism in clinically healthy and otherwise asymptomatic subjects that may become apparent already under compromised insulin sensitivity (IS) and prior to IR. 47 clinically health...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-020-73723-8

    authors: Halama A,Suleiman NN,Kulinski M,Bettahi I,Hassoun S,Alkasem M,Abdalhakam I,Iskandarani A,Samra TA,Atkin SL,Suhre K,Abou-Samra AB

    更新日期:2020-10-13 00:00:00

  • Prospects for microwave plasma synthesized N-graphene in secondary electron emission mitigation applications.

    abstract::The ability to change the secondary electron emission properties of nitrogen-doped graphene (N-graphene) has been demonstrated. To this end, a novel microwave plasma-enabled scalable route for continuous and controllable fabrication of free-standing N-graphene sheets was developed. High-quality N-graphene with prescri...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-020-69844-9

    authors: Bundaleska N,Dias A,Bundaleski N,Felizardo E,Henriques J,Tsyganov D,Abrashev M,Valcheva E,Kissovski J,Ferraria AM,do Rego AMB,Almeida A,Zavašnik J,Cvelbar U,Teodoro OMND,Strunskus T,Tatarova E

    更新日期:2020-08-03 00:00:00

  • Autonomic adaptations mediate the effect of hydration on brain functioning and mood: Evidence from two randomized controlled trials.

    abstract::Dehydration (water loss >2.0% of body weight) has significant negative effects on physical and mental performance. In two studies the effects of minor hypo-hydration (water loss <1.0% of body weight) on CNS function, mood and cardiovascular functioning were measured. Study 1: On two mornings twelve male participants w...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-019-52775-5

    authors: Young HA,Cousins A,Johnston S,Fletcher JM,Benton D

    更新日期:2019-11-11 00:00:00

  • A common protocol for the simultaneous processing of multiple clinically relevant bacterial species for whole genome sequencing.

    abstract::Whole-genome sequencing is likely to become increasingly used by local clinical microbiology laboratories, where sequencing volume is low compared with national reference laboratories. Here, we describe a universal protocol for simultaneous DNA extraction and sequencing of numerous different bacterial species, allowin...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-020-80031-8

    authors: Raven KE,Girgis ST,Akram A,Blane B,Leek D,Brown N,Peacock SJ

    更新日期:2021-01-08 00:00:00

  • Transparent organic photodetector using a near-infrared absorbing cyanine dye.

    abstract::Organic photodetectors are interesting for low cost, large area optical sensing applications. Combining organic semiconductors with discrete absorption bands outside the visible wavelength range with transparent and conductive electrodes allows for the fabrication of visibly transparent photodetectors. Visibly transpa...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/srep09439

    authors: Zhang H,Jenatsch S,De Jonghe J,Nüesch F,Steim R,Véron AC,Hany R

    更新日期:2015-03-24 00:00:00

  • Unraveling a molecular determinant for clathrin-independent internalization of the M2 muscarinic acetylcholine receptor.

    abstract::Endocytosis and postendocytic sorting of G-protein-coupled receptors (GPCRs) is important for the regulation of both their cell surface density and signaling profile. Unlike the mechanisms of clathrin-dependent endocytosis (CDE), the mechanisms underlying the control of GPCR signaling by clathrin-independent endocytos...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/srep11408

    authors: Wan M,Zhang W,Tian Y,Xu C,Xu T,Liu J,Zhang R

    更新日期:2015-06-22 00:00:00

  • Long-term bowel dysfunction following low anterior resection.

    abstract::Study aimed to assess long-term bowel function in patients who underwent low anterior resection for cancer five and more years ago. Patients who underwent low anterior resection for rectal cancer from 2010 to 2015 at National Cancer Institute were prospectively included in our study. They were interviewed using low an...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-020-68900-8

    authors: Dulskas A,Kavaliauskas P,Pilipavicius L,Jodinskas M,Mikalonis M,Samalavicius NE

    更新日期:2020-07-17 00:00:00

  • A bivariate genome-wide association study identifies ADAM12 as a novel susceptibility gene for Kashin-Beck disease.

