Cellulosic graft copolymer: poly(methyl methacrylate) with cellulose side chains.

Abstract:

:A cellulose macromonomer, N-(15-methacryloyloxypentadecanoyl)-tri-O-acetyl-beta-cellulosylamine (CTA-C15-MA (2); M(2)) with number averaged degree of polymerization (DP(n)) = 13), was copolymerized with methyl methacrylate (MMA; M(1)) to give cellulosic copolymer with CTA side chains, PMMA-g-(CTA-C15) (3-A). An absolute molecular weight determined by multiangle laser light scattering (MALS; M(w,LS)), degree of polymerization of MMA (X) and CTA-C15-MA (Y) of PMMA-g-(CTA-C15) (3-A) were determined to be M(w,LS) = 6.30 x 10(4), X = 4.14 x 10(2), and Y = 3.86. Cellulose graft copolymer with cellulose side chains, PMMA-g-(cellulose-C15) (3-H) was successfully obtained after deacetylation of the copolymer 3-A. Thermal analysis of copolymers 3-A and 3-H by means of differential scanning calorimetry (DSC) measurements revealed that a small amount of CTA and cellulose side chains affected thermal properties of the PMMA main chain.

journal_name

Biomacromolecules

journal_title

Biomacromolecules

authors

Enomoto-Rogers Y,Kamitakahara H,Takano T,Nakatsubo F

doi

10.1021/bm900229g

subject

Has Abstract

pub_date

2009-08-10 00:00:00

pages

2110-7

issue

8

eissn

1525-7797

issn

1526-4602

journal_volume

10

pub_type

杂志文章
  • A small-angle X-ray scattering study of the effect of hydration on the microstructure of flax fibers.

    abstract::Small-angle X-ray scattering (SAXS) experiments with in situ dehydration have been performed on small bundles of flax fibers. Analysis indicated that the structure of the cellulose microfibrils is consistent with a cross section of approximately 10 x 50 A2. The microfibril misalignment was Gaussian with a full width a...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm005643l

    authors: Astley OM,Donald AM

    更新日期:2001-10-01 00:00:00

  • Biodegradable nanoparticles meet the bronchial airway barrier: how surface properties affect their interaction with mucus and epithelial cells.

    abstract::Despite the wide interest raised by lung administration of nanoparticles (NPs) for the treatment of various diseases, little information is available on their effect toward the airway epithelial barrier function. In this study, the potential damage of the pulmonary epithelium upon exposure to poly(lactide-co-glycolide...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm201226x

    authors: Mura S,Hillaireau H,Nicolas J,Kerdine-Römer S,Le Droumaguet B,Deloménie C,Nicolas V,Pallardy M,Tsapis N,Fattal E

    更新日期:2011-11-14 00:00:00

  • Size control of silica nanoparticles and their surface treatment for fabrication of dental nanocomposites.

    abstract::Nearly monodispersed silica nanoparticles having a controlled size from 5 to 450 nm were synthesized via a sol-gel process, and then the optimum conditions for the surface treatment of the synthesized silica nanoparticles with a silane coupling agent (i.e., 3-methacryloxypropyltrimethoxysilane (gamma-MPS)) were explor...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm060560b

    authors: Kim JW,Kim LU,Kim CK

    更新日期:2007-01-01 00:00:00

  • Calixarene-assisted protein refolding via liquid-liquid extraction.

    abstract::In this paper we report on protein refolding by means of a liquid-liquid transfer technique using a calixarene. We have found that a calix[6]areneacetic acid derivative forms a supramolecular complex with urea-denatured cytochrome c at the oil-water interface, which enables quantitative transfer of the protein from an...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm070418q

    authors: Shimojo K,Oshima T,Naganawa H,Goto M

    更新日期:2007-10-01 00:00:00

  • Polarity and motility of large polymer-actin complexes.

    abstract::The polarity of polymer-actin complexes obtained by mixing F-actin with synthetic polymers carrying positive charges such as poly(L-lysine), x,y-ionene bromide polymers, and poly(N-[3-(dimethylamino)propyl]acrylamide) (PDMAPAA-Q) have been investigated. Actin complexes formed with poly(L-lysine) and PDMAPAA-Q, which c...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm0494038

    authors: Kakugo A,Shikinaka K,Takekawa N,Sugimoto S,Osada Y,Gong JP

    更新日期:2005-03-01 00:00:00

  • Effects of emulsion droplet size on the structure of electrospun ultrafine biocomposite fibers with cellulose nanocrystals.

    abstract::Electrospinning of cellulose nanocrystals (CNC)/poly(lactic acid) (PLA) emulsions has been demonstrated to be an effective dispersion and alignment method to control assembly of CNC into continuous composite ultrafine fibers. CNC-PLA nanocomposite random-fiber mats and aligned-fiber yarns were prepared by emulsion ele...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm400540v

    authors: Li Y,Ko FK,Hamad WY

    更新日期:2013-11-11 00:00:00

  • Photoluminescent porous alginate hybrid materials containing lanthanide ions.

