Characterization of gunpowder samples using time-of-flight secondary ion mass spectrometry (TOF-SIMS).

Abstract:

:Time-of-flight secondary ion mass spectrometry (TOF-SIMS) was utilized to obtain characteristic mass spectra from three different smokeless powders and six different black powder samples. In these mass spectra, peaks indicative of both the organic and inorganic additive constituents in the gunpowders were observed. TOF-SIMS was able to successfully differentiate between the different black and smokeless gunpowder samples analyzed with the aid of principal components analysis (PCA), a multivariate statistical analysis approach often used to reduce the dimensionality of complex data. TOF-SIMS was also used to obtain information about the spatial distribution of the various additives contained within the gunpowder samples. SIMS imaging demonstrated that that the samples could potentially be characterized by their 2-D structure, which varied from sample to sample. These results clearly demonstrate the feasibility of utilizing TOF-SIMS as a tool for the characterization and differentiation of gunpowder samples for general forensic applications.

journal_name

Forensic Sci Int

authors

Mahoney CM,Gillen G,Fahey AJ

doi

10.1016/j.forsciint.2005.02.036

keywords:

subject

Has Abstract

pub_date

2006-04-20 00:00:00

pages

39-51

issue

1

eissn

0379-0738

issn

1872-6283

pii

S0379-0738(05)00237-9

journal_volume

158

pub_type

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