    abstract::Kashin-Beck disease (KBD) is a chronic osteoarthropathy, which manifests as joint deformities and growth retardation. Only a few genetic studies of growth retardation associated with the KBD have been carried out by now. In this study, we conducted a two-stage bivariate genome-wide association study (BGWAS) of the KBD...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/srep31792

    authors: Hao J,Wang W,Wen Y,Xiao X,He A,Guo X,Yang T,Liu X,Shen H,Chen X,Tian Q,Deng HW,Zhang F

    更新日期:2016-08-22 00:00:00

  • Probing rapid carbon fixation in fast-growing seaweed Ulva meridionalis using stable isotope 13C-labelling.

    abstract::The high growth rate of Ulva seaweeds makes it a potential algal biomass resource. In particular, Ulva meridionalis grows up to fourfold a day. Here, we demonstrated strong carbon fixation by U. meridionalis using 13C stable isotope labelling and traced the 13C flux through sugar metabolites with isotope-ratio mass sp...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-020-77237-1

    authors: Tsubaki S,Nishimura H,Imai T,Onda A,Hiraoka M

    更新日期:2020-11-23 00:00:00

  • The RIFLE versus AKIN classification for incidence and mortality of acute kidney injury in critical ill patients: A meta-analysis.

    abstract::The sensitivity and accuracy of the Risk/Injury/Failure/Loss/End-stage (RIFLE) versus acute kidney injury Network (AKIN) criteria for acute kidney injury (AKI) in critically ill patients remains uncertain. Therefore, we performed a systematic review and meta-analysis to investigate the incidence and prognostic value o...

    journal_title:Scientific reports

    pub_type: 杂志文章,meta分析

    doi:10.1038/srep17917

    authors: Xiong J,Tang X,Hu Z,Nie L,Wang Y,Zhao J

    更新日期:2015-12-07 00:00:00

  • Author Correction: Iron induces insulin resistance in cardiomyocytes via regulation of oxidative stress.

    abstract::An amendment to this paper has been published and can be accessed via a link at the top of the paper. ...

    journal_title:Scientific reports

    pub_type: 已发布勘误

    doi:10.1038/s41598-020-58752-7

    authors: Sung HK,Song E,Jahng JWS,Pantopoulos K,Sweeney G

    更新日期:2020-01-30 00:00:00

  • A novel classification regression method for gridded electric power consumption estimation in China.

    abstract::Spatially explicit information on electric power consumption (EPC) is crucial for effective electricity allocation and utilization. Many studies have estimated fine-scale spatial EPC based on remotely sensed nighttime light (NTL). However, the spatial non-stationary relationship between EPC and NTL at prefectural leve...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-020-75543-2

    authors: Chen M,Cai H,Yang X,Jin C

    更新日期:2020-10-29 00:00:00

  • Structural and functional characterization of M. tuberculosis sedoheptulose- 7-phosphate isomerase, a critical enzyme involved in lipopolysaccharide biosynthetic pathway.

    abstract::M. tuberculosis GmhA enzyme catalyzes the isomerization of D-sedoheptulose 7-phosphate into D-glycero-D-α-manno-heptose-7-phosphate in GDP-D-glycero-α-D-manno-heptose biosynthetic pathway. The D-glycero-α-D-manno-heptose is a major constituent of lipopolysaccharide and contributes to virulence and antibiotic resistanc...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-020-77230-8

    authors: Karan S,Pratap B,Yadav SP,Ashish F,Saxena AK

    更新日期:2020-11-30 00:00:00

  • Solitonic Josephson-based meminductive systems.

    abstract::Memristors, memcapacitors, and meminductors represent an innovative generation of circuit elements whose properties depend on the state and history of the system. The hysteretic behavior of one of their constituent variables, is their distinctive fingerprint. This feature endows them with the ability to store and proc...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/srep46736

    authors: Guarcello C,Solinas P,Di Ventra M,Giazotto F

    更新日期:2017-04-24 00:00:00

  • Heterozygous HbAC but not HbAS is associated with higher newborn birthweight among women with pregnancy-associated malaria.