    abstract::The photoluminescence features of Eu(3+)-, Tb(3+)-, Tb(3+)/Eu(3+)-alginate aerogel (hydrogel and alcogel) and Eu(3+)-alginate xerogel hybrids were investigated. The Eu(3+)-alginate aerogel and alcogel exhibit the highest (5)D0 quantum efficiencies (9.9 and 8.2%, respectively), while the hydrogel and xerogel have lower...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm8002122

    authors: Liu F,Carlos LD,Ferreira RA,Rocha J,Gaudino MC,Robitzer M,Quignard F

    更新日期:2008-07-01 00:00:00

  • Milliscale Self-Integration of Megamolecule Biopolymers on a Drying Gas-Aqueous Liquid Crystalline Interface.

    abstract::A drying environment is always a proposition faced by dynamic living organisms using water, which are driven by biopolymer-based micro- and macrostructures. Here, we introduce a drying process for aqueous liquid crystalline (LC) solutions composed of biopolymer with extremely high molecular weight components such as p...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/acs.biomac.6b00302

    authors: Okeyoshi K,Okajima MK,Kaneko T

    更新日期:2016-06-13 00:00:00

  • Nanometer to millimeter scale peptide-porphyrin materials.

    abstract::AQ-Pal14 is a 30-residue polypeptide that was designed to form an α-helical coiled coil that contains a metal-binding 4-pyridylalanine residue on its solvent-exposed surface. However, characterization of this peptide shows that it exists as a three-stranded coiled coil, not a two-stranded one as predicted from its des...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm100540t

    authors: Zaytsev DV,Xie F,Mukherjee M,Bludin A,Demeler B,Breece RM,Tierney DL,Ogawa MY

    更新日期:2010-10-11 00:00:00

  • Functionalization of poly(oligo(ethylene glycol) methacrylate) films on gold and Si/SiO2 for immobilization of proteins and cells: SPR and QCM studies.

    abstract::Thin films of a biocompatible and nonbiofouling poly(oligo(ethylene glycol) methacrylate) ( pOEGMA) with various thicknesses were formed on gold and Si/SiO 2 substrates by a combination of the formation of self-assembled monolayers (SAMs) terminating in bromoester-an initiator of atom transfer radical polymerization (...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm7009043

    authors: Lee BS,Chi YS,Lee KB,Kim YG,Choi IS

    更新日期:2007-12-01 00:00:00

  • EGFR-Targeted Polymeric Mixed Micelles Carrying Gemcitabine for Treating Pancreatic Cancer.

    abstract::The objective of this study was to design GE11 peptide (YHWYGYTPQNVI) linked micelles of poly(ethylene glycol)-block-poly(2-methyl-2-carboxyl-propylene carbonate-graft-gemcitabine-graft-dodecanol (PEG-b-PCC-g-GEM-g-DC) for enhanced stability and target specificity of gemcitabine (GEM) to EGFR-positive pancreatic cance...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/acs.biomac.5b01419

    authors: Mondal G,Kumar V,Shukla SK,Singh PK,Mahato RI

    更新日期:2016-01-11 00:00:00

  • Bioinspired pH- and Temperature-Responsive Injectable Adhesive Hydrogels with Polyplexes Promotes Skin Wound Healing.

    abstract::Despite great potential, the delivery of genetic materials into cells or tissues of interest remains challenging owing to their susceptibility to nuclease degradation, lack of permeability to the cell membrane, and short in vivo half-life, which severely restrict their widespread use in therapeutics. To surmount these...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/acs.biomac.8b00819

    authors: Le TMD,Duong HTT,Thambi T,Giang Phan VH,Jeong JH,Lee DS

    更新日期:2018-08-13 00:00:00

  • Novel insulin thiomer nanoparticles: in vivo evaluation of an oral drug delivery system.

    abstract::It was aim of the study to investigate the in vivo potential of a novel insulin-thiomer complex nanoparticulate delivery system. Insulin loaded nanoparticles were obtained by the formation of hydrogen bonds between poly(vinyl pyrrolidone) (PVP) and poly(acrylic acid)-cysteine (PAA-Cys) or poly(acrylic acid) (PAA), res...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm700916h

    authors: Deutel B,Greindl M,Thaurer M,Bernkop-Schnürch A

    更新日期:2008-01-01 00:00:00

  • Kinetic chain lengths in highly cross-linked networks formed by the photoinitiated polymerization of divinyl monomers: a gel permeation chromatography investigation.