    abstract::Pregnancy-associated malaria (PAM) is associated with poor pregnancy outcomes. Hemoglobin S (HbS) and hemoglobin C (HbC) mutations are frequently encountered in malaria-endemic areas of Africa, where they protect children from severe and uncomplicated Plasmodium falciparum malaria. However, scant epidemiological data ...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-017-01495-9

    authors: Tétard M,Milet J,Dechavanne S,Fievet N,Dorin-Semblat D,Elion J,Fairhurst RM,Deloron P,Tuikue-Ndam N,Gamain B

    更新日期:2017-05-03 00:00:00

  • Dendritic cells and macrophages neurally hard-wired in the lymph node.

    abstract::The neural hard-wired pathways in which the lymphoid organs are innervated by the nervous system is of special interest with respect to suggested afferent and sensory systems informing the central nervous system about the status of the immune system. Until today efferent also like afferent innervation seem to be unspe...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/srep16866

    authors: Wülfing C,Günther HS

    更新日期:2015-11-19 00:00:00

  • Levosimendan displays anti-inflammatory effects and decreases MPO bioavailability in patients with severe heart failure.

    abstract::Treatment of decompensated heart failure often includes administration of levosimendan. Myeloperoxidase (MPO) is released during polymorphonuclear neutrophil (PMN) degranulation, and mediates dysregulation of vascular tone in heart failure. We evaluated the effects of levosimendan-treatment on MPO in patients with acu...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/srep09704

    authors: Adam M,Meyer S,Knors H,Klinke A,Radunski UK,Rudolph TK,Rudolph V,Spin JM,Tsao PS,Costard-Jäckle A,Baldus S

    更新日期:2015-04-13 00:00:00

  • CRISPR knockout rat cytochrome P450 3A1/2 model for advancing drug metabolism and pharmacokinetics research.

    abstract::Cytochrome P450 (CYP) 3A accounts for nearly 30% of the total CYP enzymes in the human liver and participates in the metabolism of over 50% of clinical drugs. Moreover, CYP3A plays an important role in chemical metabolism, toxicity, and carcinogenicity. New animal models are needed to investigate CYP3A functions, espe...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/srep42922

    authors: Lu J,Shao Y,Qin X,Liu D,Chen A,Li D,Liu M,Wang X

    更新日期:2017-02-20 00:00:00

  • U-shaped relationship between current and pitch in helicene molecules.

    abstract::The helicene is constructed by twisted benzene or other aromatic rings, exhibiting a helical structure. Using first-principles calculations, we investigate the electronic transport of helicenes under stretching or compressing. Interestingly, a U-shaped curve of the current against d (the pitch of a helicene) is observ...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/srep16731

    authors: Guo YD,Yan XH,Xiao Y,Liu CS

    更新日期:2015-11-19 00:00:00

  • Role of metformin in epigenetic regulation of placental mitochondrial biogenesis in maternal diabetes.

    abstract::Adverse maternal environments, such as diabetes and obesity, impair placental mitochondrial function, which affects fetal development and offspring long-term health. The underlying mechanisms and effective interventions to abrogate such effect remain unclear. Our previous studies demonstrated impaired mitochondrial bi...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-020-65415-0

    authors: Jiang S,Teague AM,Tryggestad JB,Jensen ME,Chernausek SD

    更新日期:2020-05-20 00:00:00

  • Responses of the Hybrid between Sphagneticola trilobata and Sphagneticola calendulacea to Low Temperature and Weak Light Characteristic in South China.

    abstract::Hybridization between exotic and native species is of great interest to evolutionary biologists and ecologists because it usually shows a quick evolution of species and invasiveness. It has been reported that such hybridization frequently increases the adaptation and aggressiveness of the new hybrids. A hybrid between...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/srep16906

    authors: Sun Z,Chen Y,Schaefer V,Liang H,Li W,Huang S,Peng C

    更新日期:2015-11-19 00:00:00

  • Fano resonances in bilayer graphene superlattices.

    abstract::In this work, we address the ubiquitous phenomenon of Fano resonances in bilayer graphene. We consider that this phenomenon is as exotic as other phenomena in graphene because it can arise without an external extended states source or elaborate nano designs. However, there are not theoretical and/or experimental studi...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-017-16838-9

    authors: Briones-Torres JA,Rodríguez-Vargas I

    更新日期:2017-12-01 00:00:00

  • Acute Psychological Stress Disrupts Attentional Bias to Threat-Related Stimuli.

    abstract::The present study investigated the effect of acute stress on attentional bias to threat using behavioral and ERP methods. Sixty-two male participants were randomly assigned to a stress condition (Trier Social Stress Test) or a control condition. To examine the impact of stress-induced cortisol on attentional bias to t...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-017-14138-w

    authors: Jiang C,Buchanan TW,Yao Z,Zhang K,Wu J,Zhang L

    更新日期:2017-11-06 00:00:00

  • First-in-class small molecule potentiators of cancer virotherapy.

    abstract::The use of engineered viral strains such as gene therapy vectors and oncolytic viruses (OV) to selectively destroy cancer cells is poised to make a major impact in the clinic and revolutionize cancer therapy. In particular, several studies have shown that OV therapy is safe and well tolerated in humans and can infect ...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/srep26786

    authors: Dornan MH,Krishnan R,Macklin AM,Selman M,El Sayes N,Son HH,Davis C,Chen A,Keillor K,Le PJ,Moi C,Ou P,Pardin C,Canez CR,Le Boeuf F,Bell JC,Smith JC,Diallo JS,Boddy CN

    更新日期:2016-05-26 00:00:00

  • Ultra-high open-circuit voltage of perovskite solar cells induced by nucleation thermodynamics on rough substrates.

    abstract::To obtain high performance CH3NH3PbI3 perovskite solar cells, it is highly important to realise a high open-circuit voltage. Calculation results based on a modified diode model have indicated that a low bare ratio ϕ of the perovskite film is the most important factor determining the open-circuit voltage, where ϕ is de...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/srep46141

    authors: Li Y,Ding B,Chu QQ,Yang GJ,Wang M,Li CX,Li CJ

    更新日期:2017-04-12 00:00:00

  • Achieving waste to energy through sewage sludge gasification using hot slags: syngas production.

    abstract::To relieve the environmental issues of sewage sludge (SS) disposal and greenhouse gas (GHG) emission in China, we proposed an integrated method for the first time to simultaneously deal with these two problems. The hot slags below 920 °C could act as a good heat carrier for sludge gasification and the increasing CO2 c...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/srep11436

    authors: Sun Y,Nakano J,Liu L,Wang X,Zhang Z

    更新日期:2015-06-15 00:00:00

  • Noble-metal-free plasmonic photocatalyst: hydrogen doped semiconductors.

    abstract::The unique capacity of localized surface plasmon resonance (LSPR) offers a new opportunity to overcome the limited efficiency of semiconductor photocatalyst. Here we unravel that LSPR, which usually occurs in noble metal nanoparticles, can be realized by hydrogen doping in noble-metal-free semiconductor using TiO2 as ...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/srep03986

    authors: Ma X,Dai Y,Yu L,Huang B

    更新日期:2014-02-05 00:00:00

  • Costunolide and dehydrocostuslactone combination treatment inhibit breast cancer by inducing cell cycle arrest and apoptosis through c-Myc/p53 and AKT/14-3-3 pathway.

    abstract::Our previous studies demonstrated that volatile oil from saussurea lappa root (VOSL), rich in two natural sesquiterpene lactones, costunolide (Cos) and dehydrocostuslactone (Dehy), exerts better anti-breast cancer efficacy and lower side effects than Cos or Dehy alone in vivo, however, their anti-cancer molecular mech...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/srep41254

    authors: Peng Z,Wang Y,Fan J,Lin X,Liu C,Xu Y,Ji W,Yan C,Su C

    更新日期:2017-01-24 00:00:00

  • Distinct epigenetic signatures between adult-onset and late-onset depression.

    abstract::The heterogeneity of major depressive disorder (MDD) is attributed to the fact that diagnostic criteria (e.g., DSM-5) are only based on clinical symptoms. The discovery of blood biomarkers has the potential to change the diagnosis of MDD. The purpose of this study was to identify blood biomarkers of DNA methylation by...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-021-81758-8

    authors: Yamagata H,Ogihara H,Matsuo K,Uchida S,Kobayashi A,Seki T,Kobayashi M,Harada K,Chen C,Miyata S,Fukuda M,Mikuni M,Hamamoto Y,Watanabe Y,Nakagawa S

    更新日期:2021-01-27 00:00:00