    abstract::Highly cross-linked networks formed by the photoinitiated polymerization of multifunctional monomers are finding application in the field of biomaterials because of their chemical versatility, reaction control, and ability to polymerize under physiological conditions. Typically, degradation is introduced into these ne...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm025677o

    authors: Burdick JA,Lovestead TM,Anseth KS

    更新日期:2003-01-01 00:00:00

  • Controlled synthesis and inclusion ability of a hyaluronic acid derivative bearing beta-cyclodextrin molecules.

    abstract::A new synthetic route to beta-cyclodextrin-linked hyaluronic acid (HA-CD) was developed. This was based on the preparation of a HA derivative selectively modified with adipic dihydrazide (HA-ADH) and a beta-cyclodextrin derivative possessing an aldehyde function on the primary face, followed by their coupling by a red...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm0507094

    authors: Charlot A,Heyraud A,Guenot P,Rinaudo M,Auzély-Velty R

    更新日期:2006-03-01 00:00:00

  • Conjugation with betaine: a facile and effective approach to significant improvement of gene delivery properties of PEI.

    abstract::Herein, we developed a new gene delivery vector by grafting a betaine monomer (N,N-dimethyl(acrylamidopropyl)ammonium propane sulfonate, DMAAPS) onto 25 KDa polyethylenimine (PEI 25K) via the Michael addition reaction. The graft ratio for betaine on PEI polymer could be readily controlled, and in this study three PEI-...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm301826m

    authors: Sun J,Zeng F,Jian H,Wu S

    更新日期:2013-03-11 00:00:00

  • Global structures of high methoxyl pectin from solution and in gels.

    abstract::Images of high methoxyl orange pectin deposited from solution and high methoxyl sugar acid gels (HMSAG) were obtained by atomic force microscopy (AFM) in the tapping mode. For the first time, images of pectin deposited from water revealed that the transition from pectin networks to individual molecules or aggregates t...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm0607729

    authors: Fishman ML,Cooke PH,Chau HK,Coffin DR,Hotchkiss AT Jr

    更新日期:2007-02-01 00:00:00

  • Self-assembly of monoglycerides in beta-lactoglobulin adsorbed films at the air-water interface. Structural, topographical, and rheological consequences.

    abstract::In this work, we have analyzed the structural, topographical, and surface dilatational characteristics of pure beta-lactoglobulin adsorbed films and the effect of the self-assembly of monoglycerides (monopalmitin or monoolein) in beta-lactoglobulin films at the air-water interface. Measurements were performed in a sin...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm060144r

    authors: Rodríguez Patino JM,Fernandez MC,Rodríguez Niño MR,Sanchez CC

    更新日期:2006-09-01 00:00:00

  • On-off switching of gene expression regulated with carbohydrate-lectin interaction.

    abstract::A novel strategy for artificial regulation system of gene expression applying the specific molecular recognition between carbohydrate and lectin is proposed. Plasmid-lactose conjugates (pActin-lactose and pGFP-lactose) prepared via diazocoupling maintained the transcription activity with T7 RNA polymerase. Gel-shift a...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm050255a

    authors: Matsuura K,Hayashi K,Kobayashi K

    更新日期:2005-09-01 00:00:00

  • Agarose hydrogels embedded with pH-responsive diblock copolymer micelles for triggered release of substances.

    abstract::Hybrid agarose hydrogels embedded with pH-responsive diblock copolymers micelles were developed to achieve functional hydrogels capable of stimulus-triggered drug release. Specifically, a well-defined poly(ethylene oxide) (PEO)-based diblock copolymer, PEO-b-poly(2-(N,N-diisopropylamino)ethyl methacrylate) (PEO(113)-b...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm4005639

    authors: Jin N,Morin EA,Henn DM,Cao Y,Woodcock JW,Tang S,He W,Zhao B

    更新日期:2013-08-12 00:00:00

  • Analysis of adsorption function of polyhydroxybutyrate depolymerase from Alcaligenes faecalis T1 by using a quartz crystal microbalance.

    abstract::Enzymatic adsorption and degradation of three types of aliphatic polyester films and two types of polyolefin films by the extracellular PHB depolymerase from Alcaligenes faecalis T1 have been studied by using a quartz crystal microbalance (QCM) technique. Hydrolysis of poly[(R)-3-hydroxybutyrate] was quantitatively fo...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm0000844

    authors: Yamashita K,Aoyagi Y,Abe H,Doi Y

    更新日期:2001-04-01 00:00:00

  • Radiotherapy-Sensitized Tumor Photothermal Ablation Using γ-Polyglutamic Acid Nanogels Loaded with Polypyrrole.

    abstract::Development of versatile nanoscale platforms for cancer diagnosis and therapy is of great importance for applications in translational medicine. In this work, we present the use of γ-polyglutamic acid (γ-PGA) nanogels (NGs) to load polypyrrole (PPy) for thermal/photoacoustic (PA) imaging and radiotherapy (RT)-sensitiz...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/acs.biomac.8b00184

    authors: Zhou Y,Hu Y,Sun W,Lu S,Cai C,Peng C,Yu J,Popovtzer R,Shen M,Shi X

    更新日期:2018-06-11 00:00:00

  • Oxidation-responsive OEGylated poly-L-cysteine and solution properties studies.

    abstract::The oxidation-responsive behaviors of OEGylated poly-L-cysteine homopolypeptides, that is, poly(L-EG(x)MA-C)n, were investigated. These poly-L-cysteine derivatives adopted mixed conformation in water, in which the β-sheet accounted for a significant proportion. Upon oxidation, the thioethers in polypeptide side chains...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm5000554

    authors: Fu X,Ma Y,Shen Y,Fu W,Li Z

    更新日期:2014-03-10 00:00:00

  • Specific Drug Formulation Additives: Revealing the Impact of Architecture and Block Length Ratio.

    abstract::Combining poly(ethylene glycol) (PEG) with sequence-defined peptides in PEG-peptide conjugates offers opportunities to realize next-generation drug formulation additives for overcoming undesired pharmacological profiles of difficult small molecule drugs. The tailored peptide segments provide sequence-specific, noncova...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/acs.biomac.5b00961

    authors: Wieczorek S,Schwaar T,Senge MO,Börner HG

    更新日期:2015-10-12 00:00:00

  • Sericin Promotes Fibroin Silk I Stabilization Across a Phase-Separation.

    abstract::Natural silk spinning offers several advantages over the synthetic fiber spinning, although the underlying mechanisms of this process are yet to be fully elucidated. Silkworm silks, specifically B. mori, comprise two main proteins: fibroin, which forms the fiber, and sericin, a coextruded coating that acts as a matrix...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/acs.biomac.7b00549

    authors: Kwak HW,Ju JE,Shin M,Holland C,Lee KH

    更新日期:2017-08-14 00:00:00

  • Polyethylenimine based magnetic iron-oxide vector: the effect of vector component assembly on cellular entry mechanism, intracellular localization, and cellular viability.

    abstract::The order of assembly of a magnetic nanoparticle (MNP) vector comprised of the same components (MNP, PEI, and plasmid DNA) on entry mechanism, intracellular localization, and viability of BHK21 cells was investigated. Cellular uptake measurements under four different uptake inhibiting conditions, such as low temperatu...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm100748p

    authors: Arsianti M,Lim M,Marquis CP,Amal R

    更新日期:2010-09-13 00:00:00

  • Synthesis and characterization of glycopolymer-polypeptide triblock copolymers.

    abstract::Glycopolymer-polypeptide triblock copolymers of the structure, poly(l-alanine)-b-poly(2-acryloyloxyethyl-lactoside)-b-poly(l-alanine) (AGA), have been synthesized by sequential atom transfer radical polymerization (ATRP) and ring-opening polymerization (ROP). Controlled free radical polymerization of 2-O-acryloyl-oxye...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm0343500

    authors: Dong CM,Sun XL,Faucher KM,Apkarian RP,Chaikof EL

    更新日期:2004-01-01 00:00:00

  • A platelet-mimetic paradigm for metastasis-targeted nanomedicine platforms.

    abstract::There is compelling evidence that, beyond their traditional role in hemostasis and thrombosis, platelets play a significant role in mediating hematologic mechanisms of tumor metastasis by directly and indirectly interacting with pro-metastatic cancer cells. With this rationale, we hypothesized that platelets can be an...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm301996p

    authors: Modery-Pawlowski CL,Master AM,Pan V,Howard GP,Sen Gupta A

    更新日期:2013-03-11 00:00:00

  • Formulation and drying of alginate beads for controlled release and stabilization of invertase.

    abstract::Several alternatives to the conventional alginate beads formulation were studied for encapsulation of invertase. Pectin was added to the alginate/enzyme solution while trehalose and β-cyclodextrin were added to the calcium gelation media. The effect of composition changes, freezing, drying methods (freeze, vacuum, or ...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm2009075

    authors: Santagapita PR,Mazzobre MF,Buera MP

    更新日期:2011-09-12 00:00:00

  • Simultaneous enhancement of cell proliferation and thermally induced harvest efficiency based on temperature-responsive cationic copolymer-grafted microcarriers.

    abstract::The development of large-scale suspension cell cultures using microcarriers has long been a focus of attention in the fields of pharmacy and biotechnology. Previously, we developed cell-detachable microcarriers based on temperature-responsive poly(N-isopropylacrylamide) (PIPAAm)-grafted beads, on which adhering cells ...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm300256e

    authors: Tamura A,Nishi M,Kobayashi J,Nagase K,Yajima H,Yamato M,Okano T

    更新日期:2012-06-11 00:00:00